• Title/Summary/Keyword: concentration measure

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Identification and Determination of Oil Pollutants Based on 3-D Fluorescence Spectrum Combined with Self-weighted Alternating Trilinear Decomposition Algorithm

  • Cheng, Pengfei;Wang, Yutian;Chen, Zhikun;Yang, Zhe
    • Journal of the Optical Society of Korea
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    • v.20 no.1
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    • pp.204-211
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    • 2016
  • Oil pollution seriously endangers the biological environment and human health. Due to the diversity of oils and the complexity of oil composition, it is of great significance to identify the oil contaminants. The 3-D fluorescence spectrum combined with a second order correction algorithm was adopted to measure an oil mixture with overlapped fluorescence spectra. The self-weighted alternating trilinear decomposition (SWATLD) is a kind of second order correction, which has developed rapidly in recent years. Micellar solutions of #0 diesel, #93 gasoline and ordinary kerosene in different concentrations were made up. The 3-D fluorescence spectra of the mixed oil solutions were measured by a FLS920 fluorescence spectrometer. The SWATLD algorithm was applied to decompose the spectrum data. The predict concentration and recovery rate obtained by the experiment show that the SWATLD algorithm has advantages of insensitivity to component number and high resolution for mixed oils.

Mechanical and Electrical Properties of Hydrate-bearing Sediments (하이드레이트 함유 퇴적물의 역학적 성질 및 지구물리 특성)

  • Lee, J.Y.;Francisca, F.;Santamarina, J.C.;Ruppel, C.
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.11a
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    • pp.594-596
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    • 2007
  • Using an oedometer cell instrumented to measure the evolution of electromagnetic properties, small strain stiffness, and temperature, we conducted consolidation tests on four types of sediments. The tested specimens include sediments with different gas hydrate saturation at four stages of loading. The test results show that the electromagnetic and mechanical properties of hydrate-bearing marine sediments are governed by the vertical effective stress, stress history, porosity, hydrate saturation, fabric, ionic concentration of the pore fluid, and temperature. The results also show that permittivity and electrical conductivity data can be combined to estimate hydrate volume fraction in laboratory sediments, methodology that might eventually be extended for estimation of hydrate concentrations in field settings.

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Performance of a direct methanol fuel cell (DMFCs)Using Nation 115 (Nafion 115를 사용한 DMFC MEA 의 성능실험)

  • Choi, Hoon;Hwang, Yong-Sheen;Cha, Suk-Won
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.11a
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    • pp.43-46
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    • 2007
  • To find out the optimum design of hydrogen storage and supply tank using Metal Hydride (briefly MH) and to make clear the performance characteristics under various conditions are our research purpose. In order to use the low-temperature exhaust heat, $LaNi_{4.7}Al_{0.3}$ which operates under the low pressure of 1MPa is chosen, and we measure the basic properties, namely density, specific heat, PCT(Pressure-Concentration-Temperature) characteristic, and effective thermal conductivity. Then, a numerical calculation model of hydrogen storage using MH alloy is suggested and this thermal diffusion equation of model is solved by the backward difference method. This calculation results rate compared with the experimental results of the systems which installed 1kg MH alloy and, it is found out that our calculation model can well predict the experimental results. By the experimental using MH alloy, it is recognized that the hydrogen flow rate can control by the step adjustment of brine temperature.

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Strain measurement in the interface between crystalline Silicon and amorphous Silicon with MEIS

  • Yongho Ha;Kim, Sehun;Kim, H.K.;D.W. Moon
    • Proceedings of the Korean Vacuum Society Conference
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    • 1999.07a
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    • pp.178-178
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    • 1999
  • Low temperature Si epitaxy can provide flexibility for a device designer to tailor or optimize the device performance. It is better method for controlling the doping thickness, concentration and profile than ion implantation and diffusion. But there is a limited growth thickness in this method. At a given temperature, the film grows epitaxially for a certain limiting thickness(hepi) and becomes amorphous. The transition from crystalline Si to amorphous Si is abrupt. In this study, Si film was deposited by ion beam sputter deposition on Si (0001) above a limiting thickness and measure the strain in the interface between crystalline Si and amorphous Si. The strain was compressive and the maximum value was about 2%.

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Study on Electrochemical Properties of TBT(Tributyltin)

  • Park, Chil-Nam;Yang, Hyo-Kyung
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • v.10 no.S_4
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    • pp.173-179
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    • 2001
  • The chemical behavior and properties of the redox state of environmental pollutants was investigated using electrochemical methods. The purpose was to measure the variations in the redox reaction of differential pulse polarograms and cyclic voltammograms. The results observed the influences on redox potential and current of various factors including concentration, temperature, salt, and pH. These were established factors as the effect of the redox reaction. It can be clearly recognized that the electrode reaction are from reversible to irreversible processes. Also, it was mixing with reaction current controlled.

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Assessment of Autoxidative Resistance for Organic Solvent by Pressure Monitoring Test

  • Kito, Hayato;Fujiwara, Shintaro;Kumasaki, Mieko;Miyake, Atsumi
    • International Journal of Safety
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    • v.9 no.1
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    • pp.43-46
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    • 2010
  • In the recycle process of organic solvent, the atmospheric oxygen can cause autoxidation and product peroxide. The time-saving method to evaluate the hazards has been required. In this study, oxygen pressure monitoring experiment was proposed as a new method to evaluate autoxidative resistances of solvents. Some of organic solvents were pressurized by oxygen and kept under isothermal condition. At the same time, the pressure in the vessel tracked. Iodometrical titration, thermal analysis and spectroscopic analysis were performed to measure peroxide concentration, the heat of reaction and chemical bonding change. From the results that THF has larger oxygen consumption rate than CPME, it is considered that autoxidative resistance of THF is lower than that of CPME. This method enables to obtain results in shorter time than other methods. These experimental results were consistent with the previous research with longer test durations [1-2].

Formation Characteristics of PM and SOF by Spray Combustion of Marine Heavy Fuel Oil

  • Kim, Houng-Soo;Murakami, T.;Nishida, Osami;Fujita, H.;Harano, W.
    • Journal of Advanced Marine Engineering and Technology
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    • v.28 no.2
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    • pp.292-299
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    • 2004
  • This study is intended to check a temperature of the flame to raise by burning A heavy oil in a boiler. to measure the concentration of DS and SOF after collecting the PM(Particulate Matters). and to analyze the components ingredients of SOF by G.C Mass for presupposing the generation of particulate matters(soot). It is thought that the methyl(CH3) of the cyclic compound is changed to the materials of 2 cycles and 3 cycles after becoming CH by dehydrogenation and also mixing with the CH of a chain compound. form H-$\cdot$C=C$\cdot$-H that is mentioned before. in order to become Polycyclic Aromatic Hydrocarbon.

Development of an Analytical Approach to Measure Volatile Sulfur Compounds Using a Non-Cryogenic Preconcentration Method (비냉각형 선농축 방식에 의한 대기 중 휘발성 황화합물의 분석방법 개발)

  • 김기현;이강웅
    • Journal of Korean Society for Atmospheric Environment
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    • v.13 no.5
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    • pp.355-360
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    • 1997
  • The atmospheric concentration of dimethylsulfide (DMS), known as the predominant volatile organic. sulfur compound, is determined at subnanogram level by a combined application of non-cryogenic preconcentration method and gas chromatography with flame photometric detection (GC/FPD). The volatile DMS in air is preconcentrated using a trapping tube containing adsorbent like Molecular Sieve 5A (or gold-coated sands). The tube is then connected to the GC/FPD system via a six-way rotary valve, thermally desorbed at 40$0^{\circ}C$, separated on OV101 column, and detected by a flame photometric detector. The DMS peak elutes at about 2.5 mins and is integrated electronically. The analytical precision, if expressed in terms of relative standard error, is around 5%. The detection limit of our GC/FPD system is ca 1 ng of DMS. Details of our analytical system are presented.

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A Study on the Possibility of Pattern Design Using CAD System (With concentration on the change of coat basic pattern) (CAD System을 이용한 패턴디자인설계 활용가능성에 관한 연구(I)-Coat 원형을 중심으로-)

  • 김옥경
    • Journal of the Korean Society of Costume
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    • v.20
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    • pp.49-62
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    • 1993
  • The purpose of this research was to utilize of Pattern Design System(P.D.S) by using AM-300 The conclusion were like these : 1. A coat of basic pattern was selected by design sketch. 2. The basic pattern was input into computer by digitizing. 3. The basic pattern was change into designed shape by using various skills. This system were enabled to draw straight lines, curves, delete lines, sections of lines, extend lines, cut pattern into sections, measure line or section reproduce whole pattern shape of section, rotate and mirror pattern and complete patterns. 4. Automatic grading of finished master pattern have been developed by creation and modification of grading rules of basic pattern. 5. Production pattern added seam allowance, not-ches was generated by P.D.S menu option. 6. Finished pattern design was plotted out 100% and 20% size by AM-300 Plotter. This results will be the basic materials to develop the CAD SYSTEM if some problems were improve. Furthermore, the utilization of P.D.S is expected to be developing in pattern making process.

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The Effect of Bluff-Body Shapes on the Drop Size and Flame Temperature (Bluff-Body형상이 연료액적크기와 화염온도에 미치는 영향)

  • Hwang, Sang-Ho;Cha, Keun-Jong;Kim, Duck-Jool
    • Proceedings of the KSME Conference
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    • 2000.04b
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    • pp.937-942
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    • 2000
  • The characteristics of spray combustion and dropsize of spray through twin-fluid atomizer was experimentally investigated. The distribution of flame temperature have an effect on the generation of NOx. To investigate there effects, flame temperature with different spray shape was observed. The spray shape was varied by various bluff-bodys. Mean temperature were measured by thermocouple respectively, and NOx concentration was measure by NOx analyser. Distribution of droplet sizes were measured by PMAS. The result showed that the flame with wide distribution has lower temperature and lower NOx emission compared with narrow.

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