• Title/Summary/Keyword: concentration measure

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Characterization of Nitrogen Gas Crossover in PEM Fuel Cell Stacks (고분자 연료전지 스택에서 질소 크로스오버 특성에 관한 연구)

  • Baik, Kyung-Don;Kim, Min-Soo
    • Proceedings of the KSME Conference
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    • 2008.11b
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    • pp.2227-2230
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    • 2008
  • Crossover of nitrogen from cathode to anode is inevitable in typical membranes used in PEM fuel cells. This crossovered nitrogen accumulates in anode recirculation system and excessive buildup of nitrogen in the recirculating anode gas lowers the hydrogen concentration and finally affects the performance of fuel cell stacks. In this study, characterization of nitrogen gas crossover was investigated in PEM fuel cell stacks. The mass spectroscopy (MS) has been applied to measure the amount of the crossovered nitrogen at the exit of anode. Results show that anode and cathode stoichiometric number ($SR_c$) have a big effect of nitrogen crossover.

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Correlation between Velocity Fluctuation and Fluctuation of Hydrogen Concentration in 2-D Air-Hydrogen Supersonic Mixing Layer

  • Sakima, Fuminori;Arai, Takakage;Edward, Shelley-R.;Mori, Yuko
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2004.03a
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    • pp.111-116
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    • 2004
  • An experiment was carried out to confirm the validity of time series evaluation of supersonic mixing condition by using catalytic reaction on a platinum wire. Geseous hydrogen was injected parallel to supersonic freestream (M$\infty$ $\approx$ 1.81) from a slit injector, which was located at backward facing step. Time series condition of supersonic mixing was evaluated by using W-type probe which has a platinum wire and reference wire (nickel wire). The evaluation was by simultaneously measuring each electric circuit which kept the temperature of wire constant. Investigations were also conducted for helium, air and no secondary injectant cases to compare with the hydrogen injectant case. The results indicated that it was possible to measure the time series behavior of air and hydrogen supersonic mixing layer or coherent motion of turbulence by using this evaluation.

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INVESTIGATION OF DRAG REDUCTION MECHANISM BY MICROBUBBLE INJECTION WITHIN A CHANNEL BOUNDARY LAYER USING PARTICLE TRACKING VELOCIMETRY

  • Hassan Yassin A.;Gutierrez-Torres C.C.
    • Nuclear Engineering and Technology
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    • v.38 no.8
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    • pp.763-778
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    • 2006
  • Injection of microbubbles within the turbulent boundary layer has been investigated for several years as a method to achieve drag reduction. However, the physical mechanism of this phenomenon is not yet fully understood. Experiments in a channel flow for single phase (water) and two phase (water and microbubbles) flows with various void fraction values are studied for a Reynolds number of 5128 based on the half height of the channel and bulk velocity. The state-of-the art Particle Tracking Velocimetry (PTV) measurement technique is used to measure the instantaneous full-field velocity components. Comparisons between turbulent statistical quantities with various values of local void fraction are presented to elucidate the influence of the microbubbles presence within the boundary layer. A decrease in the Reynolds stress distribution and turbulence production is obtained with the increase of microbubble concentration. The results obtained indicate a decorrelation of the streamwise and normal fluctuating velocities when microbubbles are injected within the boundary layer.

GC-FID Analysis of Tranylcypromine in Rat Urine (GC-FID에 의한 Rat 뇨중 Tranylcypromine의 분석)

  • 강건일;전순영
    • YAKHAK HOEJI
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    • v.29 no.5
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    • pp.260-267
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    • 1985
  • A gas chromatography with flame ionization detection was developed to measure tranylcypromine in rat urine. The method involves extraction of the drug and the internal standard, phenylpropylamine from the urine using ethyl acetate and back extraction into 0.5N $H_{2}SO_{4}$. Following final extraction using dichloromethane, both the drug and the internal standard were converted to trifluoroacetyl derivatives and analyzed using a column of 3% SE-30 on 80/100 mesh Chromosorb W(HP). A calibration curve was constructed in the range of $5~50{\mu}g$tranylcypromine sulfate in 0.5ml urine and found to be linear. The detection limit was $2{\mu}g$. The tranylcypromine could be analyzed with the percent recovery of $100.81{\pm}8.13$ (SD) ina concentration range of $8-40{\mu}g$ in 0.5ml urine. When 0.4mmol/kg dose of the drug was administered through, an oral route, excretion percent of tranylcypromine in rat urine over 36hr was found to be $11.90{\pm}6.04$ (SD) for tranyleypromine sulfate and $2.23{\pm}0.63$ (SD) for benzyl trans-2-phenylcyclopropanecarbamate.

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Micro PIV Measurement of Two-Fluid Flow with Different Refraction Indices (미소입자영상유속계를 이용한 굴절률이 다른 두 유체 유동 측정)

  • Kim, Byoung-Jae;Liu, Ying Zheng;Sung, Hyung-Jin
    • 유체기계공업학회:학술대회논문집
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    • 2003.12a
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    • pp.107-114
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    • 2003
  • The influence of property difference in refraction index on micro PIV measurement of two-fluid flow in a microchannel was analyzed. The difference of measurement planes in two fluids would bring misunderstanding of the physics. The objective-imaging system for two-fluid flow measurement was presented, and the condition for measurement of valid velocity profile across two-fluid interface was derived. A micro PIV experimental system was set up to measure two-fluid flow inside a Y-shape microchannel. Under the conditions, three cases of two-fluid flow of glycerol solutions at different concentration (${\phi}$), e.g., (${\phi}=0\;and\;{\phi}=0.2,\;{\phi}=0.1\;and\;{\phi}=0.5,\;{\phi}=0\;and\;{\phi}=0.6$, were measured. Close agreement of experimental and numerical results was found.

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A Study on Peanut Spouts Extract as the Anti-oxidant Activity and the Skin Whitening Cosmetic Ingredients (항산화 및 미백화장품 원료로서의 땅콩새싹 추출물에 관한 연구)

  • Yoon, Mi Yun
    • KSBB Journal
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    • v.31 no.1
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    • pp.14-19
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    • 2016
  • To investigate the effect of peanut sprout extract on skin care, we measured anti-oxidant activity and whitening action. As a result of measuring DPPH radical scavenging activity to examine independent anti-oxidation of peanut sprout extract, there was strongly scavenging activity. Fluorescent material DCF-DA was used to measure hydrogen peroxide created in RAW 264.7 cells, and all concentration dependently decreased ROS production. As a result of measuring nitric oxide to examine anti-inflammation of peanut sprout extract, there was strongly inhibited nitric oxide production in RAW 264.7 cells. Tyrosinase activation was found to inhibited dose-dependant. Melanin production was also prevented dose-dependant. Therefore, it is expected to be used effectively in development of functional cosmetic materials.

In Vitro Magnetometry, LDH Activity and Apoptosisas Indices of Cytotoxicity in Alveolar Macrophages Exposed to Cadmium Chloride (카드뮴에 폭로된 폐포된 폐포대식세포의 세포독성 평가를 위한 세포자계측정, LDH활성도 및 Apoptosis)

  • 조영채
    • Journal of Environmental Health Sciences
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    • v.26 no.4
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    • pp.115-121
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    • 2000
  • To evaluate the cytotoxicity of cadmium compounds, this study was conducted to measure the in vitro magnetometry, LDH release and cellular apoptosis using alveolar macrophages of hamsters. A series of magnetometric measurements in cadmium-added groups showed a significant dose-dependent decay of the relaxation curves. The LDH release rates showed a dose-dependently increasing tendency as the dose gradually increased. The positive rates of apoptosis were significantly higher in cadmium-added groups than the control groups. Conclusively, the cytotoxicity increased in a dose dependent way as the concentration of cadmium added increased, which reflected in the decay of relaxation curve in magnetometry, and increased LDH release rate and positive rate of apoptosis.

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Seismic progressive collapse assessment of 3-story RC moment resisting buildings with different levels of eccentricity in plan

  • Karimiyan, Somayyeh;Moghadam, Abdolreza S.;Vetr, Mohammad G.
    • Earthquakes and Structures
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    • v.5 no.3
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    • pp.277-296
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    • 2013
  • Margin of safety against potential of progressive collapse is among important features of a structural system. Often eccentricity in plan of a building causes concentration of damage, thus adversely affects its progressive collapse safety margin. In this paper the progressive collapse of symmetric and asymmetric 3-story reinforced concrete ordinary moment resisting frame buildings subjected to the earthquake ground motions are studied. The asymmetric buildings have 5%, 15% and 25% mass eccentricity. The distribution of the damage and spread of the collapse is investigated using nonlinear time history analyses. Results show that potential of the progressive collapse at both stiff and flexible edges of the buildings increases with increase in the level of asymmetry in buildings. It is also demonstrated that "drift" as a more easily available global response parameter is a good measure of the potential of progressive collapse rather than much difficult-to-calculate local response parameter of "number of collapse plastic hinges".

Flame Extinguishing Characteristics of Clean Gaseous Agents and Effects of Additives (가스계 청정소화약제의 소화특성과 첨가제에 따른 영향)

  • Shin, Chang-Sub;Kim, Sung-Min
    • Journal of the Korean Society of Safety
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    • v.23 no.6
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    • pp.95-99
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    • 2008
  • Halon was known as a cause of the ozone layer destruction. In 1987, it was designated as one of the ozone-layer-destroying materials in the Montreal Protocol. Therefore substitutes of Halon agent has been developed including inert gas extinguish system, which is one of the most widely used fire extinguishing system. This study intended to increase the efficiency of inert gas extinguishing agent by using inert gas additives. As IG-541 shows high extinguishing power, the experiment was performed to measure the effects of gaseous additives to it. Cup-burner fire extinguishing apparatus was used with n-Heptane fuel. Among many of pure inert gaseous agents, Helium showed the most excellent extinguishing power. When Helium was added to IG-541, fire extinguishing power was increased and the concentration of oxygen in chimney also risen. By adding Helium to IG-541, the effectiveness of inert gas fire extinguishing system is able to be increased.

Enzymatic Hydrolysis of p-Nitrophenyl Phsphoryl Derivatives by Phospholipase D

  • Cha, Joo-Yeun;Lee, Ji-Eun;Koh, Eun-Hie;Choi, Myung-Un
    • Bulletin of the Korean Chemical Society
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    • v.15 no.11
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    • pp.1001-1003
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    • 1994
  • A series of phosphodiesters of p-nitrophenyl phosphoryl derivatives were synthesized and used as a model substrate for phospholipase D (PLD). The phosphodiester substrates were synthesized from p-nitrophenyl phosphorodichloridate and corresponding alcohols with different chain lengths and polar groups. To measure the activity of PLD, either spectroscopic method for p-nitrophenol or pH-stat titration method was employed. For each substrate, effects of substrate concentration, pH, and $Ca^{2+}$ ion were examined. The kinetic parameters $V_{max}$ for the different substrates were varied depending on the chain lengths or charge of the alcohols. No calcium effect was observed in the hydrolysis of neutral and negatively charged alcohol derivatives, while positively charged choline derivative showed a strong $Ca^{2+}$ ion dependence.