• Title/Summary/Keyword: composite fibers

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Microstructural changes of polyacrylonitrile-based carbon fibers (T300 and T700) due to isothermal oxidation (1): focusing on morphological changes using scanning electron microscopy

  • Oh, Seong-Moon;Lee, Sang-Min;Kang, Dong-Su;Roh, Jae-Seung
    • Carbon letters
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    • v.18
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    • pp.18-23
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    • 2016
  • Polyacrylonitrile (PAN)-based carbon fibers have high specific strength, elastic modulus, thermal resistance, and thermal conductivity. Due to these properties, they have been increasingly widely used in various spheres including leisure, aviation, aerospace, military, and energy applications. However, if exposed to air at high temperatures, they are oxidized, thus weakening the properties of carbon fibers and carbon composite materials. As such, it is important to understand the oxidation reactions of carbon fibers, which are often used as a reinforcement for composite materials. PAN-based carbon fibers T300 and T700 were isothermally oxidized in air, and microstructural changes caused by oxidation reactions were examined. The results showed a decrease in the rate of oxidation with increasing burn-off for both T300 and T700 fibers. The rate of oxidation of T300 fibers was two times faster than that of T700 fibers. The diameter of T700 fibers decreased linearly with increasing burn-off. The diameter of T300 also decreased with increasing burn-off but at slower rates over time. Cross-sectional observations after oxidation reactions revealed hollow cores in the longitudinal direction for both T300 and T700 fibers. The formation of hollow cores after oxidation can be traced to differences in the fabrication process such as the starting material and final heat treatment temperature.

Molecular Composite of Cellulose Triacetate and Polyester (II) -Bulk Property- (셀룰로오즈 트리아세테이트와 폴리에스테르의 분자복합체 (II) -고체성질-)

  • Hong, Young Keun
    • Textile Coloration and Finishing
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    • v.4 no.1
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    • pp.26-29
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    • 1992
  • Ternary solutions that cellulose triacetate (CTA) and polyethylene terephthate (PET) were mixed in a solvent trifiuoroacetic acid (TFA)/methylene chloride (MC) (6/4 : v/v) showed phase separation and mesophase formation. The ternary systems which were mesomorphic were spun into a methanol both and relatively strong cellulosic fillaments were successfully produced. Analysis showed that CTA/PET fibers have fibrillar structure and high orientation parallel to the fiber axis. These fibers proved to be molecular composite and have relatively high strength and modulus as spun.

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Drop-weight impact damage evaluation for carbon fiber/epoxy composite laminates (탄소 섬유강화 복합재료의 중력 낙하 충격으로 인한 손상 평가)

  • Sohn, Min-Seok;Hu, Xiao-Xhi;Ki, Jang-Kyo;Hong, Soon-Hyung
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2001.05a
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    • pp.89-92
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    • 2001
  • Drop weight impact tests were performed to investigate the impact behavior of carbon fiber/epoxy composite laminates reinforced by short fibers and other interleaving materials. Characterization techniques, such as cross-sectional fractography and scanning acoustic microscopy, were employed quantitatively to assess the internal damage of some composite laminates. Scanning electron microscopy was used to observe impact damage and fracture modes on specimen fracture surfaces. The results show that composite laminates experience various types of fracture; delamination, intra-ply cracking, matrix cracking and fiber breakage depending on the interlayer materials. Among the composite laminates tested in this study, the composites reinforced by Zylon fibers showed very good impact damage resistance with medium level of damage, while the composites interleaved by poly(ethylene-co-acrylic acid) (PEEA) film is expected to deteriorate the bulk strength due to the reduction of fiber volume fraction, even though the damaged area is significantly reduced.

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Tensile Properties and Morphology of Carbon Fibers Stabilized by Plasma Treatment

  • Lee, Seung-Wook;Lee, Hwa-Young;Jang, Sung-Yeon;Jo, Seong-Mu;Lee, Hun-Soo;Lee, Sung-Ho
    • Carbon letters
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    • v.12 no.1
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    • pp.16-20
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    • 2011
  • Commercial PAN fibers were thermally stabilized at 220 or $240^{\circ}C$ for 30 min. Those fibers were further stabilized using radio-frequency (RF) capacitive plasma discharge during 5 or 15 min. From Fourier transform infrared spectroscopy results, it was observed that an additional plasma treatment led to further stabilization of PAN fibers. After stabilization, carbonization was performed to investigate the final tensile properties of the fabricated carbon fibers (CFs). The results revealed that a combination of thermal and plasma treatment is a possible stabilization process for manufacturing CFs. Morphology of CFs was investigated using scanning electron microscopy. The morphology shows that the plasma stabilization performed by the RF large gap plasma discharge may damage the surface of the CF, so it is necessary to select a proper process condition to minimize the damage.

Biocompatibility of 13-93 Bioactive Glass-SiC Fabric Composites

  • Park, Jewon;Na, Hyein;Choi, Sung-Churl;Kim, Hyeong-Jun
    • Journal of the Korean Ceramic Society
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    • v.56 no.2
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    • pp.205-210
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    • 2019
  • Bioactive glass (BG) finds limited use as a bone replacement material owing to its low mechanical properties. In order to solve this problem, the micro-sized 13-93 BG was prepared as a fabric composite with SiC microfibers, and its mechanical properties and biocompatibility were investigated in this study. The tensile strengths of BG-SiC fiber-bundle composites increased in proportion to the number of SiC fibers. In particular, even when only one SiC fiber was substituted, the tensile strength increased by 81% to 1428 MPa. In the early stage of the in-vitro test, a silica-rich layer was formed on the surface of the 13-93 BG fibers. With time, calcium phosphate grew on the silica-rich layer and the BG fibers were delaminated. On the other hand, no products were observed on the SiC fibers for 7 days, therefore, SiC fibers are expected to maintain their strength even after transplantation in the body.

Damage and stiffness research on steel shape steel fiber reinforced concrete composite beams

  • Xu, Chao;Wu, Kai;Cao, Ping zhou;Lin, Shi qi;Xu, Teng fei
    • Computers and Concrete
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    • v.24 no.6
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    • pp.513-525
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    • 2019
  • In this work, an experimental research has been performed on Steel Fiber-Steel Reinforced Concrete (SFSRC)specimens subjected to four-point bending tests to evaluate the feasibility of mutual replacement of steel fibers and conventional reinforcement through studying failure modes, load-deflection curves, stiffness of characteristic points, stiffness degradation curves and damage analysis. The variables considered in this experiment included steel fiber volume percentage with and without conventional reinforcements (stirrups or steel fibers) with shear span depth ratios of S/D=2.5 and 3.5. Experimental results revealed that increasing the volume percentage of steel fiber decreased the creation and propagation of shear and bond cracks, just like shortening the stirrups spacing. Higher crack resistance and suturing ability of steel fiber can improve the stability of its bearing capacity. Both steel fibers and stirrups improved the stiffness and damage resistance of specimens where stirrups played an essential role and therefore, the influence of steel fibers was greatly weakened. Increasing S/D ratio also weakened the effect of steel fibers. An equation was derived to calculate the bending stiffness of SFSRC specimens, which was used to determine mid span deflection; the accuracy of the proposed equation was proved by comparing predicted and experimental results.

Mechanical and Electrical Properties of Nonwoven Coated with CNFs/PVDF-HFP Composite (탄소나노섬유/PVDF-HFP 복합재로 코팅된 부직포의 역학적 및 전기적 특성 변화)

  • Lee, Sun-Hee
    • Fashion & Textile Research Journal
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    • v.13 no.2
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    • pp.279-284
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    • 2011
  • In this study, the process of preparation nonwoven with coated carbon nano fibers (CNFs) /poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) composite solution is described. The various contents of CNFs/PVDF-HFP composite coated nonwoven were prepared and characterized by morphological, mechanical, and electrical methods. Nonwovens are coated with CNFs/PVDF-HFP composite solution and decreased the pick up ratio with increasing CNFs contents in range from 0% to 16%. In the results of SEM images, it was clear that the CNFs were evenly distributed in coated nonwoven by SEM images, the existence of CNFs in coated nonwoven was confirmed regularly. The mechanical properties of various contents of CNFs/PVDF-HFP coated nonwoven were examined. The tensile linearity and compression linearity increased with increasing CNFs contents. The electrical properties of the CNFs/PVDF-HFP coated nonwoven increased with increasing CNFs contents.

Delamination of a composite laminated under monotonic loading

  • Achache, Habib;Benzerdjeb, Abdelouahab;Mehidi, Abdelkader;Boutabout, Benali;Ouinas, Djamel
    • Structural Engineering and Mechanics
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    • v.63 no.5
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    • pp.597-605
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    • 2017
  • Our work aims to analyze using the finite element method the evolution of the stress intensity factor (SIF) parameter K of three laminated folded plates stacks [$+{\alpha}$, $-{\alpha}$], made of the same epoxy matrix and different reinforcement fibers (boron, graphite and glass). Our results show that the angle of orientation of the boron/epoxy composite has no great influence on the variation of the parameter KI. Compared to composite graphite/epoxy and glass/epoxy, the laminated composite boron/epoxy reduces more the SIF KI in the middle of the plate for angles $0^{\circ}{\leq}{\alpha}{\leq}30^{\circ}$.

Development of AI Matrix Composite using Shape Memory Alloy (형상 기억 합금을 이용한 Al기 복합재료 개발)

  • Jeong, T.H.;Lee, D.J.;Kim, H.G.
    • Transactions of the Korean Society of Automotive Engineers
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    • v.6 no.6
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    • pp.53-62
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    • 1998
  • A simple analytical and finite element(FE) models are used to study the tensile properties of Al matrix composite with continuous TiNi fibers. The effects of residual stresses caused by the shape momory effects have been compared for various mechanical behaviors as a function of fiber volume fraction and degree of pre-strain and fiber configurations. It is found that both the back stress in the Al matrix induced by stiffness of TiNi fibers and the compressive stress in the matrix are caused of the strengthening mechanisms. Both theoretical and analytical results show quite good agreement and are closed to the experimental data except in high volume content.

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Effect of Compatibilizers on Mechanical Properties of Wood-Plastic Composites Using Styrene Polymers as Matrix Polymers (스티렌계 수지(樹脂)를 매트릭스로 사용한 목재 - 플라스틱 복합체(複合體)의 물성(物性)에 미치는 상용화제(相溶化劑)의 효과(效果))

  • Han, Gyu-Seong
    • Journal of the Korean Wood Science and Technology
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    • v.21 no.2
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    • pp.31-37
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    • 1993
  • Composites of styrene polymers with woody fibers were prepared, and the effect of compatibilizers on their mechanical properties was evaluated. To improve the compatibility of wood fibers and the matrix polymers, styrene-maleic anhydride copolymer(SMA) and maleic anhydride-modified polymers were used as compatibilizers. As results, maleic anhydride-modified polystyrene and SMA were proved to improve the tensile strength of the molded composites, and also were evaluated as good compatibilizers for the wood fiber polystyrene composite. Cellulosic fiber (dissolving pulp) provided better reinforcement than lignocellulosic fiber(thermomechanical pulp). On the contrary in the case of the composite of wood fiber and acrylonitrile-butadiene styrene copolymer(ABS), SMA and maleic anhydride-modified acrylonitrile-butadiene-styrene copolymer(MABS) did not act as compatibilizers. However, MABS was evaluated as a good polymer matrix to make wood fiber reinforced composite. The tensile properties of the composites of wood fiber and MABS were superior than those of wood fiber-ABS composites.

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