• 제목/요약/키워드: complex mixture analysis

검색결과 112건 처리시간 0.025초

순환유동층에서 폐수슬러지와 석탄의 혼소 특성 (Incineration of Waste Water Sludge and Coal In a Circulating Fluidized Bed Combustor)

  • 배달희;선도원;박재현;류호정;박도현
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2004년도 제28회 KOSCO SYMPOSIUM 논문집
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    • pp.165-172
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    • 2004
  • Co-incineration of coal and wastewater sludge was r;erfonn:rl in a O.lMWth bench scale circulating fluidized bed combustor(CFBC) Sludge was received from a wastewater treatment plant in a dye industrial complex in Busan. Metropolis. Moisture content of received sludge was 80%. Coal and sludge mixture was prepared with weight ratio of 90/10, 85/15 and 80/20. Co-combustion characteristics of the coal and sludge mixture demonstrated stable combustion conditions. Component analysis, incineration characteristics, boiler performance was measured before and after the test and application for commercial 59MWth CFBC boiler. The release of hazardous components such as $SO_2$ and Cl was suppressed by the presence of inherent minerals of Ca, Na, K in coal and sludge mixture. Pre-drying was not essential but it was recommended for the benefits of manageability of sludge.

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An Intelligent Automatic Early Detection System of Forest Fire Smoke Signatures using Gaussian Mixture Model

  • Yoon, Seok-Hwan;Min, Joonyoung
    • Journal of Information Processing Systems
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    • 제9권4호
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    • pp.621-632
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    • 2013
  • The most important things for a forest fire detection system are the exact extraction of the smoke from image and being able to clearly distinguish the smoke from those with similar qualities, such as clouds and fog. This research presents an intelligent forest fire detection algorithm via image processing by using the Gaussian Mixture model (GMM), which can be applied to detect smoke at the earliest time possible in a forest. GMMs are usually addressed by making the model adaptive so that its parameters can track changing illuminations and by making the model more complex so that it can represent multimodal backgrounds more accurately for smoke plume segmentation in the forest. Also, in this paper, we suggest a way to classify the smoke plumes via a feature extraction using HSL(Hue, Saturation and Lightness or Luminanace) color space analysis.

Application of Clustering Methods for Interpretation of Petroleum Spectra from Negative-Mode ESI FT-ICR MS

  • Yeo, In-Joon;Lee, Jae-Won;Kim, Sung-Hwan
    • Bulletin of the Korean Chemical Society
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    • 제31권11호
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    • pp.3151-3155
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    • 2010
  • This study was performed to develop analytical methods to better understand the properties and reactivity of petroleum, which is a highly complex organic mixture, using high-resolution mass spectrometry and statistical analysis. Ten crude oil samples were analyzed using negative-mode electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI FT-ICR MS). Clustering methods, including principle component analysis (PCA), hierarchical clustering analysis (HCA), and k-means clustering, were used to comparatively interpret the spectra. All the methods were consistent and showed that oxygen and sulfur-containing heteroatom species played important roles in clustering samples or peaks. The oxygen-containing samples had higher acidity than the other samples, and the clustering results were linked to properties of the crude oils. This study demonstrated that clustering methods provide a simple and effective way to interpret complex petroleomic data.

Form Follows Function - The Composite Construction and Mixed Structures in Modern Tall Buildings

  • Peng, Liu
    • 국제초고층학회논문집
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    • 제3권3호
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    • pp.191-198
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    • 2014
  • The tall building and super tall building has been a common building type in China, with multiple functions and complex geometry. Composite construction is broadly used in tall building structures and constitutes the mixed structure together with concrete and steel constructions. The mixture of the constructions is purposely designed for specific area based on the analysis results to achieve the best cost-effectiveness. New types of composite construction are conceived of by engineers for columns and walls. Material distribution is more flexible and innovative in the structural level and member level. However the reliability of computer model analysis should be verified carefully. Further researches in the design and build of composite construction are necessary to ensure the success of its application. Composite or Mixture Index is suggested to be used as a performance benchmark.

실내 분광 측정자료를 이용한 선형혼합모델의 오차 분석 (Error Analysis of Linear Mixture Model using Laboratory Spectral Measurements)

  • 김선화;신정일;신상민;이규성
    • 대한원격탐사학회지
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    • 제23권6호
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    • pp.537-546
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    • 2007
  • 초분광영상의 분석 기법 중 하나인 선형혼합분석기법은 각 화소를 구성하는 구성물질과 구성 비율을 추정하는데 매우 유용하게 사용되고 있다. 선형혼합모델은 지질 및 광물분포와 관련된 분야에서는 비교적 성공적으로 시도되고 있으나, 산림이나 여러 인공물들로 구성된 도시와 같은 상대적으로 복잡한 구조를 가진 혼합체에서는 그 정확도가 떨어진다. 본 연구에서는 식물과 토양의 혼합체를 대상으로 선형혼합모델을 적용하여 계산된 혼합체의 반사값과 실제 이 혼합체들을 분광측정기로 측정한 반사값과의 비교를 통해, 선형혼합모델의 오차를 계산하였다. 이를 통해 선형혼합모델의 오차 원인인 구성 물질간의 분광적 상호작용이 어느 경우 발생 혹은 증가하는지를 분석하고, 또한 파장대별 상호작용의 정도 차이가 있는지를 분석하였다. 연구 결과, 선형혼합모델은 혼합체를 구성하는 구성물질의 구성비율이 비슷한 경우, 각 구성 물질간의 상호작용이 증가하여 선형혼합모델의 오차가 가장 커지는 것을 알 수 있었다. 결과적으로 선형혼합모델의 오차 원인인 구성 물질간 상호작용의 발생 정도는 혼합체를 구성하는 성분의 종류, 반사 특성, 구성비율, 파장대와 구성 성분의 배열 상태에 따라 다르게 나타나는 것을 알 수 있었다. 향후 선형혼합모델의 정확도를 높이기 위해서는 이러한 혼합체의 특징들이 구성 물질간의 상호작용에 끼치는 영향을 정량적으로 분석하여야 할 것이다.

Oxidative Addition Reaction of Mono(aryl)cyanoplatinum(Ⅱ) Complex with Two Amino Ligands with the Dihalogens

  • Ko Jaejung;Kim Moonsik;Kim Seho;Shin Yookil
    • Bulletin of the Korean Chemical Society
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    • 제13권2호
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    • pp.135-139
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    • 1992
  • The mono(aryl)cyanoplatinum(II) complex $[Pt(CN)(C_6H_3{CH_2NMe_2}_2-26)]$, reacts with the dihalogens to yield the mono(aryl)cyanoplatinum complexes $[PtX_2(CN)(C_6H_3{CH_2NMe_2}_2-26)]$, (X = Cl, Br, I). The structural configuration of the two halogen atoms for a square planar platinum complex was studied by 1H-NMR spectroscopy and led to a mixture of trans and cis orientation. The trans orientation was found to be more stable in energy (1.33 kcal/mol) than the cis orientation by means of Extended H ckel calculations. On the base of a combination of the analysis of $^1H-NMR$, $^{13}C-NMR spectra and computational calculations it is assumed that the intermediate consists of an initial attack in the linear transition state, leading to the $S_{N}2$ type mechanism.

Characteristics of debris resulting from simulated molten fuel coolant interactions in SFRS

  • E. Hemanth Rao;Prabhat Kumar Shukla;D. Ponraju;B. Venkatraman
    • Nuclear Engineering and Technology
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    • 제56권1호
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    • pp.283-291
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    • 2024
  • Sodium cooled Fast Reactors (SFR) are built with several engineered safety features and hence a severe accident such as a core melt accident is hypothetical with a probability of <10-6/ry. However, in case of such accidents, the mixture of the molten fuel and structural materials interacts with sodium. This phenomenon is known as Molten Fuel Coolant Interaction (MFCI) and results in fragmentation of the melt due to various instabilities. The fragmented particles settle as a debris bed on the core catcher at the bottom of the reactor vessel, and continue to generate decay heat. Characteristics of the debris particles play a vital role in heat transfer from the bed and need thorough investigation. The size, shape, and physical state of the debris depend on the associated fragmentation mechanism, superheating of the melt, and sodium temperature. Experiments have been conducted by releasing simulated corium, a molten mixture of alumina and iron generated by the aluminothermy process at ~2400 ℃ into liquid sodium, to study the fragmentation phenomena. After the experiment, the fragmented debris was retrieved and the particle size distribution was determined by sieve analysis. The debris was subjected to microscopic investigation for obtaining morphological characteristics. Based on the characteristics of debris, an attempt has been made to assess of fragmentation mechanism of simulated corium in sodium.

Synthesis of Silica using Silk Sericin without Hydrolysis of Tetraethyl Orthosilicate

  • Lee, Ji Young;Lee, Ki Hoon
    • International Journal of Industrial Entomology and Biomaterials
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    • 제27권2호
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    • pp.298-302
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    • 2013
  • In this study, the effect of sericin on synthesis of the silica was investigated. Using the mixture of sericin solution and tetraethyl orthosilicate (TEOS), it was confirmed that silica could be synthesized in the presence of sericin, which was verified by thermal gravimetric analysis (TGA), Fourier-transformed infrared spectrometer (FT-IR) and nuclear magnetic resonance spectrometer (NMR) analysis. The TGA and FT-IR data revealed that silica-sericin complex was formed as a final product. Based on the TGA result, the content of silica and sericin in the complex would be 87 and 13%, respectively. The degree of silica condensation was higher than the natural biosilica. It could be concluded that sericin can induce the synthesis of silica directly from TEOS, which is similar to silicatein from marine sponges.

니켈도금액중의 붕산 신속정량법 (Rapid Analysis of Boric Acid in Nickel Plating Solutions)

  • 염희택
    • 한국표면공학회지
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    • 제3권1호
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    • pp.7-12
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    • 1970
  • Only mannitol or glycerine is generally used for the determination of boric acid in a nickel plating solution in order to make its acidic property so strong that it can be titrated with NaOH. However, these solutions give very amgiguous color change of indicator due to the precipitation of nickel salts . Therefore, only experienced dchemistsorwell trained workimen can accurately confirm the actual end point of the titratiion. For eliminating such interference of nickel salts and easily confirming the end point by any persons , the author attempted to find out a solution which produces no precipitates during the titration in these experiments, and also he tried to funish the reason for ambiguousness in titration. The following results were obtained after many experiments. (1) In any titrations which produce nickel salts such nI(oh)$_2$, the salt is formed umption very approximate to the end point, which shows some error by the consumption of titrant(NaOH) . Then, the pink color of phenolphthalein is absorbed by Ni(OH)$_2$ and the pH jumping at the end pint is also diminished to as little as less than 15% of the total phenophthalein ph range. (2) Known methods by complex salts of citrate,w hich do not produce precipitates of Ni(OH)$_2$, are also not very satisfactory, because, the pH jumping at the end point is only about 35% and the color change of phenolphthalein is form blue-green to purple-blue. (3) New method by complex salts of oxalate were attempted in these experiments. They also did not produce precipitates of Ni(OH)$_2$ and were very satisfactory in color change at the end of point was about 65% and the color change was from blue-green to purpled. In this methods, analytica cost was minimized by the use of less amounts of cheaper chemicals than the conventional citrates complex methods. The mixture of chemicals used was composed methods. The mixture of chemical used was composed of 37g/ι of sodium oxalate(Na$_2$C$_2$O$_4$$.$5H$_2$O), 2g/ι of phenolphthalein, and 400ml /ι of glycerin. The accuracy of analysis was within the error of 0.5%. (4) The procedure of analysis was as follows. One ml of nickel plating solution was taken out and to it were added 20ml of water and 20 ml of the above mixture for the indicator. The solution was titrated with 0.1N NaOH. The quantity of boric acid was calculated by the following equation. Boric acid (g/ι) = 6.184${\times}$F${\times}$ml .

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음향 데이터 전송 시스템의 강인한 데이터 검출 성능을 위한 Gaussian Mixture Model 기반 연구 (Data Detection Algorithm Based on GMM in the Acoustic Data Transmission System)

  • 송지현;장준혁;김문기;김동건
    • 대한전자공학회논문지SP
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    • 제48권4호
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    • pp.136-141
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    • 2011
  • 본 논문에서는 패턴 인식에서 우수한 성능을 보여주는 가우시안 혼합 모델을 이용하여 MCLT 기반 음향 데이터 전송 시스템의 데이터 검출 성능 향상을 위한 방법을 제안하였다. 기존의 MCLT 기반 음향 데이터 전송 시스템에 대해서 분석하고, 이를 기반으로 데이터 검출 알고리즘에서 우수한 성능을 보여주는 특징 벡터를 선택하여 GMM의 입력 벡터로 효과적으로 이용한다. 다양한 음원(rock, pop, classic, jazz)과 마이크-스피커 사이의 거리 (1∼5m)에서 시스템의 성능을 평가한 결과 GMM을 이용한 제안된 방법이 기존의 MCLT 기반 음향 데이터 전송 시스템의 데이터 검출 알고리즘보다 더욱 우수한 데이터 검출 성능을 보였다.