• Title/Summary/Keyword: compounding

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Characterization and Fatigue Life Evaluation of Rubber/Clay Nanocomposites (고무-점토 나노복합체 물성 및 피로내구성 평가)

  • Woo, Chang-Su;Park, Hyun-Sung;Joe, Deug-Hwan;Jun, Young-Sig
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.35 no.10
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    • pp.1199-1203
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    • 2011
  • Nanocomposites were prepared through the compounding of rubber and clay. Measurements of the static and dynamic mechanical properties of different compositions over a temperature range $70-100^{\circ}C$ showed that the mechanical properties of these rubber/clay nanocomposites are superior to those of existing rubber materials. In this study, by using the parameter of the maximum Green.Lagrange strain appearing at certain locations, the relationship between fatigue life and maximum Green.Lagrange strain, and the correlations between test-piece tests and bench tests of actual rubber components are proved. In order to predict the fatigue life of rubber components at the design stage, a simple procedure of life prediction is suggested. The predicted fatigue lives of the rubber engine mounts agree fairly well with the fatigue lives determined experimentally.

$\alpha$ Scaling Parameter Optimization On Watermarking Using Autostereogram (오토스테레오그램을 이용한 워터마킹에서 $\alpha$스켈링 파라미터 최적화)

  • 허덕규;이인정;김성옥
    • Journal of Internet Computing and Services
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    • v.2 no.4
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    • pp.101-109
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    • 2001
  • In recent year, the use of digital picture information and general picture information has been increased, However, numerous copyright infringement and pirate copy of picture information through Internet and CD-ROM happen very often, As a result, several methods of watermarking have been presented to solve and verify distortion of the original data, In addition, watermark data have been suggested to resolve the vastness of the original data, Watermarking methods are often used to protect the right of ownership of a copyright, However, these Watermarking methods have brought the obscurity of recognition caused by the complexity of verification procedure and the increase of magnitude computation occurrence, This paper mainly mentions about the local optimization of scaling parameter, the maximization of hiding of Watermark information and maximization of watermark information in case of restoration that determine the amount of inserted information which is used for preventing distortion and transformation of the original data caused by insertion and hiding of Watermark information on compounding Autostereogram into JPEG picture information.

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Performance of Electric Double Layers Capacitor Using Activated Carbon Materials from Rice Husk as Electrodes

  • Nguyen, Tuan Dung;Ryu, Jae Kyung;Bramhe, Sachin N.;Kim, Taik-Nam
    • Korean Journal of Materials Research
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    • v.23 no.11
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    • pp.643-648
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    • 2013
  • Activated carbon (AC) was synthesized from rice husks using the chemical activation method with KOH, NaOH, a combination of (NaOH + $Na_2CO_3$), and a combination of (KOH + $K_2CO_3$) as the chemical activating reagents. The activated carbon with the highest surface area (around $2000m^2/g$) and high porosity, which allows the absorption of a large number of ions, was applied as electrode material in electric double layer capacitors (EDLCs). The AC for EDLC electrodes is required to have a high surface area and an optimal pore size distribution; these are important to attain high specific capacitance of the EDLC electrodes. The electrodes were fabricated by compounding the rice husk activated carbons with super-P and mixed with polyvinylidene difluoride (PVDF) at a weight ratio of 83:10:7. AC electrodes and nickel foams were assembled with potassium hydroxide (KOH) solution as the electrolyte. Electrochemical measurements were carried out with a three electrode cell using 6 M KOH as electrolyte and Hg/HgO as the reference electrode. The specific capacitance strongly depends on the pore structure; the highest specific capacitance was 179 F/g, obtained for the AC with the highest specific surface area. Additionally, different activation times, levels of heating, and chemical reagents were used to compare and determine the optimal parameters for obtaining high surface area of the activated carbon.

Preparation and Characteristics of Polyurethane Hybrid Sealant Modified with Polydimethylsiloxane (Polydimethylsiloxnae 변성 Polyurethane Hybrid Sealant의 제조와 그 특성)

  • Kang, Doo-Whan;Park, Seung-Woo
    • Polymer(Korea)
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    • v.35 no.5
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    • pp.488-492
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    • 2011
  • Three isocyanatopropyldimethoxysilylpolydimethylsiloxanes(IDMSi-PDMS) were synthesised from the reaction of isocyanatopropyltrimethoxysilane with monohydroxyl group termainated PDMS having different molecular weight($M_n$=5000, 10000, and 20000). Then PDMS modified polyurethane hybrid elastomer(PSMPH) were prepared from the reaction of IDMSi-PDMS with ${\alpha}$, ${\omega}$-hydroxyl group terminated polyurethane. PSMPH sealant was prepared by compounding PSMPH elastomer with additives such as plasticizer, adhesion promoter, crosslinking agent, vicosity increasing agent, inorganic filler, and catalyst at room temperature under nitrogen atmosphere. The methoxy group in the PSMPH sealant should be crosslinked with the hydroxyl group in the building stone or moisture by typical sol-gel reaction. The adhesive strength of the sealant having PDMS of $M_n$=5000 showed 40.28 kg of maxium load and 20.14 kg of break load. The shrinkage rate of the sealant having PDMS of $M_n$=20000 was 5.7% as the best result. Also, their skin over time, slump, oil content after 8 days under oil soaked paper and alkaline resistance characteristics show good results.

Properties of PP/MWCNT Nanocomposite Using Pellet-Shaped MWCNT (펠렛형 MWCNT를 사용한 PP/MWCNT 나노복합체 물성 연구)

  • Jeong, Dong-Seok;Nam, Byeong-Uk
    • Polymer(Korea)
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    • v.35 no.1
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    • pp.17-22
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    • 2011
  • Polypropylene/multi-walled carbon nanotube(PP/MWCNT) composites along with various MWCNT contents up to 20 wt% were prepared by a twin screw extruder. Nanocomposites having 20 wt% MWCNT as a master batch(M/B) were diluted with PP by way of melt compounding. The electrical/thermal conductivity, morphology, thermal/viscoelastic/mechanical properties were investigated with the variation of MWCNT contents. Also, we compared some properties between 1-step PP/MWCNT and the diluted PP/MWCNT composites. The percolation threshold of electrical and thermal conductivity was measured at about 3 wt% MWCNT. And conductivity of diluted PP/MWCNT composites were superior to those of PP/MWCNT composites. The non-isothermal crystallization temperature and thermal decomposition temperature appeared at higher temperatures with increasing MWCNT contents. Morphology showed that length of MWCNT in diluted PP/MWCNT composites was shortened by twice melt blending, which contributed to improve the tensile strength of PP/MWCNT composites.

Compounding and Test of Gasket Rubber for Fuel Cell Stack Application (연료전지 스택 가스켓용 고무재료의 제조와 평가)

  • Hur, Byung-Ki;Kang, Dong-Gug;Kim, Hye-Young;Seo, Kwan-Ho;Park, Lee-Soon
    • Elastomers and Composites
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    • v.42 no.4
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    • pp.232-237
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    • 2007
  • We examined the properties of compound and made compound of the optimum state using the properties of each material to evaluate suitability of FKM, VMQ, EPDM, NBR with gasket for fuel cell which is in general use with the material of gasket. It could be found from the compound made with setting the optimum state that NBR is worse than FKM in the chemical property of matter for a long term, and VMQ is worse than FKM in the elution of a metal ion, and EPDM is worse than FKM in the permeability of gas. As a result of leak evaluation of gasket for fuel cell with using FKM, it appeared leak in short time when contracting pressure is getting lower and sealing pressure is getting higher. And as a result of the life prediction with using Arrhenius model, we could predict that it is possible to continuously drive for 60,000 hours.

New Engineering Techniques for Carbon Master Batch (탄소 마스터배치를 위한 새로운 엔지니어링 기술)

  • Pyo, Sang-Gil;Kang, Chang-Gi;Kim, Ki-Seok;Park, Soo-Jin
    • Elastomers and Composites
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    • v.48 no.2
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    • pp.125-132
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    • 2013
  • In this work, we have discussed new engineering systems for preparing carbon master batch composed by carbon black and various organic compounds. In general, polymer resin, which applied for automobile tire, household items, and various industry items, is used with the fillers including carbon black and silica to control the color or properties. Domestic part and material industry has been remarkably developed in that the development of materials including the compounding of raw materials. Meanwhile, the engineering technique for mass production has not reached to a requirement of industry due to slow technique development and high dependence on foreign. Thus, we will focus on the introduction of new engineering technique developed by domestic company for preparing carbon master batch.

THE PHYSICAL PROPERTIES AND HEALING EFFECT OF CALCIUM SULFATE-HYDROXYAPATITE COMPOUND ON ROOT PERFORATION (Calcium sulfate-Hydroxyapatite 혼합재의 물성 및 치근천공 치유효과에 관한 연구)

  • Lee, Seung-Jong;Kim, Kyoung-Nam
    • Restorative Dentistry and Endodontics
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    • v.22 no.2
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    • pp.739-750
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    • 1997
  • Treatment of root perforation elicits special considerations due to its blood-contaminated circumstances. It is known that conventional dental restorative materials are all leaking. Calcium sulfate is the material which react with water to become chemically set. This study, therefore, was performed to develop a new compound containing calcium sulfate and to evaluate its physical and biological characteristics. Three materials were used, IRM, calcium sulfate, calcium sulfate-hydroxyapatite compound. The composition of the calcium sulfate-hydroxyapatite compound was basically 50 % of calcium sulfate and 50 % of hydroxyapatite mixed with guajacol. The materials were mixed in conventional way and underwent four physical test procedures, setting time, solubility test, compressive strength, and marginal leakage test. All materials were evaluated under the scanning electron microscope to examine the marginal sealing ability. Animal experiment was also performed to test the materials' tissue response. Twenty-four dog's premolars were tested with either furcation perforations or apical retro-fillings. From the results, we found that calcium sulfate possess the good marginal sealing ability. However, calcium sulfate creates many voids which is caused by crystal thrusting action when it reacts with water. It seemed that the voids caused disintegration of the material which eventually lead to tissue reaction. By compounding calcium sulfate and hydroxyapatite, we were able to obtain the better physical properties but it showed larger marginal gap between the material and the root surface. Within the six weeks observation period, both IRM and calcium sulfate-hydroxyapatite compound showed good tissue responses in animal experiment. It is concluded that calcium sulfate would be the material of choice in root perforation repair, but the physical property needs to be further improved.

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Effect of Kenaf Fiber Loading on the Properties of Natural Fiber/Natural Rubber Composites (천연섬유/천연고무 복합재료의 특성에 미치는 Kenaf 섬유함량의 영향)

  • Cho, Yi-Seok;Cho, Dong-Hwan
    • Elastomers and Composites
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    • v.46 no.3
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    • pp.186-194
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    • 2011
  • Natural fiber/natural rubber composites were fabricated by uniformly compounding natural rubber and cellulose- based natural fiber kenaf and then by compression molding. The effect of kenaf fiber content on their vulcanization behavior, hardness, tensile properties, tear strength and static and dynamic properties was investigated. The contents of kenaf fiber in the composites were 0, 5, 10, 15, and 20 phr, compared to natural rubber and additives. The result indicated that various properties of natural rubber depended on the kenaf fiber content. With increasing kenaf fiber content, the torque for vulcanization of natural rubber was increased whereas the vulcanization time was reduced as well. The hardness, tensile modulus and tear strength of kenaf/natural rubber composites were gradually decreased with the fiber content whereas the tensile strength and elongation at break were decreased. Also, with increasing the kenaf fiber content the dynamic property of natural rubber was changed more greatly than the static property. The loss factor, which is closely related with the damping or absorption of the energy given to natural rubber, was proportionally increased with the fiber content.

A Study on Rheological Properties for Preparing Flow Mark Free PP Compounds (흐름자국이 없는 PP 복합소재 제조를 위한 유변학적 특성 연구)

  • Lee, Yong-Hee;Nam, Byeong-Uk;Lim, Jae-Gon;Choi, Chi-Hoon
    • Elastomers and Composites
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    • v.44 no.2
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    • pp.156-163
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    • 2009
  • Our objective is to increase the flowability of Polypropylene(PP) compounds and achieve flow mark free surface in injection molded specimen. We have investigated flowabilities of PP compounds which were composed of PP, rubber, talc, and trace amount of additives. Flowability measurement was performed with four types PPs of which molecular weight distributions(MWD) and melt indexes(MI) were different. Rheological properties of the PP compounding materials, such as spiral flow(SF) length, MI, and shear viscosity, were evaluated. When PP with the broad MWD was used, there were remarkable cases where the spiral flow length of low MI PP compound was longer than that of higher MI PP compound. The PP compound having low MI but broad MWD PP has more flowability than the compound with only high MI.