• Title/Summary/Keyword: composite method

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Development of Graphene Nanocomposite Membrane Using Layer-by-layer Technique for Desalination (다층박막적층법을 이용한 담수화용 그래핀 나노복합체 분리막 개발)

  • Yu, Hye-Weon;Song, Jun-Ho;Kim, Chang-Min;Yang, Euntae;Kim, In S.
    • Membrane Journal
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    • v.28 no.1
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    • pp.75-82
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    • 2018
  • Forward osmosis (FO) desalination system has been highlighted to improve the energy efficiency and drive down the carbon footprint of current reverse osmosis (RO) desalination technology. To improve the trade-off between water flux and salt rejection of thin film composite (TFC) desalination membrane, thin film nanocomposite membranes (TFN), in which nanomaterials as a filler are embeded within a polymeric matrix, are being explored to tailor the separation performance and add new functionality to membranes for water purification applications. The objective of this article is to develop a graphene nanocomposite membrane with high performance of water selective permeability (high water flux, high salt rejection, and low reverse solute diffusion) as a next-generation FO desalination membrane. For advances in fabrication of graphene oxide (GO) membranes, layer-by-layer (LBL) technique was used to control the desirable structure, alignment, and chemical functionality that can lead to ultrahigh-permeability membranes due to highly selective transport of water molecules. In this study, the GO nanocomposite membrane fabricated by LBL dip coating method showed high water flux ($J_w/{\Delta}{\pi}=2.51LMH/bar$), water selectivity ($J_w/J_s=8.3L/g$), and salt rejection (99.5%) as well as high stability in aqueous solution and under FO operation condition.

A Study on the Microstructure and Properties of Y-BA-Cu-O/Ag composite High $T_{c}$ Superconductor prepared by Sinter-forging Process (Sinter forging으로 제조한 Y-BA-Cu-O/Ag 고온 초전도 복합체의 미세조직과 특성)

  • Park, Jong-Hyeon;Kim, Byeong-Cheol;Song, Jin-Tae
    • Korean Journal of Materials Research
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    • v.4 no.1
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    • pp.37-43
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    • 1994
  • Y-Ra-Cu-0 oxide superconductors were fabricated by the sinter-forging method to make the critical current density improve through controlling of microstructure and crystal texture. The grain alignment of oxide superconductor was formed by the sinter-forging process and it's c-axis orientation was parallel to the press direction.The orientation factor of texture increased with sinking temperature and pressure, and also grain alignment was improved by the addition of Ag. As for the sinterforged Y-Ba-Cu-O/Ag sample, the $T_c$(on-set) was not almost varied with the sinter-forging temperature, but $T_c\;^{zero}$ decreased more or less at high sinter-forging temperatures. In addition, it was observed that added-Ag was mainly distributed along the grain boundar~es in the (123) matrix, resulting in the densification of microstructure. From these results, i t was thought that the improvement of $J_c$ over 2000A/$\textrm{cm}^2$ was attributed to the texture, densification of microstructure, and (123) grain growth due to the Ag addition.

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The Effects of Insoluble Polymers on Water Stability of Carbon Fiber Reinforced Polymer-MDF Cementitious Composites (불용성 폴리머가 탄소섬유 보강 Polymer-MDF 시멘트 복합재료의 기계적 특성에 미치는 영향)

  • 김태진;박춘근
    • Composites Research
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    • v.12 no.3
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    • pp.84-90
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    • 1999
  • High alumina cement(HAC) and polyvinyl alcohol(PVA) based macro-defect-free(MDF) cement composites were reinforced using short carbon fibers, 3mm in length, 1-4% in weight fraction and insoluble polymers such as polyurethane, epoxy, phenol resin, in order to increase mechanical properties and water stability. The specimens were manufactured by the low heat-press(warmpress) method. In addition, the interface and the cross-linking reaction of cement and polymers was also studied by the SEM and TEM. Flexural strength of HAC/PVA based MDF cementitious composites was proportionally decreased with increasing fiber contents due to the undensified structure around fibers. The flexural strength of insoluble polymer added specimen was decreased with increasing fiber contents, while water stability was dramatically improved. Epoxy resin added specimen showed the highest strength with increasing fiber contents, compared with other specimens. The water stability of fiber content 4% added specimen immersed in water presented about 95%, 87% at 3 and 7 days immersed in water, respectively. The interfacial adhesive strength of fiber-matrix was very much improved due to cross linking reaction of polymer and metal ions of cement. Tensile strength of insoluble polymers added composites as linearly increased with increasing the fiber contents. The epoxy resin added specimen also showed highest tensile strength. The 4% fiber added specimen presented 30~80% higher strength than controlled specimen.

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A Study on the Lightweight Design of Hybrid Modular Carbody Structures Made of Sandwich Composites and Aluminum Extrusions Using Optimum Analysis Method (최적화 해석기법을 이용한 샌드위치 복합재와 알루미늄 압출재 하이브리드 모듈화 차체구조물의 경량 설계 연구)

  • Jang, Hyung-Jin;Shin, Kwang-Bok;Han, Sung-Ho
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.36 no.11
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    • pp.1335-1343
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    • 2012
  • In this study, the lightweight modular design of hybrid railway carbody structures made of sandwich composites and aluminum extrusions was investigated by using topology and size optimization techniques. The topology optimum design was used to select the best material for parts of the carbody structure at the initial design stage, and then, the size optimum design was used to find the optimal design parameters of hybrid carbody structures using first-order and sub-problem methods. Through the topology optimization analysis, it was found that aluminum extrusions were suitable for primary members such as the underframe and lower side panel module to improve the stiffness and manufacturability of the carbody structures, and sandwich composites were appropriate for secondary members such as the roof and middle side panel module to minimize its weight. Furthermore, the results obtained by size optimization analysis showed that the weight of hybrid carbody structures composed of aluminum extrusions and sandwich composites could be reduced by a maximum of approximately 17.7% in comparison with carbody structures made of only sandwich composites.

A study on the curing characteristics of multi-concentrating UV-LED Curable Coating (다중 집광성 UV-LED 경화형 코팅의 경화특성에 관한 연구)

  • Jung, Chan-Gwon;Kim, Beom-Su;Park, Dae-Hee
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.10
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    • pp.339-345
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    • 2018
  • We investigated the curing properties of cured coatings for a multi-focal UV-LED. The coatings are for LEDs that operate at multiple UV wavelengths, unlike conventional single-wavelength UV-LEDs. Using UV-LED light sources with wavelengths of 365, 395, 420, and 450 nm, we analyzed the optical characteristics such as the direction of light flux and light source. We also analyzed the curing characteristics at each UV-LED wavelength to optimize the LED for composite wavelengths. The curing performance state was predicted through computer simulation for when the multiple wavelengths of UV light sources are superimposed, and then actual LEDs were designed and fabricated. To improve the internal high-speed curing, a multi-spot module was fabricated, in which each LED is condensed, and multiple wavelengths are synthesized and condensed at the same position. The adhesive strength, surface hardness, and internal hardness of the curing agent were tested by varying the wavelength combination conditions. The surface hardening and internal hardening were compared and analyzed using a hardness tester and FT-IR analyzer. As a result, the characteristics of the surface and internal hardness were improved by a multi-spot method in which four wavelengths were overlapped in a UV-LED rather than a single wavelength.

Numerical study on structural reinforced effects of concrete lining by spray-applied waterproofing membrane (차수용 박층 멤브레인 설치에 따른 콘크리트 라이닝의 구조적 보강효과에 관한 수치해석 연구)

  • Lee, Chulho;Lee, Kicheol;Kim, Dongwook;Choi, Soon-Wook;Kang, Tae-Ho;Chang, Soo-Ho
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.19 no.3
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    • pp.551-565
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    • 2017
  • A spray-applied waterproofing membrane which consists of polymers has a relatively higher constructability and adhesion than the conventional sheet-type waterproofing materials. Additionally, the spray-applied waterproofing membrane generally shows a waterproofing ability as a composite structure with shotcrete or concrete lining. Because its purpose is waterproofing at the structure, structural effects were not well reported than waterproofing abilities. In this study, structural effects of the membrane-attached concrete lining were evaluated using 3-point bending test by the numerical method. From the analysis, a load-displacement behavior of the concrete lining and fracturing energy after yielding were compared with various conditions. Consequently, concrete lining with spray-applied waterproofing membrane shows higher flexural strength and fracturing energy than the single-layer concrete lining.

Procuring the Fire Resistance Performance and Structure of Non-Refractory Coating CFT with Using the Corrugate-rib (Corrugate-rib를 활용한 무내화피복 CFT공법의 구조 및 내화성능 확보)

  • Lee, Dong-Oun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.11
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    • pp.747-754
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    • 2017
  • The Concrete-Filled Tube (CFT) system was developed for its excellent structural performance, such as its good stiffness, stress and ductility, which is derived from the mechanical advantages of its composite structure. However, it is known that the flat type of reinforcing plates need stiffeners placed at a certain distance from each other to avoid buckling failure, which increases the cost accordingly. This paper investigates the contribution of the rib elements placed inside the steel tube for the purpose of increasing the bond strength between the steel and concrete and fire performance with no additional protection. The test results also demonstrate the effectiveness of the corrugated rib's shape against fire. The results of this study showed that the buckling prevention and fire resistance performance criteria were satisfied by the application of the inner surface attachment rib, due to the resulting increase in the strength of the CFT column. Therefore, it is considered that the CFT method using the corrugated rib structure reinforcement developed through this study satisfies the structural and fire resistance performance criteria without the need for a refractory coating. Future studies will be needed to make the process efficient and economical for factory production.

Internal Defection Evaluation of Spot Weld Part and Carbon Composite using the Non-contact Air-coupled Ultrasonic Transducer Method (비접촉 초음파 탐상기법을 이용한 스폿용접부 및 탄소복합체의 내부 결함평가)

  • Kwak, Nam-Su;Lee, Seung-Chul
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.11
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    • pp.6432-6439
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    • 2014
  • The NAUT (Non-contact Air coupled Ultrasonic Testing) technique is one of the ultrasonic testing methods that enables non-contact ultrasonic testing by compensating for the energy loss caused by the difference in acoustic impedance of air with an ultrasonic pulser receiver, PRE-AMP and high-sensitivity transducer. As the NAUT is performed in a state of steady ultrasonic transmission and reception, testing can be performed on materials of high or low temperatures or specimens with a rough surface or narrow part, which could not have been tested using the conventional contact-type testing technique. For this study, the internal defects of spot weld, which are often applied to auto parts, and CFRP parts, were tested to determine if it is practical to make the NAUT technique commercial. As the spot welded part had a high ultrasonic transmissivity, the result was shown as red. On the other hand, the part with an internal defect had a layer of air and low transmissivity, which was shown as blue. In addition, depending on the PRF (Pulse Repetition Frequency), an important factor that determines the measurement speed, the color sharpness showed differences. With the images obtained from CFRP specimens or an imaging device, it was possible to identify the shape, size and position of the internal defect within a short period of time. In this paper, it was confirmed in the above-described experiment that both internal defect detection and image processing of the defect could be possible using the NAUT technique. Moreover, it was possible to apply NAUT to the detection of internal defects in the spot welded parts or in CFRP parts, and commercialize its practical application to various fields.

Computational estimation of the earthquake response for fibre reinforced concrete rectangular columns

  • Liu, Chanjuan;Wu, Xinling;Wakil, Karzan;Jermsittiparsert, Kittisak;Ho, Lanh Si;Alabduljabbar, Hisham;Alaskar, Abdulaziz;Alrshoudi, Fahed;Alyousef, Rayed;Mohamed, Abdeliazim Mustafa
    • Steel and Composite Structures
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    • v.34 no.5
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    • pp.743-767
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    • 2020
  • Due to the impressive flexural performance, enhanced compressive strength and more constrained crack propagation, Fibre-reinforced concrete (FRC) have been widely employed in the construction application. Majority of experimental studies have focused on the seismic behavior of FRC columns. Based on the valid experimental data obtained from the previous studies, the current study has evaluated the seismic response and compressive strength of FRC rectangular columns while following hybrid metaheuristic techniques. Due to the non-linearity of seismic data, Adaptive neuro-fuzzy inference system (ANFIS) has been incorporated with metaheuristic algorithms. 317 different datasets from FRC column tests has been applied as one database in order to determine the most influential factor on the ultimate strengths of FRC rectangular columns subjected to the simulated seismic loading. ANFIS has been used with the incorporation of Particle Swarm Optimization (PSO) and Genetic algorithm (GA). For the analysis of the attained results, Extreme learning machine (ELM) as an authentic prediction method has been concurrently used. The variable selection procedure is to choose the most dominant parameters affecting the ultimate strengths of FRC rectangular columns subjected to simulated seismic loading. Accordingly, the results have shown that ANFIS-PSO has successfully predicted the seismic lateral load with R2 = 0.857 and 0.902 for the test and train phase, respectively, nominated as the lateral load prediction estimator. On the other hand, in case of compressive strength prediction, ELM is to predict the compressive strength with R2 = 0.657 and 0.862 for test and train phase, respectively. The results have shown that the seismic lateral force trend is more predictable than the compressive strength of FRC rectangular columns, in which the best results belong to the lateral force prediction. Compressive strength prediction has illustrated a significant deviation above 40 Mpa which could be related to the considerable non-linearity and possible empirical shortcomings. Finally, employing ANFIS-GA and ANFIS-PSO techniques to evaluate the seismic response of FRC are a promising reliable approach to be replaced for high cost and time-consuming experimental tests.

Improvement of Removal Characteristics of Uranium by the Immobilization of Diphosil Powder onto Alginate Bed (다이포실 분말수지의 비드화에 의한 우라늄 제거특성 개선)

  • Kim Kil-Jeong;Shon Jong-Sik;Hong Kwon-Pyo
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.4 no.2
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    • pp.133-138
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    • 2006
  • Chemical wastes containing small amounts of uranium can not be disposed of them after treatment as an industrial waste, because the uranium concentration in the final dry cake exceeds the exemption level. Especially for the removal of uranium in this study, the method for immobilizing Diphosil powder within alginate beads is adopted to make a bead form from a powdered resin. Sodium alginate bead itself showed a capability to uptake uranium to above 60%, but the value was decreased to below 30% after equilibrium. The adsorption rate of uranium increased with the increasing content of Diphosil in the sodium alginate bead. Diphosil resin itself showed very fast uptake of uranium from early stages, and then the rates were leveled off. Diphosil bead showed an improved capability to uptake uranium considering the pure Diphosil content in the composite bead, and provide a considerable potential for further applications of a continuous process by using Diphosil as a bead form.

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