• 한국항만학회지
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• 제14권4호
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• pp.475-479
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• 2000

A possibility of the implementation of a quartz crystal sensor to the determination of chemical oxygen demand is examined by checking the electrochemical behavior of the sensor in a glucose solution. Since the surface of a quartz crystal has to be oxidized, a relatively active metal is coated on the surface of a usual 9 MHz AT-cut crystal. The electrochemical behavior is investigated by measuring the changes of current, resonant frequency and resonant resistance while a constant potential is applied. The crystal is installed in a specially designed container, and a quartz crystal analyzer is utilized to measure the frequency and resistance simultaneously. The variations of the measurements are examined at different concentrations of glucose solution, and a proper relation between the concentrations of glucose solution, and a proper relation between the concentration and the measurements is analyzed. As a result, it is found that a linear relation between the concentration of less than 900 ppm and the peak current when a constant potential of -180 mV (SSCE) is applied. The relation can be utilized for the determination of glucose concentration in sea water, and considering a direct relation between gluose concentration and chemical oxygen demand tells a possibility of the measurement of chemical oxygen demand using quartz crystal oscillators.

• Nuclear Engineering and Technology
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• 제56권2호
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• pp.419-425
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• 2024

The purpose of this study is to improve the concentration of U(VI) in carbonate solution reasonably, which to improve the application potential of the alkaline reprocessing processes. The dissolution behavior of U₃O₈ in carbonate peroxide solutions was investigated under different conditions, including pH, carbonate concentration, and solid-liquid ratio. The results showed that the dissolution rate of U₃O₈ increased with the increase of pH from 8 to 11 in the mixed carbonate solution containing 0.5 mol/L H₂O₂. The role of carbonate ions in the dissolution of U₃O₈ was further elucidated by observing the dissolution of UO₄⋅4H₂O in carbonate solutions. Furthermore, the concentration of U(VI) in 3 mol/L Na₂CO₃ solution was successfully increased to 350 g/L under ultrasonic-assisted conditions at 60 ℃ and a solid-liquid ratio at 1/2 g/mL. Meanwhile, it is suggested that increasing the concentration of carbonate ions can improve the stability of the dissolved solution containing uranyl peroxycarbonate complex.

• 한국환경과학회지
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• 제11권7호
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• pp.757-763
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• 2002

The objective of this study is to delineate removal efficiency of the Linear alkylbenzene sulfonates(LAS) in solution by $TiO_2$ photocatalytic oxidation as a function of the following different experimental conditions : initial concentration of LAS, $TiO_2$ concentration, UV wavelength and pH of the solution. It was increased with decreasing initial concentration of LAS and with decreasing pH of the solution. Removal efficiency increased with increasing $TiO_2$ concentration but was almost the same at $TiO_2$ concentration of 2 g/L and 3 g/L, i.e., for initial LAS concentration of 50 mg/L. It was removal efficiency was 85% at 150 min in the case of $TiO_2$ concentration of 0.5 g/L but 100% after 150 min in the case of $TiO_2$ concentration of 1 g/L, 100% after 110 min in the case of $TiO_2$ concentration of 2 g/L and 3 g/L. UV wavelength affection on the removal efficiency of LAS decreased in the order of 254, 312 and 365 nm as increasing wavelength. But the removal efficiency of LAS was nearly the same at UV wavelength of 254 nm and 312 nm.

• 한국표면공학회지
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• 제28권2호
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• pp.101-109
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• 1995

Electroetching rates of $FeCl_3$ solution were increased according to increasing solution temperature. Activation energy of electroetching at Be'36 and 5A/$dm^2$ condition was 28.3Kcal and also, at Be'46 and 5A/dm$^2$ condition was 33.2Kcal. At Be'36 concentration of $FeCl_3$ solution, electroetching rate were more higher than at Be'46 concentration. Surfaces of etched grooves obtained at 8A/$dm^2$ or higher current density in 46 Be' concentration of $FeCl_3$ solution were observed to be flat and smooth owing to suppressing chemical etching reaction. Distinctly etched boundaries became to be appeared at 2A/$dm^2$ in Be'41 electroetching condition by differential effects. In case of applying 8A/$dm^2$ current density to Be'46 of $FeCl_3$ solution, etching depth were 4 times and side etching were 6 times more than chemical etching case respectively.

• 한국수산과학회지
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• 제29권1호
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• pp.92-96
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• 1996

CM-chitin의 고유특성 및 유동특성을 밝혀 효과적으로 식품산업에 이용하기 위하여 CM-chitin 수용액의 유동특성 중 임계농도와 유동방정식을 조사하였다. 물에서 CM-chitin의 환원농도는 2.5이었으며, 이 때의 임계농도는 $0.8\%(w/v)$이었다. 즉 $0.8\%$ 이하의 농도에서는 분자사슬간 상호작용이 일어나지 않았으며, $0.8\%$ 이상에서 상호작용이 일어나는 것으로 나타났다. $0.5\%$ CM-chitin 용액은 전단속도가 증가하여도 점도는 일정하게 유지되는 뉴우튼 유체의 특성을 보였으며, $1.0\%$ 용액은 전단속도가 증가하면 점도가 낮아지는 의가소성 유체의 특성을 보였다. $3.0\%$ CM-chitin 수용액의 유동상수 $\eta_\infty,\;\eta_0,\;\beta$, n은 각각 $0.0908(\fallingdotseq0.1)cp$, 770cp, 0.81, 0.36이었다. 따라서 $3.0\%$ CM-chitin 수용액의 유동방정식은 $\eta=0.1+\{{770/(1+0.81D^{0.36})\}$으로 나타낼 수 있다.

• 한국항행학회논문지
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• 제26권6호
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• pp.510-515
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• 2022

본 논문에서는 마이크로리터 부피의 에탄올 수용액 농도를 검출하기 위한 마이크로스트립 패치 센서 안테나를 제안하였다. 비유전율 변화에 대한 감도를 높이기 위해 패치의 방사 모서리에 직사각형 슬롯을 추가하였다. 높은 비유전율과 높은 손실 탄젠트를 가지는 극성 액체인 에탄올 수용액을 패치에 놓으면 발생하는 낮은 입력 저항을 개선하기 위해 1/4 파장 임피던스 변환기를 50 오옴 급전선과 패치 사이에 추가하여 0.76 mm 두께의 RF-35 기판에 안테나를 제작하였다. 원통형 용기를 아크릴로 제작하여 15 마이크로리터 부피의 에탄올 수용액을 에탄올 농도 0% ~ 100%까지 20% 농도 간격으로 만들어 실험하였다. 실험 결과, 에탄올 수용액의 에탄올 농도가 0%에서 100%로 증가할 때 공진 주파수가 1.947 GHz에서 2.509 GHz로 증가하여 농도검출 센서로서의 성능을 입증하였다.

• Korean Journal of Acupuncture
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• 제17권1호
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• pp.11-17
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• 2000

금은화, 당귀, 감두를 이용하여 조제한 각각의 약침액을 이용하여 암예방효과를 살펴 보았다. 발암물질을 무독화시키는 QR 생성 유도를 생쥐의 간암세포인 Hepa1c1c7과 측정하였으며, 그 결과 금은화 약침액, 당귀 약침액, 감두약침액을 처리한 Hepa1c1c7에서 QR생성이 유도되었으며 GSH 생성을 살펴본 결과 Hepa1c1c7 세포에서 실험에 이용된 모든 생약 약침액에 의한 GSH 생성이 증가하였고, GST 생성 또한 증가하였다.

• 한국가시화정보학회지
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• 제8권4호
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• pp.38-42
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• 2010

Ion concentration polarization is an electrokinetic phenomenon which occurs in membrane systems, such as in an electrodialysis and fuel-cell system. But the phenomenon is not fully understood because hydrodynamics, electrokinetics and electrochemistry are coupled with each other. Here, we report that there occurs a change of pH value of buffer solution in concentration polarization phenomenon. To visualize the change of pH, the litmus solution which is one of the pH indicators was used. It is conjectured that the pH of solution changes because hydrogen ions were concentrated in cathodic side and hydroxide ions were concentrated in anodic side. We anticipate that this work may contribute to the fundamental understanding on the ion concentration polarization phenomenon.

• 한국환경과학회지
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• 제11권4호
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• pp.361-366
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• 2002

Several effects on Pb$^{2+}$ removal by crab shell from aqueous solution were investigated. As the increase of initial Pb$^{2+}$ concentration and decrease of initial crab shell concentration, the time required to reach an equilibrium state and the residual Pb$^{2+}$ concentration increased. In our experimental ranges, the optimum initial Pb$^{2+}$ concentration and crab shell concentration were below 103 mg/$\ell$ and over 0.5 mg/$\ell$, respectively. Also, in order to investigate the mechanism of Pb$^{2+}$ removal by crab shell in aqueous solution, the crab shell was compared with chitosan and chitin on aspects of Pb$^{2+}$ removal capacity and Pb$^{2+}$ removal rate. The Pb$^{2+}$ removal by crab shell was greater than that by chitin and chitosan. The role of chitin was not so great in Pb$^{2+}$ removal by crab shell. The Pb$^{2+}$ removal by chitosan was not exactly correlated to the molecular weight of chitosan. weight of chitosan.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1991년도 가을 학술발표회 논문집
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• pp.11-14
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• 1991

Apparent diffusion coefficients of Cl-ions through hardened cement paste(HCP), which were partly substituted blending materials, were determined. Also, pore solution was extracted from HCP which were immersed in NaCl solution, and Cl- concentration of the solution were analyzed. Partly substitution of pozzolanic materials considerably reduced the diffusion rate for Cl-ions and Cl- concentration of pore solution. Binding capacity of Cl- is related to the content of Al2O3 and pozzolanic reactivity.