• Title/Summary/Keyword: concentration equation equation

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An investigation on the in si.tu measurement of the oil-concentration

  • Kim, Chang-Nyeun;Park, Young-Moo
    • International Journal of Air-Conditioning and Refrigeration
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    • v.8 no.2
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    • pp.80-88
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    • 2000
  • In order to predict thermodynamic performance of refrigeration system, it is required to know the oil concentration of the refrigerant/oil mixture. The current method is to extract the working mixture and then to measure the oil weight. In this study, oil concentration is measured in si.tu way without any extraction of the working fluid. Based on the measurement, a working equation is presented as follows, C=a +b x t +c x $t^2$ +(d + e x t +f x $t^2$) x SG. C is oil concentration, t is temperature($^{\circ}C). SG Is specific gravity of mixture and a~f is coefficients The oil concentration ranges over 0~l2 wt% and the temperature ranges over 20~50$^{\circ}C. The specific gravity and temperature are measured using the on-line densimeter and thermometer. This working equation enables to predict the oil concentration without any extraction of the mixture. This equation can be applied for R-12/Naphthenic oil and R-134a/P0E oil liquid mixtures.

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A Study on the Development of Air Pollution Dispersion Model for Personal Computer (特定地域의 大氣汚染 擴散모델 開發에 關한 硏究)

  • 송기유;임흥재;윤명희
    • Journal of Korean Society for Atmospheric Environment
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    • v.2 no.2
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    • pp.19-30
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    • 1986
  • This study was performed to develop a long-term air pollution dispersion model based on CDM program for use in the personal computer. The model CDM.PC, developmented for use of this study, simplified the plum equation of point pollution source in a windy state and sindless state. We used the classified 8 class stability, 16 wind direction and 4 class wind speed for the computer input climatological data. The plum rise equation is applied for CONCAWE's equation above 2,000 Kcal/sec of the exhaust calorie and Moses-Carson's equation below 2,000Kcal/sec at windy state, and Brigg's equation at calm. The time required is 200 minutes for drawing the air pollution contour for treating ten stacks under the above-stated conditions. It is the weakness of using personal computer that the operation time is longer than a large-size computer. But it strength is that the personal computer is used widely. To compare the treatment results of CDM.PC with TCM, we comfirmed that the shape of $SO_2$ pollution contour is similar but the concentration distribution is quite different because of characteristics of each models. Estimated and measured $SO_2$ concentration were similar, namely, Cest/Cob ratio of CDM.PC and TCM were respectively $0.96 \pm 0.25 (mean\pmS.D)$ and $1.08\pm0.26$.

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Comparison of linear and non-linear equation for the calibration of roxithromycin analysis using liquid chromatography/mass spectrometry

  • Lim, Jong-Hwan;Yun, Hyo-In
    • Korean Journal of Veterinary Research
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    • v.50 no.1
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    • pp.11-17
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    • 2010
  • Linear and non-linear regressions were used to derive the calibration function for the measurement of roxithromycin plasma concentration. Their results were compared with weighted least squares regression by usual weight factors. In this paper the performance of a non-linear calibration equation with the capacity to account empirically for the curvature, y = ax$^{b}$ + c (b $\neq$ 1) is compared with the commonly used linear equation, y = ax + b, as well as the quadratic equation, y = ax$^{2}$+ bx + c. In the calibration curve (range of 0.01 to 10 ${\mu}g/mL$) of roxithromycin, both heteroscedasticity and nonlinearity were present therefore linear least squares regression methods could result in large errors in the determination of roxithromycin concentration. By the non-linear and weighted least squares regression, the accuracy of the analytical method was improved at the lower end of the calibration curve. This study suggests that the non-linear calibration equation should be considered when a curve is required to be fitted to low dose calibration data which exhibit slight curvature.

Thermal Behavior of Critical Micelle Concentration from the Standpoint of Flory-Huggins Model

  • Lim, Kyung-Hee
    • Bulletin of the Korean Chemical Society
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    • v.30 no.9
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    • pp.2001-2006
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    • 2009
  • Temperature dependence of the critical micelle concentration (CMC), $x_{CMC}$, in micellization can be described by ln $x_{CMC}$ = A + BT + C lnT + D/T, which has been derived statistical-mechanically. Here A, B, C, and D are fitting parameters. The equation fits the CMC data better than conventionally used polynomial equations of temperature. Moreover, it yields the unique(exponent) value of 2 when the CMC is expressed in a power-law form. This finding is quite significant, because it may point to the universality of the thermal behavior of CMC. Hence, in this article, the nature of the equation ln $x_{CMC}$ = A + BT + C lnT + D/T is examined from a lattice-theory point of view through the Flory-Huggins model. It is found that a linear behavior of heat capacity change of micellization is responsible for the CMC equation of temperature.

Simulations of Pollutant Dispersion over Rectangular Building (사각 건물 주위의 오염물 확산에 대한 수치해석적 연구)

  • Hong B. Y.;Park C. G.
    • Journal of computational fluids engineering
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    • v.6 no.4
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    • pp.1-7
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    • 2001
  • Wind flow perturbations, recirculations and turbulence generated by buildings often dominate air pollutant distributions around buildings. This paper describes dispersion of contaminants in the vicinity of a building by solving the concentration equation based on previously simulated wind flow field. Turbulence closure is achieved by using the standard k-ε two-equation model. The paper shows application of the CIP method for solving a species concentration equation of contaminant gas around a rectangular building for two different sources under conditions of neutral atmospheric stratification. Results have been compared to the experimental data and the previous numerical results by hybrid scheme. The computational results of concentration profiles by the CIP method agree well with experimental data.

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Numerical Analysis of Flow and Pollutant Dispersion over 2-D Bell Shaped Hills

  • Jung, Young-Rae;Park, Keun;Park, Warn-Gyu;Park, Ok-Hyun
    • Journal of Mechanical Science and Technology
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    • v.17 no.7
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    • pp.1054-1062
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    • 2003
  • The numerical simulations of flow and pollutant particle dispersion are described for two-dimensional bell shaped hills with various aspect ratios. The Reynolds-averaged incompressible Navier-Stokes equations with low Reynolds number $\kappa$-$\varepsilon$ turbulent model are used to simulate the flowfield. The gradient diffusion equation is used to solve the pollutant dispersion field. The code was validated by comparison of velocity, turbulent kinetic energy, Reynolds shear stress, speed-up ratio, and ground level concentration with experimental and numerical data. Good agreement has been achieved and it has been found that the pollutant dispersion pattern and ground level concentration have been strongly influenced by the hill shape and aspect ratio, as well as the location and height of the source.

Numerical Simulations of Using CIP Method for Dispersion of Pollutants around a Building (CIP 방법을 이용한 건물 주위의 오염물 확산에 대한 수치해석)

  • Hong, Bo-Young;Park, Chan-Guk
    • Proceedings of the KSME Conference
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    • 2001.11b
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    • pp.723-728
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    • 2001
  • Wind flow perturbations, recirculations and turbulence generated by buildings often dominate air pollutant distributions around buildings. This paper describes dispersion of contaminants in the vicinity of a building by solving the concentration equation based on previously simulated wind flow field. Turbulence closure is achieved by using the standard k-e two-equation model. The paper shows application of the CIP method for solving a species concentration equation of contaminant gas around a rectangular building for two different sources under conditions of neutral atmospheric stratification. Results have been compared to the experimental data and the previous numerical results by hybrid scheme. The computational results of concentration profiles by the CIP method agree well with experimental data.

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Characteristics of Enzyme Sensors using Carboxylated PVC for Immobilizing Penicillinase (Carboxylated PVC에 페니실리나제를 고정한 효소 센서의 특성)

  • Kim, Ki-Myo;Kim, Young-Hak;Lee, Eun-Yup;Hur, Moon-Hye;Ahn, Moon-Kyu
    • YAKHAK HOEJI
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    • v.40 no.1
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    • pp.72-77
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    • 1996
  • Penicillin sensor was manufactured by immobillizing penicillinase with glutaraldehyde on the $H^+$-selective membrane based on PVC-COOH-TDDA. This membrane was not inter fered by $K^+$ ion in Pc-G potassium salt. When enzyme was immobilized with glutaraldehyde, the PVC-COOH matrix was more effective than PVC matrix. Calibration curve calculated from Nernst equation was not linear. But potential was relative to concentration of Pc-G. And maximal potentiometric velocity was also relative to concentration of Pc-G. Therefore, it may be applied to Michaelis-Menten equation. The penicillin sensor was useful for determination of Pc-G at concentration of 0.1~10mM level.

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Description of Temperature Dependence of Critical Micelle Concentration

  • Kim, Hong-Un;Lim, Kyung-Hee
    • Bulletin of the Korean Chemical Society
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    • v.24 no.10
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    • pp.1449-1454
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    • 2003
  • A new equation has been derived on the basis of ${\delta}G^o$ = -RT lnK, linear behavior of the enthalpy of micellization with temperature, and the Gibbs-Helmholtz relation. It describes correctly the dependence of critical micelle concentration $(X_{CMC})$ on temperature and has yielded excellent fitting results for various surfactant systems. The new equation results in the linear behavior of the entropy of micellization with temperature and accounts for the compensation phenomena observed for the micellization in aqueous solutions, along with the linear dependence of the enthalpy of micellization on temperature. These results imply that the new equation of $X_{CMC}(T)$ accounts for the temperature dependence of CMC correctly.

The Effect of Predictive Reaeration Estimation Equation on Stream Water Quality Modeling

  • Kim, Hyung-Joong
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.39 no.2
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    • pp.97-103
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    • 1997
  • DO concentration in the aquatic system is important for the water quality management perspective. Water quality model uses available reaeration coefficient (K2) estimation equations in calculating DO, however, they might include inevitable uncertainty that the model output can be less reliable. In this study, the calibrated QUAL2E model for the Passaic River in New Jersey, U.S., was used to examine the effect of K2 estimation equation on the output DO concentration of the river. The model was run with six commonly used equations separately with all the other conditions remained same. The result showed that the output DO concentration profiles varied widely with different equations, and maximum difference was 4.96 mg/L for the same location which is unacceptably large. It implies that the development of reliable equation is required for proper water quality management. The unreliable model output can lead to a wrong decision in water quality management such as unnecessarily high or too low treatment of wastewater, which will cause serious effect on the community economically and socially in either case. Generating more reliable model output with slight investment to develop a site specific K$_2$ equation can improve the decision making process significantly and is highly recommended.