• Title/Summary/Keyword: composition gradient

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Deposition of SiC/C functionally gradient materials by chemical vapour deposition (화학기상증착법(CVD)에 의한 SiC/C 경사기능재료의 증착)

  • Yootaek Kim;Nam Hun Kim;Keun Ho Orr
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.4 no.3
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    • pp.262-275
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    • 1994
  • SiC/C functionally gradient materials (FGM) were deposited on the graphite substrate by the chemical vapor deposition method. The best deposition conditions of SiC/C FGM were $1300^{\circ}C, H_2/[SiCl_4+CH_4]=10, CH_4/[$SiCl_4+CH_4]=0.5-0.6$. Despite of discontinuous input gas ratio change, the FGM of which composition was continuously changed could be obtained and continuous structural change without definite interfaces was confirmed by the SEM observation.

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A size-dependent quasi-3D model for wave dispersion analysis of FG nanoplates

  • Karami, Behrouz;Janghorban, Maziar;Shahsavari, Davood;Tounsi, Abdelouahed
    • Steel and Composite Structures
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    • v.28 no.1
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    • pp.99-110
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    • 2018
  • In this paper, a new size-dependent quasi-3D plate theory is presented for wave dispersion analysis of functionally graded nanoplates while resting on an elastic foundation and under the hygrothermaal environment. This quasi-3D plate theory considers both thickness stretching influences and shear deformation with the variations of displacements in the thickness direction as a parabolic function. Moreover, the stress-free boundary conditions on both sides of the plate are satisfied without using a shear correction factor. This theory includes five independent unknowns with results in only five governing equations. Size effects are obtained via a higher-order nonlocal strain gradient theory of elasticity. A variational approach is adopted to owning the governing equations employing Hamilton's principle. Solving analytically via Fourier series, these equations gives wave frequencies and phase velocities as a function of wave numbers. The validity of the present results is examined by comparing them with those of the known data in the literature. Parametric studies are conducted for material composition, size dependency, two parametric elastic foundation, temperature and moisture differences, and wave number. Some conclusions are drawn from the parametric studies with respect to the wave characteristics.

Accuracy Evaluation of Machine Learning Model for Concrete Aging Prediction due to Thermal Effect and Carbonation (콘크리트 탄산화 및 열효과에 의한 경년열화 예측을 위한 기계학습 모델의 정확성 검토)

  • Kim, Hyun-Su
    • Journal of Korean Association for Spatial Structures
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    • v.23 no.4
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    • pp.81-88
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    • 2023
  • Numerous factors contribute to the deterioration of reinforced concrete structures. Elevated temperatures significantly alter the composition of the concrete ingredients, consequently diminishing the concrete's strength properties. With the escalation of global CO2 levels, the carbonation of concrete structures has emerged as a critical challenge, substantially affecting concrete durability research. Assessing and predicting concrete degradation due to thermal effects and carbonation are crucial yet intricate tasks. To address this, multiple prediction models for concrete carbonation and compressive strength under thermal impact have been developed. This study employs seven machine learning algorithms-specifically, multiple linear regression, decision trees, random forest, support vector machines, k-nearest neighbors, artificial neural networks, and extreme gradient boosting algorithms-to formulate predictive models for concrete carbonation and thermal impact. Two distinct datasets, derived from reported experimental studies, were utilized for training these predictive models. Performance evaluation relied on metrics like root mean square error, mean square error, mean absolute error, and coefficient of determination. The optimization of hyperparameters was achieved through k-fold cross-validation and grid search techniques. The analytical outcomes demonstrate that neural networks and extreme gradient boosting algorithms outshine the remaining five machine learning approaches, showcasing outstanding predictive performance for concrete carbonation and thermal effect modeling.

Effects of Acidification on the Changes of Microbial Diversity in Aquatic Microcosms

  • Young-Beom Ahn;Hong-Bum Cho;Byung Re Min;Yong-Keel Choi
    • Animal cells and systems
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    • v.3 no.2
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    • pp.153-159
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    • 1999
  • In an artificial pH-gradient batch culture system, the effects of acidification on the species composition of a heterotrophic bacterial community were analyzed. As a result of this study, it was found that total bacteria numbers were not affected by acidification and that the population of hetero-trophic bacteria decreased as pH became lower. The heterotrophic bacteria isolated from the entire pH gradient were 12 genera and 22 species. Among them, 64% were gram negative and 36% were gram positive bacteria. As pH decreased, the distribution rate of gram negative bacteria increased while that of gram positive bacteria decreased. The diversity of genera decreased from 13 to 5 as pH decreased from 7 to 3. The G+C content of all of the 202 isolated strains varied from 22.8 to 77.0%, and increased in interspecies of same genus as pH decreased. As a result of clustering analysis, the diversity index of species ranged from 1.13 to 2.37, and it had lower indices as pH decreased. In order to evaluate the diversity of numbers of sample of different size, a rarefaction method was used to analyze the expected number of species appearance according to pH. The statistical significance of species diversity was verified by the fact that the number decreased at lower pH.

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Free vibration analysis of FG nanoplate with poriferous imperfection in hygrothermal environment

  • Karami, Behrouz;Shahsavari, Davood;Janghorban, Maziar;Li, Li
    • Structural Engineering and Mechanics
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    • v.73 no.2
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    • pp.191-207
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    • 2020
  • This study aims at investigating the size-dependent free vibration of porous nanoplates when exposed to hygrothermal environment and rested on Kerr foundation. Based on the modified power-law model, material properties of porous functionally graded (FG) nanoplates are supposed to change continuously along the thickness direction. The generalized nonlocal strain gradient elasticity theory incorporating three scale factors (i.e. lower- and higher-order nonlocal parameters, strain gradient length scale parameter), is employed to expand the assumption of second shear deformation theory (SSDT) for considering the small size effect on plates. The governing equations are obtained based on Hamilton's principle and then the equations are solved using an analytical method. The elastic Kerr foundation, as a highly effected foundation type, is adopted to capture the foundation effects. Three different patterns of porosity (namely, even, uneven and logarithmic-uneven porosities) are also considered to fill some gaps of porosity impact. A comparative study is given by using various structural models to show the effect of material composition, porosity distribution, temperature and moisture differences, size dependency and elastic Kerr foundation on the size-dependent free vibration of porous nanoplates. Results show a significant change in higher-order frequencies due to small scale parameters, which could be due to the size effect mechanisms. Furthermore, Porosities inside of the material properties often present a stiffness softening effect on the vibration frequency of FG nanoplates.

Response of Old-field Plant Community to an Experimental Nitrogen Gradient (질소 시비 구배에 따른 묵밭의 식물 군집 반응)

  • Lee, Kyu-Song;Joon-Ho Kim
    • The Korean Journal of Ecology
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    • v.19 no.4
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    • pp.341-351
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    • 1996
  • In order to elucidate the differences in early successional development among similary aged old-fields having different soil nitrogen (N), caused by the land use history before at abandonment, the response of plant community along an experimental nitrogen gradient (control plot (No), plot NI with 5.8g $N/m^2$, plot N2 with 11.7g $N/m^2$ and plot N3 with 23.3g $N/m^2$) was investigated in a five-year-old abandoned field. Although the N content in soil among treatments was similar at the end of the growing season, N concentrations in plant tissue increased with the amount of N supplied. These results suggest that almost all the N contained in N-enriched soil might be absorbed by plants during the growing season after N supply. Vegetation tended to grow vigorously by nitrogen supply, and the standing biomass increased significantly in plots NI and N2 . Species richness of plants, especially of annuals and perennials, was more reduced than the control plot, and the species diversity was also reduced by N supply. The importance value (IV) of species by N supply differed in each species along the position on the successional sere: Artemisia princeps var. orientalis as the dominant species in this old-field decreased slightly; annuals as the earlier successional species decreased clearly along nitrogen gardients; Erigeron annuals as the earlier successional species and as a strong competitor with Artemisia princeps var. orientalis had the highest IV by small N supply; Miscanthus sinensis and Rubus crataegifolius as the later successional species increased by large N supply. These results suggest that old-fields with high soil N might show the structural and functional characteristics of the earlier successional stages, but community composition in those old-fields might be changed more quickly from the sarlier successional species than the later successional species.

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Gradient Structures and Surface Composition of Polypropylene/Ethylene-Propylene Rubber Blends (폴리프로필렌/에틸렌-프로필렌 고무 블렌드 경사구조 및 표면조성)

  • Kim, Seog Je;Lee, Sung-Goo;Lee, Jae Heung;Choi, Kil-Yeong
    • Journal of Adhesion and Interface
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    • v.2 no.4
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    • pp.24-31
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    • 2001
  • Polypropylenes(PP) with different melt index values were mixed with ethylene-propylene rubber(EPR) or ethylene-propylene diene monomer rubber(EPDM) and an ethylene copolymer containing carboxylic acid group in a twin screw extruder. Then test specimens were prepared from the pellets of the blends with an injection molding machine. The mechanical properties and morphology of fractured surfaces were measured. Relative peak intensities of carboxylic acid group on the specimen surface were measured with an attennuated total reflection infrared spectrometer (ATR-IR) and compared with each other. The blend specimens were found to have the gradient morphology of rubber domains in PP matrix in the core region and PP skin layer. The blends containing PP of higher melt index showed greater content of ethylene copolymer containing carboxylic acid on the surface when the relative peak intensities of ATR-IR for carboxylic acid were compared. As the melt index values were increased, the decrease tendency in mechanical propeties such as tensile strength and impact strength was more significant for PP/EPR blends than PP/EPDM blends.

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Shift in benthic diatom community structure and salinity thresholds in a hypersaline environment of solar saltern, Korea

  • Bae, Hanna;Park, Jinsoon;Ahn, Hyojin;Khim, Jong Seong
    • ALGAE
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    • v.35 no.4
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    • pp.361-373
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    • 2020
  • The community dynamics of benthic diatoms in the hypersaline environment are investigated to advance our understanding how salinity impacts marine life. Diatoms were sampled in the two salterns encompassing salt Ponds, ditches, and seawater reservoirs (n = 11), along the salinity gradient (max = 324 psu), and nearby tidal flats (n = 2). The floral assemblages and distributions across sites and stations showed great variations, with a total of 169 identified taxa. First, not surprisingly, higher diversity of benthic diatoms was found at natural tidal flats than salterns. The saltern diatoms generally showed salinity dependent distributions with distinct spatial changes in species composition and dominant taxa. Biota-environment and principal component analysis confirmed that salinity, mud content, and total nitrogen were key factors influencing the overall benthic community structure. Some dominant species, e.g., Nitzschia scalpelliformis and Achnanthes sp. 1, showed salinity tolerance / preference. The number of diatom species at salinity of >100 psu reduced over half and no diatoms were found at maximum salinity of 324 psu. The highest salinity for the observed live diatoms was 205 psu, however, a simple regression indicated a theoretical salinity threshold of ~300 psu on the survival. Finally, the indicator species were identified along the salinity gradient in salterns as well as natural tidal flats. Overall, high species numbers, varying taxa, and euryhaline distributions of saltern diatoms collectively reflected a dynamic saltern ecosystem. The present study would provide backgrounds for biodiversity monitoring of ecologically important microalgal producers in some unique hypersaline environment, and elsewhere.

Effects of Acidification on the Species Composition and the Changes of Extracelluar Enzymes of Heterotrophic Bacterial Community (수계종속 영양세균 군집의 종조성 및 세포외 효소의 변화에 미치는 산성화의 영향)

  • Choi, Yong-Keel;Han, Myung-Soo;Kim, Sewha;Lee, Kyung;Yoo, Kwang-Il
    • Korean Journal of Environmental Biology
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    • v.20 no.1
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    • pp.85-90
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    • 2002
  • In an artificial pH-gradient batch culture system, the author analyzed the effects of acidification on the species composition of heterotrophic bacteria. As the result of this study, it was found that the numbers of total bacteria were not affected by acidification and that the population size of heterotrophic bacteria decreased as pH became lower. The heterotrophic bacteria isolated from all of the pH gradient were 12 genera and 22 species, and among them, gram negative and gram positive bacteria were 04% and 30%, respectively. As pH decreased, the distribution rate of gram negative bacteria increased while that of gram positive bacteria decreased. Regarding to distribution rate of genuses in each pH gradient, 13 genuses appeared at pH 7 while only 5 genuses appeared at pH 3, which means that the diversity of genera decrease as pH decreased. The activities of extracellular enzyme showed the ranges of $0.008-0.292\;\mu{M}\ell^{-1}\;hr^{-1}$ in bioreactor system. The enzymatic activities decreased rapidly below pH 5 and then sustained 5-38% at the lower pH values.

Floristic composition and species richness of soil seed bank in three abandoned rice paddies along a seral gradient in Gwangneung Forest Biosphere Reserve, South Korea

  • Cho, Yong-Chan;Lee, Seon-Mi;Lee, Chang-Seok
    • Journal of Ecology and Environment
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    • v.42 no.3
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    • pp.90-102
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    • 2018
  • Background: We sought to understand the relationship between the seed bank and vegetation in abandoned rice paddies in South Korea, in order to guide management of these sites. We investigated the floristic composition and species richness of the soil seed bank and ground vegetation in former paddies along three seral gradients (wet meadow, young forest, and mature forest) in Gwangneung Forest Biosphere Reserve. Results: Seed bank samples contained 59 species, of which the dominant families were Cyperaceae, Gramineae, and Polygonaceae. Species richness and seedling density (59 taxa and 19,121 germinants from all samples) were high. Carex spp. (11, 921 germinants) were the dominant taxa. The species composition in the seed bank changed gradually as the land transitioned from wet meadow to mature forest. Sørensen's index of similarity between above- and below-ground vegetation was 29.3% for wet meadow, 10.8% for young forest, and 2.1% for mature forest. Germinant density also declined, with 10, 256 germinants for wet meadow, 6445 germinants for young forest, and 2420 germinants for mature forest. Conclusions: Changes in aboveground environment and life history traits such as amphicarpic plants, likely affect the composition of soil seed bank species. Abandoned paddy fields may be good sites for restoration of wetland forest and conservation of wetland habitat. Some intervention may be required to promote the recovery of a natural species assemblage.