• Journal of the Korean Chemical Society
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• v.31 no.5
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• pp.444-451
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• 1987

The dependence of polarographic parameters on the pressure for the reduction of copper(II), cadmium(II), and zinc(II) complex ions with ethylenediamine, propylenediamine, and diethylenetriamine has been studied. In this study the dropping mercury electrode, the mercury pool electrode, and helix type of platinum wire were used as the working, the reference, and the auxilary electrode, respectively. With increasing the pressure from 1 atmosphere to 1,500 atmospheres, the reduction half-wave potentials of metal complex ions are shifted to the negative values and the diffusion currents become considerably larger, in keeping with the theory on the change of the physical properties of the electrolytic solution such as the density, the viscosity, the dielectric constant, and the electrical conductance, etc. The slope values of the logarithmic plot are increased with increasing the pressure, which indicates the more irreversible reduction. The temperature coefficients of diffusion current observed over the range of the temperature from 25$^{\circ}$C to 35$^{\circ}$C are about two percentage with increasing the pressure, therefore the polarographic reduction under the high pressure is controlled by diffusion. The linear relationships between diffusion current and concentration of metal complex ions are established over all pressure range.

• Applied Chemistry for Engineering
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• v.29 no.3
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• pp.307-311
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• 2018

Mid-range vinylidene content polyisobutylenes were prepared by using a Lewis acid catalyst. The best results were obtained when a complex catalyst composed of n-propanol as a cocatalyst and $BF_3$ as a main catalyst was used at the reaction temperature of -8 to $5^{\circ}C$ under a pressure of $2.5kg/cm^2$. The number average molecular weight ($M_n$) and viscosity of the polyisobutylenes were 500~1,000 g/mol and 20~210 cSt (at $100^{\circ}C$), respectively. The vinylidene content was 40~70% and easily varied by adjusting the reaction temperature.

• Journal of Biosystems Engineering
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• v.37 no.1
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• pp.28-35
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• 2012

Purpose: This study performed the oscillatory test using the texture analyzer to characterize the viscoelastic behavior of apples such as the storage modulus (E'), the loss modulus (E"), the complex modulus (${\mid}E^*{\mid}$) and the energy dissipated per cycle ($W_{diss}$). Methods: The sinusoidal deformation with the frequency of 1-10 Hz and the maximum displacement of 0.1 mm were applied to the flesh tissues of Fuji, Golden Delicious and Red Delicious apples. The Lissajous figure was used to measure the phase angle(${\delta}$) between stress and strain curve. Results: Trigger force was critical to the measurement of the phase angle. E', E", ${\mid}E^*{\mid}$ and Wdiss were measured using the Lissajous figure and the phase angle. The complex modulus of Golden Delicious apple was significantly lower than those of Fuji apple and Red Delicious apple. Conclusions: Apple flesh was exhibiting more elasticity at low frequency, and more viscosity at high frequency. Dynamic compressive properties of Fuji apple were similar to those of Red Delicious apple but significantly different from those of Golden Delicious apple.

• Journal of Soil and Groundwater Environment
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• v.21 no.3
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• pp.14-20
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• 2016

Remediation of crude oil contaminated soil is complicate and hard to apply traditional methods because of its persistency, durability, and high viscosity. Therefore, in this study, the efficiency of crude oil contaminated soil remediation was tested by developing a pilot-scale thermal desorption system using the indirect heating method with an exhaust gas treatment. Under optimal condition drawed by temperature and retention time, the remedial efficiency of crude oil contaminated soil and treatability of exhaust gas were analyzed. Total Petroleum Hydrocarbon (TPH) concentration of crude oil contaminated soil was decreased to 69.7 mg/kg on average and the remedial efficiency was measured at 99.60%. Through the exhaust gas, 86.0% of Volatile Organic Compounds (VOC) was degraded and 97.16% of complex malodor was reduced under the suggested optimum operation condition. This study provides important basic data to be useful in scaling up of the indirect thermal desorption system for the remediation of crude oil contaminated soil.

• International Journal of Aerospace System Engineering
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• v.2 no.2
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• pp.67-72
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• 2015

The main concern of this study is to integrate the EARSM into an industrial RANS solver in conjunction with the $k-{\omega}$ model, as proposed by Hellsten (EARSMKO2005). In order to improve the robustness, particular limiters are introduced to turbulent conservative variables, and a suitable full-approximation storage (FAS) multi-grid (MG) strategy is designed to incorporate turbulence model equations. The present limiters and MG strategy improve both robustness and efficiency significantly but without degenerating accuracy. Two discretization approachs for velocity gradient on cell interfaces are implemented and compared with each other. Numerical results of a three-dimensional supersonic square duct flow show that the proper discretization of velocity gradient improves the accuracy essentially. To assess the capability of the resulting EARSM $k-{\omega}$ model to predict complex engineering flow, the case of Common Research Model (CRM, Wing-Body) is performed. All the numerical results demonstrate that the resulting model performs well and is comparable to the standard two-equation models such as SST $k-{\omega}$ model in terms of computational effort, thus it is suitable for industrial applications.

• Journal of the Korean Society of Food Science and Nutrition
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• v.46 no.5
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• pp.608-615
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• 2017

The objective of this study was to evaluate the physicochemical, structural, and rheological properties of new domestic potato cultivars ('Goun', 'Sebong', and 'Jinsun') against the foreign potato cultivar 'Atlantic'. Based on the results obtained from scanning electron micrograph, X-ray, and Fourier transform infrared spectrum analyses, the structural properties of all potato flours were not considerably different. Rapid visco analyzer analyses showed that the setback viscosities of 'Goun', 'Sebong', and 'Jinsun' were significantly lower than that of 'Atlantic'. For steady shear rheological properties, potato flour dispersions showed shear-thinning behaviors (n=0.45~0.49) at $25^{\circ}C$. Apparent viscosity and consistency index of 'Atlantic' were similar to those of 'Sebong' and 'Jinsun'. For dynamic shear rheological properties, storage modulus (G′) and loss modulus increased, whereas complex viscosity (${\eta}^*$) was reduced with increasing frequency from 0.63 to 62.8 rad/s. G′ and ${\eta}^*$ values of 'Jinsun' were significantly higher than those of the other potato cultivars.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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• 2002.10b
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• pp.333-334
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• 2002

Injection-compression molding parts are many cases with complicated boundary condition which is difficult to analysis of mold characteristics precisely. In this study, the effects of various process parameters such as multi-point gate location, initial charge volume, injection time and pressure have been investigated using finite element method to fomulate the melt front advancement during the mold filling process. A general governing equation for tracking the filling process during injection-compression molding is applied to volume of fluid method. To verify the results of present analysis, they are compared with those of the other paper. The results show a strong effect of processing conditions as a result of variations in the three-dimensional complex geometry model.

• The Korean Journal of Rheology
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• v.9 no.2
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• pp.81-87
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• 1997

비상용성 고분자는 그 계면의 특성에 의해서 복잡한 유변학적 거동을 갖는데 그러 한 거동을 해석하기 위해서 최근에 제안된 구성방정식을 토대로 소폭 진동 전단 흐름장에서 의 유변학적 물성과 몰폴로지 전개를 예측한 바 있다. Takahashi[2]등은 이런 흐름하에서의 계면은 거의 변하지 않음을 보여주었고 따라서 이경우는 상대적으로 쉬운편이었다. 본연구 에서는 정상전단흐름장하에서의 몰폴로지 전개에 대한 구성방정식을 간단한 형태로 표현함 으로써 실제 산업계에서 이용될수 있도록 하였다. 그러한 해석을 통하여 원래의 모델에서 제시되었던 3개의 실험변수를 2개로 줄일수 있었으며 계면의 특성을 잘 나타내 주는 새로운 변수($textsc{k}$)를 도입하였다. 계면의 특성을 잘 나타내 주는 이새로운 변수를 통하여 그 계면의 영향을 예측할수 있었다. 한편 분산상의 파괴, 변형, 합체 메카니즘을 모델에 제시되었던 변 수값들을 통하여 해석하였고 이를 실험적인 데이터와 비교해 보았다.

• Proceedings of the KSME Conference
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• 2003.04a
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• pp.2162-2167
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• 2003

It is well-known that high anisotropic characteristic of turbulent flow field is dominant inside tip leakage vortex. This anisotropic nature of turbulence invalidates the use of the conventional isotropic eddy viscosity turbulence model based on the Boussinesq assumption. In this study, to check whether an anisotropic turbulence model is superior to the isotropic ones or not, the results obtained from steady-state Reynolds averaged Navier-Stokes simulations based on the RNG ${\kappa}-{\varepsilon}$ and the Reynolds stress model in two test cases, such as a linear compressor cascade and a forward-swept axial-flow fan, are compared with experimental data. Through the comparative study of turbulence models, it is clearly shown that the Reynolds stress model, which can express the production term and body-force term induced by system rotation without any modeling, should be used to predict the complex tip leakage flow, including the locus of tip leakage vortex center, quantitatively.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2003.06a
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• pp.1135-1138
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• 2003

ERFs(Electrorheological Fluids) arc a complex system consisting of polarizable particles and insulation liquid. When an external electric field is applied to ERFs, its apparent viscosity increases dramatically. This phenomenon is called the ER effect. Generally, the behavior of ERFs has been modeled on those of Bingham fluids. But the behavior of ERFs differs from those of Bingham fluids in many respects. In the paper, ER effect concerning flow mode of ERFs is analyzed experimentally. According to several flow conditions, the change of ER effect is presented and visualized. A new modeling methodology of ER effect to reduce the modeling error is presented.