• Title/Summary/Keyword: complex viscosity

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A Performance Analysis and Experiment of Viscous Torsional Vibration Damper for High Speed Engine Shaft System (고속엔진축계용 점성 비틀림진동감쇠기의 성능해석 및 실험)

  • Yang, B.S.;Jeong, T.Y.;Kim, K.D.;Kim, D.J.
    • Journal of Power System Engineering
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    • v.1 no.1
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    • pp.98-105
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    • 1997
  • In general, crankshafts which are used in internal combustion reciprocating engines are subjects to high torsional vibration. Therefore, a damper is often used to minimize the torsional vibration in reciprocating engines. In this paper, in order to investigate damping performance of viscous damper, the real effective viscosity and complex damping coefficient of silicone oil, and the effective inertia moment of inertia ring are calculated considering the relative motion between damper casing and inertia ring. Based on these results multi-cylinder shaft is modeled into equivalent 2-degree of freedom system and optimum condition is estimated by calculating the amplification factor of viscous damper. Also the test damper was manufactured according to the result of theoretical investigation, the performance and durability was ascertained through experimental examination.

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Visocoelasticity of Electrorhedlogical Fluid from Vertical Oscillation Rheometer (수직진동 rheometer를 이용한 전도유체의 점탄성 연구)

  • Kim, Sang-Guk;Kim, Dong-Chan;Choe, Yeong-Jin;Jo, Min-Seong
    • Korean Journal of Materials Research
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    • v.6 no.11
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    • pp.1067-1073
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    • 1996
  • 본 연구에서는 직접 제작된 전도유체(electrorheological fluid)용 수직진동 rhemeter 기기상의 구조 해석 및 실험을 실시하였다. 수직진동 rheomether는 간단하게 제작이 가능하고, 고전압 발생장치를 연결하므로 전동유체의 점탄성 특성을 비교적 쉽게 측정할 수 있다. Rheometer의 구조적 변수와 측정된 힘, 변형 등을 이용하여 복소 점도(complex viscosity), 복소 전단 변형률(complex shear modulus), loss tangent 등의 선형 점탄성 물질 함수를 직접 계산할 수 있으며, corn starch를 polybutene/kerosene에 분산시킨 전동유체를 이용하여 전기장하의 점탄성을 측정하였다.

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Strong Orientation Anchoring and Shear Flow of a Nematic Liquid Crystal

  • Won Hee HAN
    • International journal of advanced smart convergence
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    • v.13 no.2
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    • pp.103-109
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    • 2024
  • A nonlinear numerical analysis of orientation and velocity fields of the full Ericksen-Leslie theory for a nematic liquid crystal under shear flow is given. We obtained for the first time the three-dimensional orientation and two component velocity profiles evolutions for both in- and out-of-shear plane orientation anchorings. Complex evolution routes to steady state were found even for shear aligning nematic. As the Ericksen number increases monotonic evolution of velocity and orientation shifts towards multi-region nucleating director rotation growth with complex secondary flow generations. We found that contrary to the in-shear-plane anchorings like homeotropic or parallel anchorings, binormal anchoring gives rise to substantial non-planar three-dimensional orientation with nonzero secondary flow.

Studies on the synthesis and characteristics of calcium sulfonate complex grease (칼슘 술폰산염 컴플렉스 그리스 합성과 특성 연구)

  • Woo, Jaegu;Lee, Dongkyu;Ha, KiRyong
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.7
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    • pp.8-15
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    • 2019
  • In this study, we synthesized a calcium sulfonate complex grease and a lithium complex grease to investigate their physical, rheological and tribological properties. The thermal stability of the calcium sulfonate was higher than $300^{\circ}C$ and the lithium complex grease was $245^{\circ}C$ in the dropping point test. In the grease viscosity measurement, the calcium sulfonate complex grease was measured as $7.0Pa{\cdot}s$ and the lithium complex grease was as $4.5Pa{\cdot}s$. Therefore, it was confirmed that the calcium sulfonate complex grease is superior to the lithium complex grease in terms of thermal stability and cohesiveness. In the 4-ball wear test, the calcium sulfonate complex grease was measured to be 0.43 mm and the lithium complex grease to 0.85 mm. In the 4-ball extreme pressure test, calcium sulfonate complex grease was measured as 620 kgf and the lithium complex grease was as 125 kgf. Therefore, it was confirmed that the calcium sulfonate complex grease is superior to the lithium complex grease in abrasion resistance and load-bearing property. It was found that the calcium sulfonate complex grease is more effective than the lithium complex grease in the lubrication at high temperature and high load.

Thermal and Rheological Properties, and Biodegradability of Chemically Modified PLA by Reactive Extrusion (반응압출법에 의해 화학적으로 개질된 PLA의 열적 특성, 유연학적 성질 및 생분해도)

  • Jang, Woo-Yeul;Hong, Ki-Heon;Cho, Baek-Hee;Jang, Sang-Hee;Lee, Sang-Il;Kim, Bong-Shik;Shin, Boo-Young
    • Polymer(Korea)
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    • v.32 no.2
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    • pp.116-124
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    • 2008
  • A commercialized biobased and biodegradable poly(lactic acid)(PLA) containing the functional monomer of glycidyl methacrylate (GMA) was chemically modified using reactive extrusion to enhance its melt strength. Modified PLAs were prepared with various contents of GMA and initiator, and were characterized by observing their gel fraction, thermal properties, melt viscoelasticity and biodegradability. The complex viscosity and storage modulus of chemically modified PLA with the initiator alone was increased by addition of initiator and were more increased in the presence of GMA. There was a optimum content of GMA showing the maximum complex viscosity with the amount of initiator. The biodegradebility of modified PLA was slightly decreased by addition of GMA.

In situ viscoelastic properties of insoluble and porous polysaccharide biopolymer dextran produced by Leuconostoc mesenteroides using particle-tracking microrheology

  • Jeon, Min-Kyung;Kwon, Tae-Hyuk;Park, Jin-Sung;Shin, Jennifer H.
    • Geomechanics and Engineering
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    • v.12 no.5
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    • pp.849-862
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    • 2017
  • With growing interests in using bacterial biopolymers in geotechnical practices, identifying mechanical properties of soft gel-like biopolymers is important in predicting their efficacy in soil modification and treatment. As one of the promising candidates, dextran was found to be produced by Leuconostoc mesenteroides. The model bacteria utilize sucrose as working material and synthesize both soluble and insoluble dextran which forms a complex and inhomogeneous polymer network. However, the traditional rheometer has a limitation to capture in situ properties of inherently porous and inhomogeneous biopolymers. Therefore, we used the particle tracking microrheology to characterize the material properties of the dextran polymer. TEM images revealed a range of pore size mostly less than $20{\mu}m$, showing large pores > $2{\mu}m$ and small pores within the solid matrix whose sizes are less than $1{\mu}m$. Microrheology data showed two distinct regimes in the bacterial dextran, purely viscous pore region of soluble dextran and viscoelastic region of the solid part of insoluble dextran matrix. Diffusive beads represented the soluble dextran dissolved in an aqueous phase, of which viscosity was three times higher than the growth medium viscosity. The local properties of the insoluble dextran were extracted from the results of the minimally moving beads embedded in the dextran matrix or trapped in small pores. At high frequency (${\omega}>0.2Hz$), the insoluble dextran showed the elastic behavior with the storage modulus of ~0.1 Pa. As frequency decreased, the insoluble dextran matrix exhibited the viscoelastic behavior with the decreasing storage modulus in the range of ${\sim}0.1-10^{-3}Pa$ and the increasing loss modulus in the range of ${\sim}10^{-4}-1\;Pa$. The obtained results provide a compilation of frequency-dependent rheological or viscoelastic properties of soft gel-like porous biopolymers at the particular conditions where soil bacteria produce bacterial biopolymers in subsurface.

Synthesis and Properties of Exfoliated Poly(methyl methacrylate-co-acrylonitrile)/Clay Nanocomposites via Emulsion Polymerization

  • Mingzhe Xu;Park, Yeong-Suk;Wang, Ki-Hyun;Kim, Jong-Hyun;Chung, In-Jae
    • Macromolecular Research
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    • v.11 no.6
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    • pp.410-417
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    • 2003
  • Poly(methyl methacrylate-co-acrylonitrile) [P(MMA-co-AN)]/Na-MMT nanocomposites were synthesized through emulsion polymerization with pristine Na-MMT. The nanocomposites were exfoliated up to 20 wt% content of pristine Na-MMT relative to the amount of MMA and AN, and exhibited enhanced storage moduli, E', relative to the neat copolymer. The exfoliated morphology of the nanocomposite was confirmed by XRD and TEM. 2-Acryla-mido-2-methyl-1-propane sulfonic acid (AMPS) widened the galleries between the clay layers before polymerization and facilitated the comonomers, penetration into the clay to create the exfoliated nanocomposites. The onset of the thermal decomposition of the nanocomposites shifted to a higher temperature as the clay content increased. By calculating areas of tan$\delta$ of the nanocomposites, we observed that the nanocomposites show more solid-like behavior as the clay content increases. The dynamic storage modulus and complex viscosity increased with clay content. The complex viscosity showed shear-thinning behavior as the clay content increased. The Young's moduli of the nano-composites are higher than that of the neat copolymer and they increase steadily as the silicate content increases, as a result of the exfoliated structure at high clay content.

Effects of Compatibilizer on Mechanical, Morphological, and Rheological Properties of Polypropylene/Poly(acrylonitrile-butadiene-styrene) Blends

  • Kum, Chong-K.;Sung, Yu-Taek;Kim, Yong-Su;Lee, Hyung-Gon;Kim, Woo-Nyon;Lee, Heon-Sang;Yoon, Ho-Gyu
    • Macromolecular Research
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    • v.15 no.4
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    • pp.308-314
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    • 2007
  • The effects of a compatibilizer on polypropylene (PP)/poly(acrylonitrile-butadiene-styrene) (ABS) blends were studied. Blends of the PP/ABS, with PP-g-SAN copolymer as a compatibilizer, were prepared using a twin screw extruder. The flexural and impact strength of the PP/ABS blends with the PP-g-SAN copolymer increased significantly with PP-rich compositions on the addition of the PP-g-SAN copolymer at 3 phr. The increase in the mechanical properties of the PP/ABS/PP-g-SAN blend may have been due to the toughening effects of the ABS in the PP-rich compositions. In the morphology study of the PP/ABS/PP-g-SAN (80/20) blend with the PP-g-SAN copolymer, the minimum droplet size, $5.1{\mu}m$, was observed with the addition on phr of the PP-g-SAN copolymer. The complex viscosity of the PP/ABS/PP-g-SAN (80/20) blends increased with the addition of3 phr of the PP-g-SAN copolymer. From the above mechanical properties, morphology and complex viscosity results for the PP/ABS blends, it is suggested that the compatibility is more increased with the PP-rich composition (PP:ABS=80/20 wt%) of the PP/ABS blend on the addition of 3 phr of the PP-g-SAN copolymer.

Morphological, Mechanical and Rheological Properties of Poly(acrylonitrile-butadiene-styrene)/Polycarbonate/Poly$({\varepsilon}-caprolactone)$ Ternary Blends

  • Hong, John-Hee;Song, Ki-Heon;Lee, Hyung-Gon;Han, Mi-Sun;Kim, Youn-Hee;Kim, Woo-Nyon
    • Macromolecular Research
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    • v.15 no.6
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    • pp.520-526
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    • 2007
  • The effects of poly($({\varepsilon}$-caprolactone) (PCL) on poly(acrylonitrile-butadiene-styrene) (ABS) and polycarbonate (PC) blends were studied. Blends of ABS/PC (70/30, wt%) with PCL as a compatibilizer were prepared by a twin screw extruder. From the glass transition temperature $(T_g)$ results of the ABS/PC blends with PCL, the $T_g$(PC) of the ABS/PC (70/30) blends decreased with increasing PCL content. From the results of the morphology of the ABS/PC (70/30) blends with PCL, the phase separation between the ABS and PC phases became less significant after adding PCL in the ABS/PC blends. In addition, the morphological studies of the ABS/PC blends etched by NaOH indicated that the shape of the droplet was changed from regular round to irregular round by adding PCL in the ABS/PC blends. These results for the mechanical properties of the ABS/PC blends with PCL indicated that the tensile, flexural and impact strengths of the ABS/PC (70/30) blends peaked at a PCL content of 0.5 phr. From the results for the rheological properties of the ABS/PC (70/30) blends with PCL content, the storage modulus, loss modulus and complex viscosity increased at PCL content up to 5 phr. From the above results of the $T_g$, mechanical properties, morphology and complex viscosity of the ABS/PC blends with PCL, it was concluded that the compatibility was increased with PCL addition in the ABS/PC (70/30, wt%) blends and that the optimum concentration of PCL as a compatibilizer is 0.5 phr.

Effect of Latex Particle Size on Rheological and Electrical Properties of Polystyrene/Multi-Walled Carbon Nanotube Nanocomposites (라텍스 입자 크기가 폴리스티렌/탄소나노튜브 나노복합재료의 유변물성 및 전기적 물성에 미치는 영향)

  • Kang, Myung-Hwan;Noh, Won-Jin;Lee, Seong-Jae
    • Polymer(Korea)
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    • v.35 no.5
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    • pp.451-457
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    • 2011
  • The effect of latex particle size on rheological and electrical properties of latex-blended polystyrene (PS)/multi-walled carbon nanotube (MWCNT) nanocomposites was investigated. Mono-dispersed PS particles synthesized either by emulsifier-free emulsion polymerization or by dispersion polymerization were mixed with MWCNTs under ultrasonication, and freeze-dried to prepare the nanocomposites. As the MWCNT content increased, storage modulus, complex viscosity and electrical conductivity were substantially increased. The increase of storage modulus and complex viscosity was higher for larger PS particles. The effect of particle size on electrical properties was different depending on MWCNT content. With lower MWCNT content, the nanocomposite prepared by smaller PS particles showed higher electrical conductivity, but the opposite result was given as the content increased.