• Title/Summary/Keyword: composite case

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Studies on the Fouling Reduction through the Coating of Poly (vinyl alcohol) on Polyamide Reverse Osmosis Membrane Surfaces (역삼투막 표면에 폴리비닐알코올 코팅을 통한 파울링 현상 감소연구)

  • Kim, Il Hyoung;Ji, Eun Hee;Rhim, Ji Won;Cheong, Seong Ihl
    • Membrane Journal
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    • v.22 no.4
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    • pp.272-279
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    • 2012
  • The neutral polymer, poly (vinyl alcohol) (PVA), was coated onto polyamide (PA) thin film composite reverse osmosis (RO) membranes. And then these membranes were investigated for the model foulants, bovine serum albumin (BSA), humic acid (HA), and sodium alginate (SA) whether there are aome improvement. As the operating pressure increased with 2, 4, 8 atm for BSA, HA and SA 100 ppm in feed solution, the fouling phenomena was worse for both none and PSSA coated membranes. The fouling occurred in the sequence of BSA > HA > SA due to the interactions between PVA snd functional groups of foulants, and on the other hand the fouling reduction was observed in the order of HA > BSA > SA. The observation of scanning electron microscopy photographs showed the same trend. As a result, there should be the improvement of fouling phenomena for the PVA coated RO membranes and the case of HA was shown distinct.

Treatment of AP Solutions Extracted from Solid Propellant by NF/RO Membrane Process (NF/RO 멤브레인 공정을 적용한 고체추진제에서 추출된 암모늄 퍼클로레이트 (AP) 처리 연구)

  • Kong, Choongsik;Heo, Jiyong;Yoon, Yeomin;Han, Jonghun;Her, Namguk
    • Membrane Journal
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    • v.22 no.4
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    • pp.235-242
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    • 2012
  • Ammonium perchlorate (AP) is primarily derived from the process of liquid incineration treatment when dismantling a solid rocket propellant. A series of batch dead-end nanofiltration (NF) and reverse osmosis (RO) membrane experiments were conducted to explore the retention mechanisms of AP under various hydrodynamic and solution conditions. Low levels of silicate type of siloxane had been detected through the GC/MS and FTIR analysis of liquid solutions extracted from solid ammonium perchlorate composite propellant (APCP). It is indicated that NF/RO membranes fouling in the presence of APCP was mainly attributed to the AP interactions because the concentration of silicate type of siloxane was negligible compared to that of AP. The osmotic pressure of AP was presumably resulted in the flux declines ranging from 13 to 17% in the case of the application of low-pressure (551 and 896 kPa for NF and RO) compared to those in application of high-pressure. The retention of AP by NF/RO membranes significantly varied from approximately 10 to 70% for NF and 26 to 87% for RO, depending on the operating and solution water chemistry conditions. The results suggested that retention efficiency of AP was fairly increased by reducing concentration polarization (i.e. application of low-pressure and stirring speed of 600 rpm) and increasing the pH of a solution. The result of this study was also consistent with the previous modeling of 'solute mass transfer of NF/RO membranes' and demonstrated that hydrodynamic and solution water chemistry conditions are to be a key factor in the retention of AP by NF/RO membranes.

Analysis of Contact Pressure for Material Combination in Unicompartmental Knee Implant (반치환 무릎 인공관절에서의 재료조합에 따른 접촉압력 분석)

  • Noh, Tae-Heon;Chun, Heoung-Jae
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.31 no.1
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    • pp.23-29
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    • 2018
  • In knee implants, contact pressure has a significant effect on wear. In this study, finite element analysis is performed using the knee implant model developed in the previous research. The contact pressures for a total of 10 knee implant materials combinations were analyzed using the combinations actually used in research and industry. In order to calculate the contact pressure, The load was applied when the flection angle of knee was $30^{\circ}$, $45^{\circ}$ and $60^{\circ}$. The result of contact pressure revealed the smallest contact pressure in the titanium alloy-UHMWPE combination. In the case of UHMWPE, contact pressure did not change much with any material used in the femur. Compared the combination with the largest contact pressure and the smallest contact pressure, the difference was 0.77%. On the other hand, Carbon / PEEK composites showed 5.3% difference when the contact pressure was the largest and the smallest. It can be seen that when the Carbon / PEEK composite material is used as the bearing part, the material of the femoral part affects the wear. This study will contribute to the prediction of knee implant wear and minimization of wear.

Tribological properties of pressureless-sintered $SiC/Si_3N_4$ composites (상압소결 $SiC/Si_3N_4$ 복합체의 마찰마모특성)

  • Baik, Yong-Hyuck;Choi, Woong;Seo, Young-Hean;Kim, In-Sub;Kim, Joo-Young
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.9 no.2
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    • pp.260-265
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    • 1999
  • $SiC/Si_3N_4$ composites were prepared by mixing ${\alpha}-Si_3N_4$ powder to $\alpha$-SiC powder in the range of 10 to 30 vol% with 10 vol% interval. 6 wt% of $Al_2O_3$ and $Y_2O_3$ were also added respectively as sintering aids. Then, pressureless sintering was performed at 1,78$0^{\circ}C$ for 2 hours in $N_2$ gas. In the case of adding 20 vol% of ${\alpha}-Si_3N_4$ powder, the relative desity to theoretical value and the flexutal strength were 92 % and 3,560 MPa, respectively. The smallest relative worn amount thereof was $2.68{\times}10^{-3}\;mm^2$ for 20 vol% ${\alpha}-Si_3N_4$. The composite containing 30 vol % of ${\alpha}-Si_3N_4$ powder showed the highest fracture toughness $(K_{1c})$ of $4.9\;MN/m^{3/2}$, although the reduction of the wear resistance due to the effect of the pores was observed.

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Attachment of Human Gingival Fibroblast to Various Subgingival Restorations;A Comparative Study in Vitro (다양한 치은 연하 수복물에 대한 치은 섬유아 세포 부착 연구)

  • Lee, Eun-Suk;Song, In-Taeck;Lim, Jeong-Su;Kim, Hyung-Seop
    • Journal of Periodontal and Implant Science
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    • v.29 no.3
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    • pp.621-636
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    • 1999
  • When mucoperiosteal flaps are positioned and sutured to desirable position, the wound contains several interface between tissues which differ fundamentally in composition & biological reaction. Thus the C-T surface of the flap will, on one hand, oppose another vascularized surface, and on the other, the avascular dental material for example, when root resoptions, fractured root, endodontic perforation, deep root carious lesions were filled with amalgam, glass ionomer, resin etc. Recently, a number of case report described the successful treatment of a subgingival root lesion with restorative material & free gingival graft, open flap surgery, but more objective research was needed . Most of study on restorative materials were concerned for cytotoxicity not for actual healing event on that materials and its influencing factors such as biocompatibility, surface wettability, surface topography . The aim of this in vitro study was to evaluate the effect of amalgam, resin modified glass ionomer, composite resin per se, and their surface roughness on the growth of human gingival fibroblast. The cells were obtained and placed on culture flask and incubated for 3 days with the prepared test materials. Then count the attached cell number with hemocytometer,(n=12) and 2 samples were examined with SEM about attachment cell morphology . Another 4 samples were evaluated on their surface roughness with Talysurf and average surface roughness value(Ra) were obtained. Statistical difference in attached cell number, roughness value were analyzed using ANOVA. The number of attached cell was as follows, for root dentin specimen 16.7${\pm}$4.41, resin modified glass ionomer 14.0${\pm}$4.15, resin 8.13${\pm}$3.63, amalgam 0.72${\pm}$3.33(${\times}10^3$). Between root dentin and resin-modified glass ionomer, no significant difference was observed, but resin, amalgam showed a significant less cell numbers than for root dentin, resin modified glass ionomer cement. SEM examination expressed many cell surface attachment apparatus in root dentin and resin modified glass ionomer specimens. For resin specimen, cell attachment was observed but exposed less appratus. The average surface roughness value are following results. Dentin specimen 0.6972${\pm}$ 0.104, resin modified glass ionomer 0.0822${\pm}$0.009, resin 0.0875${\pm}$0.005, amalgam 4.2145${\pm}$0.985(${\mu}m$). Between root dentin, resin-modified glass ionomer, and resin, no significant difference was observed, but amalgam showed a significant more rough surface than other groups. When evlauated the interrelationship between cell attachment and surface roughness, therefore, there was weak reverse correlation.(pearson correlation : - 0.593) These results suggest that resin modified glass ionomer have the favorable healing potential when used for subgingival restoration. And for relationship between cell attachment and surface characteristics, further investigations were needed.

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Nondestructive Interfacial Evaluation and fiber fracture Source Location of Single-Fiber/Epoxy Composite using Micromechanical Technique and Acoustic Emission (음향방출과 미세역학적시험법을 이용한 단일섬유강화 에폭시 복합재료의 비파지적 섬유파단 위치표정 및 계면물성 평가)

  • Park, Joung-Man;Kong, Jin-Woo;Kim, Dae-Sik;Yoon, Dong-Jin
    • Journal of the Korean Society for Nondestructive Testing
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    • v.23 no.5
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    • pp.418-428
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    • 2003
  • Fiber fracture is one of the dominant failure phenomena affecting the total mechanical Performance of the composites. Fiber fracture locations were measured through the conventional optical microscope and the nondestructive acoustic emission (AE) technique and then were compared together as a function of the epoxy matrix modulus and the fiber surface treatment by the electrodeposition method (ED). Interfacial shear strength (IFSS) was measured using tensile fragmentation test in combination of AE method. ED treatment of the fiber surface enlarged the number of fiber fracture locations in comparison to the untreated case. The number of fiber fracture events measured by the AE method was less than optically obtained one. However, fiber fracture locations determined by AE detection corresponded with those by optical observation with small errors. The source location of fiber breaks by AE analysis could be a nondestructive, valuable method to measure interfacial shear strength (IFSS) of matrix in non-, semi- and/or transparent polymer composites.

A Study on the Compression Moldability for Continuous Fiber-Reinforced Polymeric Composites -Part II : Effect of Correlation Coefficient on Compression Moldability- (연속섬유강화 플라스틱 복합재료의 압축성형성에 관한 연구 -제II보 : 압축성형성에 미치는 상관계수의 영향-)

  • 오영준;김이곤
    • Composites Research
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    • v.13 no.1
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    • pp.1-10
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    • 2000
  • During the compression molding process of the continuous fiber-reinforced polymeric composites, two main problems such as fiber-matrix separation and fiber orientation are produced by the difference of flow velocity. Molded parts are lead to be nonhomogeneous and anisotropic. As the mechanical property of the products are dependent on the separation and orientation, it is important to research the fiber mat structure and molding condition. If the fiber mat structure is changed by the increment of needling, the separation decreases and after compression molding the orientation is easily aligned. As it were, the compression moldability is good. But the defects as tears, thin thickness are produced in the products. Therefore, it is important to clarify the moldability in relation to the usage of products and the expenses of produce on the actual process. Therefore we must make the measurement methods that can define the moldability of products. In this research, the effects of the fiber mat structure(NP = 0, 5, 10, 25, 50 punches/$cm^2$) and the mold geometry($r_p$ = 1, 25, 50 mm) on the moldability of products were discussed. We investigated the case of one-dimensional flow in order to obtain the degree of nonhomogeneity and the fiber orientation function. In result, we could gain the correlation coefficient of the continuous fiber-reinforced polymeric composites. Also we experimented on the cup-type compression molding which was appeared the wrinkle on the flange part by the complex stress condition in order to gain the degree of nonhomogeneity and area ratio. In result, the moldability of products was expressed as the correlation coefficient and area ratio.

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MOLAR RESTORATION WITH AN ORTHODONTIC BAND (교정용 밴드를 이용한 구치부 수복)

  • Lee, Suk-Woo;Lee, Jae-Ho;Choi, Hyung-Jun;Sohn, Hyung-Kyu;Kim, Seong-Oh;Choi, Byung-Jai
    • Journal of the korean academy of Pediatric Dentistry
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    • v.36 no.1
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    • pp.91-95
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    • 2009
  • The use of stainless steel crowns are indicated for restoration of primary or permanent molars with proximal dental caries, extensive dental caries, or previous pulp treatment with increased danger of tooth fracture. Stainless steel crowns were introduced by Humphrey in 1950. For their improved durability, longevity, and success rate, they have been strongly considered for restoring extensive and multi-surfaced dental caries of molars in pediatric dentistry. However, they also have shortcomings, such as possibility of pulpal exposure or damaging proximal surface of adjacent teeth. In addition, when oversized stainless steel crowns are used, eruption of the adjacent permanent teeth may be disturbed by their prominent margin. As a means to compensate the shortcomings of stainless steel crowns, use of orthodontics bands may be considered. It is an alternative restoration method, where an orthodontic band is placed on a tooth first and cavity is restored with filling material, such as composite resin, glass ionomer, or amalgam. The use of an orthodontic band is indicated for molar restoration with cervical dental caries, extensive dental caries, enamel hypoplasia, or previous pulp treatment. Because it requires shorter chair time compared to stainless steel crown, its application is very useful for children with poor behavior. However, restoration using an orthodontic band requires good oral hygiene after its application. This case report illustrates the conservative restoration of primary molars and permanent molars with extensive dental caries using orthodontic bands.

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Effect of Seed Coating Layer on the Microstructure of NaA Zeolite Separation Layer Grown on ${\alpha}$-alumina Support (종결정 코팅층이 다공성 ${\alpha}$-알루미나 지지체 표면에 성장되는 NaA 제올라이트 분리층의 미세구조에 미치는 영향)

  • Kim, Min-Ji;Sharma, Pankaj;Han, Moon-Hee;Cho, Churl-Hee
    • Membrane Journal
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    • v.24 no.5
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    • pp.375-385
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    • 2014
  • NaA zeolite/${\alpha}$-alumina composite membranes were hydrothermally synthesized at $100^{\circ}C$ for 24 hr by using nanosize seed of 100 nm in diameter and an ${\alpha}$-alumina support of $0.1{\mu}m$ in pore diameter, and then effect of seed coating layer on the microstructure of NaA zeolite separation layer was systematically investigated. In cases when nanosize seed was coated with a monolayer, increment in seed coverage induced small grained and thick NaA zeolite separation layer. On the other hand, in case when nanosize seed was coated with a multilayer, much small grained and thick separation layer was formed. It was clear that an uniform monolayer seed coating is required to grow hydrothermally a thin and defect-free NaA zeolite separation layer. In the present study, it was clearly announced that seed coating layer is a key factor to determine the microstructure of NaA zeolite layer, secondary grown on a porous support.

Effects of Corrugated GFRP Shear Connector Width and Pitch on In-plane Shear Behavior of Insulated Concrete Sandwich Wall Panels (CSWP) (파형 GFRP 전단연결재의 폭 및 너비에 따른 중단열 벽체의 면내전단거동)

  • Jang, Seok-Joon;Oh, Tae-Sik;You, Young-Chan;Kim, Ho-Royng;Yun, Hyun-Do
    • Journal of the Korea Concrete Institute
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    • v.26 no.4
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    • pp.421-428
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    • 2014
  • This paper describes the experimental results of insulated concrete sandwich wall panels (CSWP) with corrugated glass fiber-reinforced polymer (GFRP) shear connectors under in-plane shear loading. Corrugated GFRP shear connectors were used to improve the thermal property of insulated CSWP and to achieve composite action between the interior and exterior concrete wall panels. Test specimens were consist of three concrete panels with two insulation layers between concrete panels and middle concrete panels was loaded in the direction of gravity. To evaluate the effects of insulation types (extruded polystyrene, XPSS and expanded polystyrene, EPS), shear connector pitch (300 and 400 mm) and width (10 and 15 mm) on in-plane shear behavior of insulted CSWP, failure mode and shear flow-average relative slip relationship of specimens were investigated. Test results indicate that the bond stress between concrete panel and insulation is considerable initially. Especially in case of insulated CSWP without shear connector, initial stiffness of CSWP with XPSS is superior to that of CSWP with EPS. The shear connector's contribution to in-plane shear performance of insulated CSWP depends on the type of insulation.