• Korean Journal of Soil Science and Fertilizer
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• v.48 no.1
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• pp.1-7
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• 2015

Global population is expected to reach nine billion in 2050 and the total demand for food is expected to increase approximately by 60 percent by 2050 as compared to 2005. Therefore, it is important to increase crop production in order to meet the global demand for food. Slow release fertilizers have been developed and designed in order to improve the efficiency of fertilizers. Mineral-based slow release fertilizers are useful because the minerals have a crystalline structure and are environmentally friendly in a soil. This review focuses on slow release fertilizers based on montmorillonite, zeolite, and layered double hydroxide phases as a host for nutrients, especially N. Urea was successfully stabilized in the interlayer space of montmorillonite by the formation of urea-Mg or Ca complex, $[(Urea)_6Mg\;or\;Ca]^{2+}$ protecting its rapid degradation in soils. Naturally occurring zeolites occluded with ammonium nitrate and potassium nitrate by molten salt treatment could be used as slow release fertilizer because the occlusion process increased the capacity of zeolites to store nutrients in addition to exchangeable cations. Additionally, surface-modified zeolites could also be used as slow release fertilizer because the modified surface showed high affinity for anionic nutrients such as nitrate and phosphate. Moreover, there were attempts to develop and use synthetic layered double hydroxide as a carrier of nitrate because it has positively charged layers which electrostatically bond nitrate anions. Kaolin was also tested by combining with a polymer or through the mechanical-chemical process for slow release of nutrients.

• Korean Journal of Organic Agriculture
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• v.19 no.spc
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• pp.178-181
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• 2011

The test was carried out at a test field at the Wanju Eco-Farming Complex from 2009 to 2010 to figure out the proper application of fertilizers when growing rice at the Eco-Farming Complex. The result showed that when compared to the basal application of compost as fertilizer, applying supplementary compost after natural re-seeding of chinese milk vetch (CMV) helped balance soil nutrition and maintained rice yields.

• Korean Journal of Soil Science and Fertilizer
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• v.51 no.2
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• pp.128-141
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• 2018

Industrial complex releasing huge amounts of dusts, fumes and wastewater containing heavy metal(loid)s could be a source of heavy metal(loid)s pollution in arable soil. Heavy metal(loid)s pollution in arable soil adversely affect crops safety, subsequently human being. Hence, it is important to accurately assess the heavy metal(loid)s pollution in soil using pollution indices. The objectives of this study are 1) to compare assessment methods of heavy metal(loid)s pollution in arable soils located near industrial complex in Gyeongsang provinces and 2) to determine the relationship between concentration of plant available heavy metal(loid)s and chemical properties of soil. Soil samples were collected from 85 sites of arable lands nearby 10 industrial complex in Gyeongsang provinces. The average total concentration of all heavy metal(loid)s of the studied soils was higher than that of Korean arable soils but did not exceed the warning criteria established by the Soil Environmental Conservation Act of Korea. Only six sites of arable soils for the total concentration of As, Cu and Ni exceeded the warning criteria (As: $25mg\;kg^{-1}$, Cu: $150mg\;kg^{-1}$, Ni: $100mg\;kg^{-1}$). The contamination factor (CF) and geoaccumulation index ($I_{geo}$) of the heavy metal(loid)s in arable soils varied among the sampling sites, and the average values of As and Cd were relatively higher than that of other metals. Results of integrated indices of As and Cd in arable soils located near industrial complex indicated that some arable soils were moderately or heavily polluted. The plant available concentration of heavy metal(loid)s was negatively related to the soil pH and negative charge of soil. Available Cd, Pb, and Zn concentrations had relatively high correlation coefficient with pH and negative charge of soil when compared with other heavy metal(loid)s. Based on the above results, it might be a good soil management to control pH with soil amendments such as lime and compost to reduce phytoavailability of heavy metal(loid)s in arable soil located near industrial complex.

• Korean Journal of Soil Science and Fertilizer
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• v.28 no.2
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• pp.114-122
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• 1995

Complexation experiment between humic acid and heavy metal cations was conducted to clear information on heavy metal adsorption by soil organic constituent. The absorbance of UV-visible light of humic acid-metal complexes increased with increasing wavelength, and the order of their absorbance was in the order of Zn->Cd->Cu- saturated humic acid. Carboxyl and phenolic OH groups participated in the complex formation between heavy metal cations and functional groups of humic acid, and the amounts complex was in the order of $Cu^{+{+}}$ > $Zn^{+{+}}$ $\geq$ $Cd^{+{+}}$. The stability constants of humic acid-metal complexes increased with increasing pH, and the order of first stability constants was $Zn^{+{+}}$ > $Cd^{+{+}}$ > $Cu^{+{+}}$, and those of second and overall stability constants were $Cu^{+{+}}$ > $Zn^{+{+}}$ > $Cd^{+{+}}$. With increasing pH, the average binding numbers betwen heavy metal cations and functional groups of humic acid increased the order of $Cu^{+{+}}$ > $Zn^{+{+}}$ > $Cd^{+{+}}$. It was postulated that two types of complexations between heavy metal cations and functional groups of humic acid. One was the reactions in which only carboxyl groups participated to form complexes, and the other was those in which both carboxyl and phenolic OH groups simultaneously participated.

• Korean Journal of Soil Science and Fertilizer
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• v.44 no.2
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• pp.297-302
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• 2011

Acid drainage generated by pyrite oxidation has caused the acidification of soil and surface water, the heavy metal contamination and the corrosion of structures in abandoned mine and construction sites. The applicability of Na-acetate (Na-OAc) buffer and/or Na-silicate solution was tested for suppressing pyrite oxidation by reacting pyrite containing rock and treating solution and by analyzing solution chemistry after the reaction. A finely ground Mesozoic andesite containing 10.99% of pyrite and four types of reacting solutions were used in the applicability test: 1) $H_2O_2$, 2) $H_2O_2$ and Na-silicate, 3) $H_2O_2$ and 0.01M Na-OAc buffer at pH 6.0, and 4) $H_2O_2$, Na-silicate and 0.01M Na-OAc buffer at pH 6.0. The pH in the solution after the reaction with the andesite sample and the solutions was decreased with increasing the initial $H_2O_2$ concentration but the concentrations of Fe and $SO_4^{2-}$ were increased 10 - 20 times. However, the pH of the solution after the reaction increased and the concentrations of Fe and $SO_4^{2-}$ decreased in the presence of Na-acetate buffer and with increasing Na-silicate concentration at the same $H_2O_2$ concentration. The solution chemistry indicates that Na-OAc buffer and Na-silicate suppress the oxidation of pyrite due to the formation of Fe-hydroxide and Fe-silicate complex and their coating on the pyrite surface. The effect of Na-OAc buffer and Na-silicate on reduction of pyrite oxidation was also confirmed with the surface examination of pyrite using scanning electron microscopy (SEM). The result of this study implies that the treatment of pyrite containing material with the Na-OAc buffer and Na-silicate solution reduces the generation of acid drainage.

• Korean Journal of Soil Science and Fertilizer
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• v.27 no.3
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• pp.226-231
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• 1994

This experiment was conducted to evaluate the effect of coated urea complex fertilizer(CUC) on the growth and quality of rice in high-ridged dry seeding and infant -seedling machine transplanting on clay loam and sandy loam in Milyang, Korea, 1993. The CUC level applicated was 100 %, 80 %, 60% and 40% to standard application amount of fertilizer. Results obtained were as follows : 1. The nitrogen releasing rate in dry seeding was 83% for sandy loam, 81% in clay loam for 3.5 months after initial releasing, and in infant-seedling was 89% in both soil types for 4 months. 2. The degree of rice leaf color was the highest at the heading stage, and was high with increasing CUC application level regardless of cultural methods, especially was higher at harvesting stage in the 100% level of CUC to standard application amount of fertilizer than conventional fertilizer. 3. The perfect rice grain ratio was higher in infant-seedling than in dry seeding, but lowered with increasing CUC application level regardless of cultural methods. The green kerneled rice ratio among imperfect rice grain was high in dry seeding, and the notched belly rice kernel ratio was high in infant-than infant-seedling of the both soil types, and increased with increasing CUC application level. 4. Hon-value in rice grain was higher at the treatment of CUC application than conventional fertilizer in dry seeding. However, it was contrary result in infant seedling, and was low tendency with decreasing CUC application. On the other hand, the protein in rice grain was also same tendency of Hon-value. Cel-consistency related to eating quality was longer with increasing CUC application level regardless of cultural methods. However, there was no clear tendency at clay loam. 5. No significant difference between rice yield and CUC application in the range of 60% to 100% at both soil types in dry seeding was observed. These results appeared in clay loam under infant seedling except sandy loam. Accordingly, it was thought that 60% level of CUC to standard application amount of fertilizer could be applicated for growth and quality of rice.

• Korean Journal of Soil Science and Fertilizer
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• v.19 no.4
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• pp.307-314
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• 1986

Cu(II) binding mechanisms with water soluble organic fractions (WSOF) extracted from an agricultural soil (W), a soil treated with sludge for 6 years ($WS_6$), a sludge-soil mixture incubated for one week ($WS_1$), and sewage sludge (SS) were studied by electron spin resonance (ESR) spectroscopy and potentiometric titrations. Cu(II)-WSOF complexes produced $g_{11}$ values which were larger than $g_{\perp}$ values, indicating that the coordination of Cu(II) complex was an elongated octahedron. At liquid $N_2$ temperature (77K), the Cu(II)-W complex showed an anisotropic ESR spectrum while the Cu(II)-SS complex showed an isotropic spectrum. These spectral results suggest that the oxygen donor ligands of W may form relatively strong bonds with $Cu^{2+}$ due to extensive chelation while ligands of SS may form little or no chelate bonds with $Cu^{2+}$. The ESR spectra of Cu(II)-SS complex also suggest that each of four in-plane ligands (e.g., $COO^-$, $H_2O$, $Cl^-$, etc.) may act independently as monodentate ligands. Oxygen donor ligands such as aromatic carboxyl groups were probably the major Cu(II) binding sites in W. Sulfonate, aliphatic carboxyl group, and N-containing ligands were probably the major binding sites in SS at pH 5. The Cu(II) complexation with N-containing groups increased as sludge was added to the soil. Much higher (6x) pyridine concentrations were required to displace W from Cu(II)-W complex as compared to the Cu(II)-SS complex.

• Current Research on Agriculture and Life Sciences
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• v.6
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• pp.105-112
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• 1988

Experiment was conducted to elucidate the effect of various nitrogen fertilizers on the growth and yield of soybean cv. Backwoon in field, and to examine soybeans produced with different nitrogen fertilizers for their nutritional constituents and protein digestibility. Soybean plants were generally similar in growth among fertilizers applied, and plants with non-nitrogen and with ammonium sulfate showed tendency to have fewer internodes. Nodule number and nodule weight also were lower in plants with non-nitrogen and with ammonium sulfate. Nitrogen fixation ability per nodule number were similar at an early growth stage and at flowering stage treatments and were relatively higher with newly developed complex fertilizer at pod elongation stage. With newly developed complex fertilizer and with non-nitrogen, there were slight increase and in 100 grain weight and yield per 10a, respectively. Crude protein contents in soybeans with nitrogen fertilizers were higher than that with non-nitrogen, and the reverse were true for crude fat. Crude ash contents were relatively similar among the treatment. Crude fiber contents were higher with readily used complex fertilizer than with the others. The contents of inorganic constituents were of the same sort among the treatments, that of Fe with non-nitrogen being much lower than with the others. Protein digestibility was the highest in the non-nitrogen treated soybean.

• KOREAN JOURNAL OF CROP SCIENCE
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• v.37 no.4
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• pp.383-396
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• 1992

In order to find out the reasons for the excessive accumulation of certain fertilizer elements in arable land in Korea, which may be a detrimental factor for her sustainable agriculture in the future, total requirement of fertilizers were estimated from the huge number of soil test data obtained throughout the country using the fertilizer requirement models based on the soil analysis data and the concepts of multi nutrient factor balance or starter fertiliazer. The total fertilizer requirements estimated based on the present soil fertility status were much less than those estimated from the suspected cropping area of various crops cultivated depending on the conventional fertilizer recommendation for each crops or the actual amount of fertilizer elements consumed through National Agricultural Cooporative Federation(NACF). The excessive accumulation of certain fertilizer elements in arable land in Korea must be due to excessively high dose of chemical fertilizers as well as those farm wastes such as animal wasts produced unexpectedly in large amounts or crop residues. And it is suggested that the improved fertilizer recommendation must be developed in consideration both with the soil fertility status and the amounts of nutrient removal by each crop, and that the high analyzed complex fertilizers commonly used by farmers must ugently be developed in a form containing low P and K with Mg and slow release type N for the better balanced management practices of soil fertility by farmers arid for their practices of sustainable agriculture.

• Asian Journal of Turfgrass Science
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• v.24 no.1
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• pp.36-44
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• 2010

We were investigated turf color and Normalized Difference Vegetation Index (NDVI) to affect greenup promotion of 38 cultivar in 5 species for spring season, most popularly used in Korea golf courses. Kentucky bluegrass (Poa pratensis L.), tall fescue (Festuca arundinacea Schreb), creeping bentrgass (Agrostis palustris Huds), perennial ryegrass (Lolium parenne L.) and zoysiagrass (Zoysia spp.) cultivar had higher leaf color for greenup promotion in Ami, Amx and Oligo than Con treatment and there were also significantly difference among treatments. Turfgrass NDVI also showed significant difference among cultivars in species. Spray of Ami, Amx and Oligo has the higher value of turf NDVI than Con. Based on our results, green up fast during spring season may affected much more with application of Ami, Amx and Oligo than Con.