• 제목/요약/키워드: complex organic acid

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Quality of Persimmon Vinegar Fermented by Complex Fermentation Method (복발효 감식초의 품질)

  • 김미경;김미정;김소연;정대성;정용진;김순동
    • Journal of the East Asian Society of Dietary Life
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    • v.4 no.2
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    • pp.39-44
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    • 1994
  • To prepare the basic information for the fermentation of high quality persimmon vinegar in the farm. the quality of the complex fermented persimmon vinegar(CFPV) was compared to that of naturally fermented persimmon vinegar (NFPV). The titratable acidity of the CFPV was 3% which was the half concentration of the NFPV. The content of total free sugar by HPLC was 6% in CFPV and NFPV was 5%. Organic acid compositions in persimmon vinegar were oxalic acid, malic acid, lactic acid, citric acid, succinic acid and glutaric acid in addition to acetic acid. Total content of the organic acids in NFPV was higer than in CFPV. Especially, the content of latic acid in NFPV was very higher than that of CFPV. the flavour, color and taste of persimmon fruit itself in CFPV were stronger than those in NFPV.

Preparation of Calcium Powder from Eggshell and Use of Organic Acids for Enhancement of Calcium Ionization (난각칼슘의 제조 조건 및 유기산이 칼슘의 이온화에 미치는 영향)

  • Shin, Hyung-Soon;Kim, Kong-Hwan
    • Applied Biological Chemistry
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    • v.40 no.6
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    • pp.531-535
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    • 1997
  • An efficient process for recovery of calcium from the eggshell was developed and some organic acids were used in an attempt to enhance the degree of calcium ionization. Eggshell membrane was readily separated from crushed eggshell based on the differences in specific gravities. The conditions which allowed most efficient membrane removal were found to be 30 rpm of speed, 30 min of residence time and 0.08 of volume fraction. It took 3 hours for the eggshell powder prepared at $1000^{\circ}C$ to reach L value of 90 with the Hausner ratio being 1.43. The calcium ion concentrations were 990, 3500, 3900 and 4200 ppm in pure water, acetic acid, citric acid and lactic acid$(0.05{\sim}3%)$ aqueous solution, respectively. The degrees of ionization of calcium-citrate-malate complex(CCM), calcium-citric acid complex(CC) and calcium malic acid complex(CM) increased by 4 to 5 times compared to eggshell calcium powder.

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Oxidation of Dibenzothiophene Catalyzed by Surfactant-Hemoprotein Complexes in Anhydrous Nonpolar Organic Solvents

  • Ryu, Keun-Garp;Chae, Young-Rae;Kwon, O-Yul
    • Journal of Microbiology and Biotechnology
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    • v.13 no.5
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    • pp.647-650
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    • 2003
  • In anhydrous organic solvents, the complexes formed between AOT (dodecylbenzene sulfuric acid sodium salt) and hemoproteins, such as hemoglobin, myoglobin, or cytochrome c, displayed remarkably higher activity than the hemoprotein powders to oxidize dibenzothiophene, a model compound of organic sulfurs contained in fossil fuels. In slightly hydrophobic organic solvents, such as ethyl acetate and butyl acetate, dibenzothiophene was completely oxidized catalytically by the cytochrome c-AOT complex with cumene hydroperoxide (${\alpha},{\alpha}-dimethylbenzyl$ hydroperoxide) as an oxidant. In highly hydrophobic organic solvents, such as decane and hexadecane, however, the activity of the cytochrome c-AOT complex decreased, presumably due to the aggregation of the hemoprotein-AOT complex in these solvents.

Effect of Salicylic and Picolinic Acids Acids on the Adsorption of U(VI) onto Oxides (산화물 표면의 U(VI) 흡착에 미치는 살리실산과 피콜린산의 영향)

  • Park, Kyoung-Kyun;Jung, Euo-Chang;Cho, Hye-Ryun;Song, Kyu-Seok
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.7 no.4
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    • pp.219-227
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    • 2009
  • The effect of organic acids on the adsorption of U(VI) onto oxide surfaces ($TiO_2)$(anatase), $SiO_2$(amorphous) and $Al_2O_3$(amorphous)) has been investigated. Two different organic acids, salicylic and picolinic acids, were used. Changes of adsorption ratio of U(VI), which depend on the existence of organic acids in a sample, were measured as a function of pH. Quantities of adsorbed organic acids, which depend on the existence of U(VI) in a sample, were also measured as a function of pH. It is confirmed that the soluble complex formation of U(VI) with organic acids can deteriorate the adsorption of U(VI) onto $TiO_2$ surface. It is noteworthy that salicylic acid does not affect the adsorption of U(VI) onto $SiO_2$ surface, however, picolinic acid enhances the adsorption of U(VI) onto $SiO_2$ surface. The latter effect can be understood by considering the formation of a ternary surface complex on $SiO_2$ surface, which was confirmed by the co-adsorption of picolinic acid with U(VI) and the change in a fluorescence spectra of U(VI) on surface, In the case of $Al_2O_3$, organic acids themselves were largely adsorbed onto a surface without deteriorating the adsorption of U(VI). This would support the possibility of a ternary surface complex formation on the $Al_2O_3$ surface, and an additional spectroscopic study is required.

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A study for Solubilization and Bioavailability of Sewage Sludge Using the Complex Pre-treatment (복합 전처리를 통한 하수슬러지의 가용화 및 생물학적 유용성에 관한 연구)

  • Kang, Jung-Hyun;Lee, Hee-Soo;Lee, Tae-Jin
    • Journal of the Korea Organic Resources Recycling Association
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    • v.19 no.3
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    • pp.35-43
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    • 2011
  • In this study, anaerobic biological decomposition were attempted after solubilization treatment of sewage sludge with the complex pre-treatment (acid/base treatment with ultrasonic radiation). Solubilization ratios were compared for ultrasonic treatment at acid or base condition. Solubilization effect of the complex pre-treatment was more effective at higher pH. Biological decomposition of complex pre-treated sludge was faster than non treated (raw) sludge, showing 10 times higher total gas production. Biological digestion of the sludge shows more biogas production. B/A ratio. which indicates hydrogen production potential, was 50% higher with complex pre-treated sludge than raw sludge but lactic acid or propionic acid were also detected during anaerobic decomposition process.

Correlation Analysis of Organic Acid Comprehensive Profile Markers with Chemotherapy Induced Peripheral Neuropathy in Cancer Patients (항암제 유발 말초신경병증환자와 유기산검사 마커와의 상관성 연구)

  • Park, Ji Hye;Sung, Simon SangYup;Lee, Jin Sun;Yoo, Hwa Seung
    • The Journal of Korean Medicine
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    • v.38 no.1
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    • pp.72-80
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    • 2017
  • Objectives: The purpose of this study is to evaluate the urinary organic acid comprehensive profile for chemotherapy induced peripheral neuropathy (CIPN). Methods: Participants are 66 patients with CIPN who had symptom (Visual analog scale ${\geq}30mm$, Eastern Cooperative Oncology Group ${\leq}2$). Participants were tested with organic acid comprehensive profile markers. Results: Positive Correlation was observed in the neurotransmitter metabolism markers, N-methyl-D-aspartate (NMDA) modulators markers, detoxification markers, energy production markers, amino acid metabolism markers, and intestinal dysbiosis markers. Especially, all the neurotransmitter metabolism markers were showed positive rate of 44%. In addition, neuro-endo-immune was associated with energy metabolism (mitochondrial dysfunction) in CIPN of cancer patient. especially detoxification, intestinal bacterial hyperplasia, vitamin deficiency (folate, complex B group, vitamin C). Conclusions: Significant urinary organic acid comprehensive profile results were obtained in cancer patients who induced peripheral neuropathy by chemotherapy.

Determination of the Formation Constants of Metal Complexes with Organic Acids by Adsorption Method (흡착법에 의한 금속이온과 유기산간의 착염 생성계수의 측정법)

  • Jae, Won-Mok
    • Journal of the Korean Chemical Society
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    • v.15 no.4
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    • pp.199-203
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    • 1971
  • The adsorption method for the determination of the formation constants of the metal complexes with organic acids was developed by using membrane filters. The adsorption method involved the measurements of radioactivities of the adsorbed metal on membrane filters and the filtrate solution after the radioactive metal ion were filtered through membrane filters in the presence of organic ions of varying concentration. Comparing the adsorption method with the ion exchange method, it was seen that the adsorption method was simpler and faster than the ion exchange method. As an example of the metal complex with organic acid yttrium citrate complex was chosen, and the formation constant of the complex obtained by the adsorption method showed $K_f=2.0{\times}10^{-4}(l. mole^{-1})$ at a pH of 7. Also the present study revealed that the carrierfree state of yttrium in aqueous solution was present in the completely ionized state.

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Green synthesis of aluminum-based metal organic framework for the removal of azo dye Acid Black 1 from aqueous media

  • Jung, Kyung-Won;Choi, Brian Hyun;Lee, Seon Yong;Ahn, Kyu-Hong;Lee, Young Jae
    • Journal of Industrial and Engineering Chemistry
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    • v.67
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    • pp.316-325
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    • 2018
  • Aluminum based metal-organic framework using a di-carboxylate linker succinic acid (Al-SA MOF), are synthesized in water with minimal generation of secondary pollutants. The physicochemical properties of Al-SA MOF were examined, followed by its utility for the adsorption of Acid Black 1 (AB1) in aqueous media. Influences of key parameters such as pH, contact time, initial AB1 concentration,temperature, and selectivity on the adsorption process were assessed. A series of adsorption mechanisms are proposed, which involve electrostatic, hydrogen bonding, and hydrophobic interactions. These findings suggest that Al-SA MOF is a potent candidate in removing complex azo dyes molecules from aqueous media.

Functional Characteristics of Kombucha Fermented with Lactic Acid Bacteria, Yeast, and Acetic Acid Bacteria Derived from Korea Traditional Foods

  • Lee, Su-Min;Lee, Jae-Yong;Yoo, Dong-Gyu;Jeon, Yu-Bin;Yoon, Ho-Sik;Kim, Cheol-Hyun
    • Journal of Dairy Science and Biotechnology
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    • v.40 no.1
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    • pp.23-34
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    • 2022
  • In this study, to determine the importance of lactic acid bacteria (LAB) in Kombucha fermentation, biological functions, such as organic acid production and anti-inflammatory and antibacterial activities, of Kombucha, with or without LAB inoculation, were evaluated. Lactobacillus paracasei DK215, Saccharomyces cerevisiae C3, and Acetobacter pasteurianus P2 were selected as the inoculants. Organic acids were measured every 3 days from the end of fermentation using HPLC; the organic acid content of LAB-inoculated Kombucha was relatively high. Samples with or without LAB inoculation showed high antibacterial activity against Escherichia coli. The MTT assay results indicated no significant difference in concentration difference and cell death. In the NO production test, compared with the uninoculated Kombucha sample, the LAB-inoculated Kombucha sample exhibited a value similar to that of the group without LPS treatment. The levels of cytokine (IL-1α, IL-6, TNF-α) production were significantly lower than those of the LPS(+) group, indicating the anti-inflammatory activity potential of the Kombucha sample. This improvement in the biological function of the LAB-inoculated Kombucha further verifies the value of LAB in the fermented food and beverage industry.