• 제목/요약/키워드: compound particle

검색결과 190건 처리시간 0.029초

Nb2O5-TiO2 화합물을 이용한 염료감응형 태양전지의 성능 향상 (The Enhancement of the Performance of Dye Sensitized Solar Cells Using Nb2O5-TiO2 Compound)

  • 최석원;서현웅;손민규;김수경;홍나영;김희제;김종락
    • 전기학회논문지
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    • 제61권8호
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    • pp.1153-1158
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    • 2012
  • Niobium oxide ($Nb_2O_5$) has a strong chemical coherence and good electrical conductivity. Therefore, this material is helpful to enhance the performance of the dye sensitized solar cells (DSC) by improving the electron mobility. In this study, $Nb_2O_5$ was mixed with $TiO_2$ and this compound was applied to the DSC to improve its performance. As a result, the current density of the DSC using the $Nb_2O_5-TiO_2$ compound on the photoelectrode was increased, because the internal resistance concerned to the electron transfer in the photoelectrode of DSC was decreased. However, large amount of the $Nb_2O_5$ induces the decrease of the efficiency of the DSC because the surface area to attach dye molecules is decreased due to the large particle of $Nb_2O_5$. Therefore, it is important to optimize the mixture ratio of the $Nb_2O_5-TiO_2$ compound for maximizing the performance of the DSC. Finally, the most optimum performance of the DSC was shown in case of the $Nb_2O_5$ concentration of 10 wt% of the $Nb_2O_5-TiO_2$ compound.

균일침전법에 의한 균일입도 초미분 이트륨화합물의 제조에 관한 연구 I. $Y(NO_3)_3$ 농도의 영향 (Preparation of Monodispersed Colloidal Particles of Yttrium Compound by Homogeneous Precipitation. I.Effect of $Y(NO_3)_3$ Concentration)

  • 권영식;김연식
    • 한국세라믹학회지
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    • 제33권5호
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    • pp.495-506
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    • 1996
  • Monodispersed colloidaly yttria(Y2O3) can be used in a variety of applications such as phosphors. IR transparent materials and fine ceramics. For preparing monodispersed yttria homogeneous precipitation has been regarded as a fovorable method that is monodispersed yttria can be obtained through calcining monodispersed colloidal compound of yttrium (eg:Y(OH)CO3.nH2O)which can be prepared by homogeneous precipitation with urea. It is however still required to find out the quantitative effects of important variables of precipitation such as concentration of yttrium and urea reaction temperature and initial pH of reactant even though homogeneous precipitation of Y3+ with urea has been studied extensively. Among the effects of these variables we investiga-ted 1) the effect of yttrium concentration on the shape and size of precipitate and the reation rate 2) range of yttrium concentration required to make monodispersed colloidal particles 3) the reason for limited concentra-tion range of yttrium and 4) the effect of ultrasonic radiation on the limited concentration.

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인 변성 폴리우레탄 에멀젼의 합성에 관한 연구 (Synthesis of Polyurethane Emulsion Modified with Phosphorus Compounds)

  • 우종표;조선영
    • 한국응용과학기술학회지
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    • 제20권4호
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    • pp.275-282
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    • 2003
  • Aqueous polyurethane dispersion was synthesized using phosphorus compound which received significant attention for the replacement of halogenated flame retardants. In this study, polyols which have phosphorus moity in their structural unit were synthesized by two-step polycondensation reaction using dimethyl phenylphosphonate, ethylene glycols. adipic acid, and 1,4-butanediol. In the next step, polyurethane dispersion was prepared using these polyols, isophorone diisocyanate with dimethyl propionic acid. The particle size of polyurethane latex was reduced from 347 nm to 240 nm with increasing DMPA content. It was observed that the LOI values of prepared coatings increased from 27% to 35% with increasing phosphorus content.

감성물질의 마이크로캡슐화에 의한 감성기능 섬유의 개발(III) -방향 기능 섬유- (Development of Susceptible Functional Fibers Using Microencapsulation of Susceptible Materials(III) ―Fragrant Functional Fibers―)

  • Kim, Moon Sik;Park, Soo Min
    • 한국염색가공학회지
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    • 제8권4호
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    • pp.11-18
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    • 1996
  • Natural functional compound in the textile finishing for health and amenity using fragrant material have been applied by microencapsulation method. The microcapsules containing fragrant materials as functional compound were produced by in situ polymerization using urea-formaldehyde prepolymer. The average diameter of microcapsules is 2.75$\mu$ and particle size ranges over 0.5~10$\mu$. Fragment material is extracted approximatly proportioned from microcapsule at room temperature. The adsorption of microcapsule was improved by pretreatment of cationic agent. Fragrant materials in microcapsule was revealed to have long release time.

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Mössbauer Analysis of Cations on Iron Oxyhydroxide Formation

  • Oh, Sei-Jin;Kwon, Soon-Ju
    • 한국자기학회지
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    • 제15권2호
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    • pp.85-91
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    • 2005
  • Effect of different cations to the formation of iron oxyhydroxide was studied using $M\ddot{o}ssbauer$ spectroscopy, X-ray diffraction (XRD) and BET. Redox Potential and pH were measured for the determination of the internal reaction rate, as well. The phases of iron oxyhydroxide could not be the same with each other, due to the presence of different cations in solution. Although the oxyhydroxide compound was composed of the same phases, the fraction of each phase was different from each other. The internal reaction rate was varied by the substitution of cation. It could be a cause of the different phase and particle size of oxyhydroxide compound.

시멘트의 수화특성에 대한 유·무기 복합 나노실리카의 영향 (Influence of Nano Silica Dispersant on Hydration Properties of Cementitious Materials)

  • 강현주;송명신;박종헌;송수재
    • 한국세라믹학회지
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    • 제48권6호
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    • pp.510-515
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    • 2011
  • In this study, as a material used to replace silica fumes for high strength concrete, nano-silica compound with organic functional group for dispersion and with inorganic silica group that can cause a pozzolan reaction is synthesized, These nano silica compound is divided into IC, which is nano size $SiO_2$ with irregularly combined hydroxyl group and carboxyl group, and RC, which is nano size $SiO_2$ with regularly combined hydroxyl group and carboxyl group. The effects of these nano silica compound on the hydration of cement are reviewed. As a result, all of synthesized nano-silica compounds have excellent dispersion on the cement flow, we think that dispersion property is the effect of air entraining by synthesized nano-silica compounds. The result of the microstructure observation showed that the particle size of the synthesized nano-silica is smaller than silica fume and spread evenly among the cement particles. In initial The phenomenon of strength decreasing occurred due to delayed hydration reaction by the synthesized nano-silica with carboxyl(-COOH) and hydroxyl(-OH) functional group.

한국어의 형태소해석 (Morphological Analysis of the Korean Language)

  • 이수현;;이주근
    • 대한전자공학회논문지
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    • 제26권4호
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    • pp.53-61
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    • 1989
  • 한국어의 구문 및 의미해석등에 필요한 정보를 도출하기 위한 입력분의 형태해석에 대하여 기술한다. 명사구에서 명사와 조사를 분리하고, 복합명사의 분리점을 선택하는 조건을 규정하며, 변형된 복합명사를 처리하는 규칙을 표시한다. 그리고 규칙동사에서 어간과 어미를 분리하고, 변칙용언과 음운축약 등을 효과적으로 처리하기 위한 논리표현 형식을 제안한다. 이 논리표현은 해석규칙과 속성값으로 구성한다. 명사사전의 중복을 배제하기 위하여 "명사형 하다" 동사의 분리 처리와 Q parameter 도입에 의한 "이다"의 처리방법을 보이고, 또한 부정문의 처리형식도 유도하여 복합술부의 형태소와 기본형식을 제시한다.

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FORMULATION AND STABILITY TEST OF ANTIAGING CREAM CONTAINING METHANOL FRACTION OIL OF PANGIUM EDULE.REINW. AS A RADICAL SCAVENGER AGENT

  • Djajadisastra, J.;Anwar, E.;Milani, E.
    • 대한화장품학회:학술대회논문집
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    • 대한화장품학회 2003년도 IFSCC Conference Proceeding Book II
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    • pp.303-306
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    • 2003
  • Indonesia is a tropical country having a temperature range of 25-35$^{\circ}C$ which can affect the skin and causes damages like aging. This aging process is due, at least, to free radical reactions. For this reason, many attempts had been done to find out creams containing natural antioxidant compound which have a potential of free radical scavenger. Kluwek, a fermented form of foot ball fruit or picung (Pangium edule.Reinw), had been proved to contain antioxidant compound in its methanol fraction oil to which antiaging cream was formulated. Stability evaluation was conducted for cream with Kluwek oil compared to base cream, including organoleptic (colour and odour), pH, viscosity, particle size, centrifugation test and flow characteristics either in room temperature (27$^{\circ}C$) or stress condition (4$^{\circ}C$ and 5$0^{\circ}C$) for 8 weeks continuously, and six times cycling test at 4$^{\circ}C$ and 5$0^{\circ}C$ every 24 hours. The results showed that cream with Kluwek oil and base cream were stable at temperature 27 and 4$^{\circ}C$, cycling test and centrifugation test, but not stable at 5$0^{\circ}C$. Free radical evaluation was done by Electron Spin Resonance and the result showed that cream with Kluwek oil had less free radicals compared to base cream.

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한국산 Zeolite의 필터첨가제로서의 흡착효과에 관하여 (A Study on the Adsorption Effect of Korean zeolite "Clinoptilolite" as Cigarette Cavity Filter Additive.)

  • 양광규;송치현;김찬호
    • 한국연초학회지
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    • 제2권1호
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    • pp.8-16
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    • 1980
  • Zeolite의 일종인 clinoptilolite를 담배필터 첨가제로 활용하는 연구를 하였다. 입자크기 30 $\pm$ 5 A.S.T.M. mesh의 clinoptilolite와 charcoal 1 : 1 (V/V)로 혼합하여 삼중필터의 cavity부분에 충진했을 때, 1. Cellulose acetate필터에 비하여 nicotine 35%, T.P..M.22%를 감소시켰으며, 2. Gas phase중 n-amyl alcohol등 aliphatic compound와 furan등 cyclic compound를 cellulose acetate filter에 비하여 60$\pm$ 5%를 감소시켰다. 3. Charcoal의 removal efficiency는 40-50% clinoptilolite의 10-20%에 비하여 큰 값이였지만 charcoal은 분자량이 큰 aromatic compound의 removal efficiency가 50$\pm$5%로서 aliphatic compound의 removal efficiency 40: 5%보다 큰 값이였음에 비하여 clinoptilolite는 alcohol과 ketone계열의 분자갹이 작은 화합물의 removal efficiency가 15-20%로 cyclic compounds의 removal efficiency 10-15%에 비하여 보다 큰 값이었다. 이 두물질의 gas phase성분의 흡착기능은 상호 보완적임을 알 수 있었다.

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PSS-PT-PZ 초전형 적외선 센서의 잡음특성 개선에 관한 연구 (A Study on the Improvement of Noise Properties of the PSS-PT-PZ Pyroelectric Infrared Sensor)

  • 우승일;이성갑;이영희;박창엽
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1992년도 하계학술대회 논문집 B
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    • pp.759-761
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    • 1992
  • $0.10Pb(Sb_{1/2}Sn_{1/2})O_3-0.25PbTiO_3-0.65PbZrO_3+MnO_2(0.18mol%)$, NiO(0.15mol%) temary compound ceramics won fabricated by the mixed-oxide method. Noise properties of the pyroelectric infrared sensor were investigated with particle size of the raw materials and gain size of the specimens. Particle size were decreased and sintered density, voltage resposivity were increased with increasing the ball-mill times. The specimen ball-milled for a 80[hr] showed a good pop-corn noise properties.

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