• Title/Summary/Keyword: composite sol

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Industry-University Cooperation Research Activities Through Idea Factory (Optimized Modeling in Butterfly Valve Disk by Creative Selection in Material) (Idea Factory를 통한 산학 협력 연구 활동 (소재의 적절한 선정을 통한 버터플라이 밸브 디스크의 최적화 모델링))

  • Kim, Yun-Hae;Park, Chang-Wook;Bae, Chang-Won;Kim, Han-Sol;Jung, Min-Kyo
    • Journal of Engineering Education Research
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    • v.19 no.6
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    • pp.44-48
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    • 2016
  • This research is one of the Industry-University cooperation in idea factory of Korea Maritime and Ocean University. Idea factory of Korea Maritime and Ocean University is trying to train creative talented students and discover ingenious ideas. The contents are consisted of the possibility for the replacement of a metal valve disk to composite valve disk in butterfly valve based on the diversification. Purpose in this study is to predict failure field by each fly by appling Tsai-Wu Failure Index.

A Study on $TiO_2$/Nafion composite membrane in PEMFC (고분자 전해질 연료전지에서 $TiO_2$-Nafion 혼합막에 관한 연구)

  • Kim, Mirrim;Kim, Taeyoung;Kim, Sungsoo;Min, Byongjun;Cho, Sungyong
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.88.2-88.2
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    • 2011
  • Proton exchange memb rane fuel cell has been considered one of the next generation power source for electric vehicles due to high power density and low emissions. $TiO_2$/Nafion composite was prepared by the in-situ sol-gel method. The electrochemical characteristics of the $TiO_2$-Nafion composite membrane were evaluated by current-voltage and impedance of the membrane eletrode assembly in a single Proton exchange membrane fuel cell (PEMFC).

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Photocatalytic and Hydrophilic Properties or $TiO_2$/$Fe_2O_3$ Composite Films

  • Liu, Q.J.;L, Q.;Wu, X.H.;Zhang, G.Q.;Gao, Z.Q.;Chen, G.X.
    • Journal of Korean Vacuum Science & Technology
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    • v.6 no.1
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    • pp.40-42
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    • 2002
  • TiO$_2$/Fe$_2$O$_3$composite thin films were prepared on common glass substrates by sol-gel processing and dip-drawing method. The effect of Fe$_2$O$_3$content on the photocatalytic and hydrophilic properties of composite films was studied. The results indicate that the photocatalytic activities of composite TiO$_2$films are superior to that of pure TiO$_2$film, and the film containing 0.5% Fe$_2$O$_3$has the best photocatalytic activity. The hydrophilicity is difference with variant Fe$_2$O$_3$content, the films containing 0.05% ~0.1% Fe$_2$O$_3$have the best hydrophilicity and their contact angles are 0。.

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Preparation and Permeation Characteristics of PTMSP-PDMS-Silica/PEI Composite Membranes (PTMSP-PDMS-Silica/PEI 복합막의 제조 및 투과특성)

  • Lee, Hyun-Kyung;Hong, Se-Lyung
    • Membrane Journal
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    • v.18 no.2
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    • pp.146-156
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    • 2008
  • In this study, PTMSP of high permeability and high molecular weight was synthesized, and PTMSP-PDMS graft copolymer was synthesized from poly [1-(trimethylsily)propyne] (PTMSP) and hydroxy-terminated poly(dimethylsiloxane) (PDMS). The PTMSP-PDMS-silica composites were prepared by the addition of 15, 30, or 50 wt% tetraethoxysilane (TEOS) to PTMSP-PDMS graft copolymer by sol-gel process. To investigate the physico-chemical characteristics of PTMSP-PDMS-silica/PEI composite membranes, the analytical methods such as $^1H$-NMR, FT-IR, TGA, XPS, GPC, and SEM have been utilized. The gas permeability and selectivity properties of $H_2,\;O_2,\;N_2,\;CO_2,\;CH_4,\;n-C_4H_{10}$, were evaluated. Permeability of the composite membranes increased as TEOS content and pressure increased. Selectivity of $H_2,\;O_2,\;N_2,\;CO_2,\;CH_4,\;and\;n-C_4H_{10}$, showed the maximum value at 30 wt% of TEOS content and decreased thereafter.

Fabrication and microstructure of the Fe doped $TiO_{2}$ composite membranes with ultrafine pores (미세기공을 가지는 철이 첨가된 티타니아 복합여과막 제조 및 미세구조)

  • Dong-Sik Bae;Kyong-Sop Han;Sang-Hael Choi
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.6 no.3
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    • pp.463-470
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    • 1996
  • Ceramic membrane consisting of an ${\alpha}-Al_{2}O_{3}$ support and Fe doped $TiO_{2}$ top layer was prepared by the sol-gel method. The supported Fe doped $TiO_{2}$ top layer was made by dip coating the support in a mixed sol. The microstructure of the composite membranes was studied by SEM after calcination at $550~850^{\circ}C$. After sintering at $650^{\circ}C$ for 1 hr., the average particle diameter of the Fe doped $TiO_{2}$ top layer was ~40 nm. The supported Fe doped $TiO_{2}$ composite membranes exhibited much higher heat resistance than the $TiO_{2}$ membrane. The Fe doped $TiO_{2}$ composite membrane retained a crack-free microstructure and narrow particle size distribution even after calcination up to $650^{\circ}C$.

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Characterization of SPAES Composite Membrane Using Silane Based Inorganics (실란계 복합화 무기물을 이용한 SPAES 복합막의 특성평가)

  • Woo, Chang Hwa;Kim, Deuk Ju;Nam, Sang Yong
    • Membrane Journal
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    • v.25 no.5
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    • pp.456-463
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    • 2015
  • In this study, we synthesize novel silane based inorganics for preparation of the polymer electrolyte membrane with high proton conductivity under high temperature condition and developed membranes are characterized. SPAES, hydrocarbon based polymer are synthesized and used as main polymeric material. We used sol-gel method to prepare inorganic material with high performance using silica, phosphate and zirconium. Three types of inorganics were prepared by control of the mole ration of each component. As a result of EDX analysis, the inorganic materials are well dispersed in the polymer membrane. The water uptake of the composite membrane is increased by introduction of the hydrophilic inorganic material in the membrane. When the content of the zirconium in the membrane is increased, the proton conductivity of the composite membrane shows the higher value than pure SPAES membrane at the high temperature. And the silica based inorganics effect to increase the proton conductivity under low temperature condition.