• Title/Summary/Keyword: complex analytical method

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Development of a quantification method for modelling the energy budget of water distribution system (상수관망 에너지 모의를 위한 정량화 분석기법 개발)

  • Choi, Doo Yong;Kim, Sanghyun;Kim, Kyoung-Pilc
    • Journal of Korea Water Resources Association
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    • v.55 no.spc1
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    • pp.1223-1234
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    • 2022
  • Efforts for reducing greenhouse gas emission coping with climate change have also been performed in the field of water and wastewater works. In particular, the technical development for reducing energy has been applied in operating water distribution system. The reduction of energy in water distribution system can be achieved by reducing structural loss induced by topographic variation and operational loss induced by leakage and friction. However, both analytical and numerical approaches for analyzing energy budget of water distribution system has been challengeable because energy components are affected by the complex interaction of affecting factors. This research drew mathematical equations for 5 types of state (hypothetical, ideal, leak-included ideal, leak-excluded real, and real), which depend on the assumptions of topographic variation, leakage, and friction. Furthermore, the derived equations are schematically illustrated and applied into simple water network. The suggested method makes water utilities quantify, classify, and evaluate the energy of water distribution system.

Oligotrophic Media Compared with a Tryptic Soy Agar or Broth for the Recovery of Burkholderia cepacia Complex from Different Storage Temperatures and Culture Conditions

  • Ahn, Youngbeom;Lee, Un Jung;Lee, Yong-Jin;LiPuma, John J.;Hussong, David;Marasa, Bernard;Cerniglia, Carl E.
    • Journal of Microbiology and Biotechnology
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    • v.29 no.10
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    • pp.1495-1505
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    • 2019
  • The Burkholderia cepacia complex (BCC) is capable of remaining viable in low-nutrient environments and harsh conditions, posing a contamination risk in non-sterile pharmaceutical products as well as a challenge for detection. To develop optimal recovery methods to detect BCC, three oligotrophic media were evaluated and compared with nutrient media for the recovery of BCC from autoclaved distilled water or antiseptic solutions. Serial dilutions ($10^{-1}$ to $10^{-12}CFU/ml$) of 20 BCC strains were inoculated into autoclaved distilled water and stored at $6^{\circ}C$, $23^{\circ}C$ and $42^{\circ}C$ for 42 days. Six suspensions of Burkholderia cenocepacia were used to inoculate aqueous solutions containing $5{\mu}g/ml$ and $50{\mu}g/ml$ chlorhexidine gluconate (CHX) and $10{\mu}g/ml$ benzalkonium chloride (BZK), and stored at $23^{\circ}C$ for a further 199 days. Nutrient media such as Tryptic Soy Agar (TSA) or Tryptic Soy Broth (TSB), oligotrophic media (1/10 strength TSA or TSB, Reasoner's $2^{nd}$ Agar [R2A] or Reasoner's $2^{nd}$ Broth [R2AB], and 1/3 strength R2A or R2AB) were compared by inoculating these media with BCC from autoclaved distilled water and from antiseptic samples. The recovery of BCC in water or antiseptics was higher in culture broth than on solid media. Oligotrophic medium showed a higher recovery efficiency than TSA or TSB for the detection of 20 BCC samples. Results from multiple comparisons allowed us to directly identify significant differences between TSA or TSB and oligotrophic media. An oligotrophic medium pre-enrichment resuscitation step is offered for the United States Pharmacopeia (USP) proposed compendial test method for BCC detection.

Studies on the Determination of Heavy Metal Ions by Flow Injection, the Photochemical Characterization and Polymerization of Eight-Coordinated Complex(Part I): Spectrophotometric Determination of Uranium and Thorium Ions by Flow Injection Analysis using Chrome Azurol S in the Presence of Surfactant (금속이온의 흐름주입법에 의한 정량, 8-배위착물의 광학적 특성 및 중합체에 관한 연구(제1보): 계면활성제 존재하에서 Chrome Azurol S를 사용하여 우라늄 및 토륨이온의 흐름 주입법에 의한 분광광도 정량)

  • Chang, Choo-Hwan;Kang, Sam-Woo;Son, Byung-Chan;Cho, Kwang-Hee
    • Analytical Science and Technology
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    • v.8 no.1
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    • pp.1-7
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    • 1995
  • Spectrophotometric determination of U(VI) and Th(IV) by Flow injection method is described. Chrome Azurol S forms water soluble complexes with U(VI) and Th(IV) in the presence of cethyltrimethylammonium bromide. The maximum adsorption of U(VI) and Th(IV) complexes are at 600nm with molar absorptivity of $2.3{\times}10^5Lmol^{-1}cm^{-1}$ and 611nm with molar absorptivity of $3.8{\times}10^5Lmol^{-1}cm^{-1}$ in acetate buffer medium having pH 5.0 and 5.5. The calibration curves of U(VI) and Th(IV) are linear over the range of 0.1~0.8ppm and the correlation coefficients are ca. 0.9960 and 0.9930 respectively. The detection limits(S/N) are 20ppb for U(VI) and 15ppb for Th(IV). The relative standard deviation are ${\pm}1.8%$ for U(VI) and ${\pm}2.1%$ for Th(IV). The sample throughput was ca. $50hr^{-1}$.

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Solvent Extraction of Trace Amount of Ni(II) in Sea Water by using Salen[N,N'-bis(salicylidene)ethylenediamine] (Salen[N,N'-bis(salicylidene)ethylenediamine]을 이용한 해수 중 극미량 니켈의 용매추출)

  • In, Gyo;Choi, Jong-Moon;Kim, Young-Sang
    • Analytical Science and Technology
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    • v.17 no.6
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    • pp.481-488
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    • 2004
  • Solvent extraction of Ni(II) into a chloroform by using salen[N,N'-Bis (salicylidene)-ethylenediamine] as a ligand has been studied. Salen was synthesized from ethylenediamine and salicylaldehyde by simple condensation reaction in an ethanol. Salen formed a 1 : 1 complex with Ni(II) and its extraction constant was $10^{5.12}$. For the determination of Ni(II) in sea water samples, some experimental conditions such as pH of solution, amount of salen, acid type and concentration for back extraction, extraction time, and influence of foreign ions were optimized by using a synthetic sea water. The sea water of which the composition was similar to a natural sea water was synthesized in this laboratory. Trace Ni(II) was extracted into the chloroform in the weak basic solution above pH 8. And the nickel could be quantitatively extracted with the concentration of salen higher than $1.2{\times}10^{-4}mol/L$. This concentration was more than 180 times of Ni(II) in the solution with a mole ratio. Real samples of Korean coastal sea water were analyzed under optimized conditions. Even though Ni(II) was not detected in these samples. Recoveries more than 98% were obtained in the samples which 40 ng/mL of Ni(II) was spiked. And detection limit of proposed method was 1.3 ng/mL. From these results, it could be known that salen of this type would be applied for the determination of trace metals as an organic chelating reagent.

Determination Method of Hydrocarbon Compounds in DME-LPG Blending Fuels by Gas Chromatography with Deans Switching (Deans Switching을 이용한 가스크로마토그래피에서 DME-LPG 혼합연료의 탄화수소 화합물 분석방법)

  • Youn, Ju Min;Park, Cheon Kyu;Yim, Eui Soon;Jung, Choong Sub
    • Korean Chemical Engineering Research
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    • v.50 no.2
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    • pp.353-357
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    • 2012
  • The new qualitative and quantitative analytical method for hydrocarbon compounds in DME-LPG blending fuel, mixing dimethyl ether (DME) with liquefied petroleum gas (LPG), by using gas chromatography (GC) was investigated. It is difficult to analyze all components of DME-LPG blending fuel by using single column in GC due to consisting of the non-polar LPG and the polar DME which is oxygen-containing compound. Therefore, it has been introduced the Deans switching system, which are useful for analyzing mixtures of a very different nature and/or target analytes in very complex matrix. This technique is to control the pressure between two columns and to selectively change the path of effluent flows to either one of two columns. As a result, we found that DME and LPG can be completely separated at the different columns and the determination of all hydrocarbon compounds in DME-LPG blending fuel can be achieved to this method qualitatively and quantitatively during the operation of one injection. In addition, this method can be applied to the determination of trace components of by-product, such as methanol, methyl formate and ethyl methyl ether, which will be derived from DME synthesis process.

Mechanical Behavior of Cable Net Structures Considering Sag Ratio (새그 비를 고려한 케이블 네트 구조물의 역학적 거동)

  • Park, Kang-Geun;Lee, Dong-Woo
    • Journal of Korean Association for Spatial Structures
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    • v.16 no.3
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    • pp.47-58
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    • 2016
  • Cable network system is a flexible lightweight structure which curved cables can transmit only tensile forces. The weight of cable roof dramatically can reduce when the length becomes large. The cable network system is too flexible, most cable systems are stabilized by pretension forces. The tensile force of cable system is greatly influenced by the sag ratio and pretension forces. Determining initial sag ratio of cable roof system is essential in a design process of cable structures. Final sag ratio and pretension depends on initial installed sag and on proper handling during installation. The design shape of cable system has an affect on the sag and pretension, and must be determined using well-defined design philosophy. This paper is carried out the comparative data of the deflection and tensile forces on the geometric non-linear analysis of cable network systems according to sag ratio. The study of cable network system is provided to technical informations for the design of a large span cable roof, analytical results are compared with the results of other researchers. Structural nonlinear analysis of systems having cable elements is relatively complex than other rigid structural systems because displacements are large as a reason of flexibility, initial prestress is applied to cables in order to increase the rigidity, and then divergence of nonlinear analysis occurs rather frequently. Therefore, cable network systems do not exhibit a typical nonlinear behavior, iterative method that can handle geometric nonlinearities are necessary.

Unconscious Response Characteristics of Pupils in the Observation toward to Spatial Image (공간이미지를 향한 주시에 나타난 동공의 무의식적 반응 특성)

  • Kim, Jong-Ha
    • Korean Institute of Interior Design Journal
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    • v.27 no.3
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    • pp.136-144
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    • 2018
  • The purpose of this study is to examined the unconscious response of the pupil in the observation toward the image in the eye-tracking experiments that target on a large complex cultural space. Twenty-five men participated in this experiment and the observation data were analyzed in seconds per minute on watching time. It could examine the unconscious response of information searching in the change of pupil size in the process of observing the space. The results could be defined as following several points. First, it was possible to outline the unconscious response characteristics of pupil by analyzing sudden changes in pupil size as total, cumulative, and individual. The response characteristics using frequency and time can be utilized as the analytical method to examine the degree of interest of spatial components according to the purpose of analysis in the future. Second, according to the over ${\pm}5%$ of cumulative variation rate on the pupil size change, during in the 60 seconds, the continuous pupil dilation was used 25.2 seconds in 8.8 rounds and the pupil reduction was used 18.0 seconds in 7.0 rounds. Third, when the variation rate of ${\pm}5%$ or more was regarded as the sudden changes on pupil size by individual variation, the pupil dilation was 7.2 rounds of 8.6 seconds and pupil reduction was 6.0 seconds in 5.0 rounds. This means that the pupil increases 9.3% in one expansion and decreases -8.5% in the reduction process. As regarding pupil changes as cumulative rate, it appeared high change rate on pupil reduction but it became higher on pupil dilation in individual.

Computer aided failure prediction of reinforced concrete beam

  • Islam, A.B.M. Saiful
    • Computers and Concrete
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    • v.25 no.1
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    • pp.67-73
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    • 2020
  • Traditionally used analytical approach to predict the fatigue failure of reinforced concrete (RC) structure is generally conservative and has certain limitations. The nonlinear finite element method (FEM) offers less expensive solution for fatigue analysis with sufficient accuracy. However, the conventional implicit dynamic analysis is very expensive for high level computation. Whereas, an explicit dynamic analysis approach offers a computationally operative modelling to predict true responses of a structural element under periodic loading and might be perfectly matched to accomplish long life fatigue computations. Hence, this study simulates the fatigue behaviour of RC beams with finite element (FE) assemblage presenting a simplified explicit dynamic numerical solution to show computer aided fatigue behaviour of RC beam. A commercial FEM package, ABAQUS has been chosen for this complex modelling. The concrete has been modelled as a 8-node solid element providing competent compression hardening and tension stiffening. The steel reinforcements are simulated as two-node truss elements comprising elasto-plastic stress-strain behaviour. All the possible nonlinearities are duly incorporated. Time domain analysis has been adopted through an automatic Newmark-β time incremental technique. The program consists of twelve RC beams to visualize the real behaviour during fatigue process and to obtain the reliability of the study. Both the numerical and experimental results indicate a redistribution of stresses along the time and damage accumulation of beam which severely affect the serviceability and ultimate capacity of RC beam. The output of the FEM analysis demonstrates good match with the experimental consequences which affirm the efficacy of the computer aided model. The controlled fatigue damage evolution at service fatigue load limits makes the FE model an efficient tool in predicting high cycle fatigue behaviour of RC structures.

Analysis of the Flow Field of Carrier-Based Aircraft Exhaust Jets Impact on the Flight Deck

  • Yue, Kuizhi;Sun, Yicheng;Liu, Hu;Guo, Weigang
    • International Journal of Aeronautical and Space Sciences
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    • v.16 no.1
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    • pp.1-7
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    • 2015
  • In order to provide some references for suitability of carrier-based aircrafts, this paper studies the flow field of exhaust jets and its impact on the flight deck. The geometrical models of aircraft carrier and carrier-based aircrafts are firstly built, on which unstructured tetrahedral meshes are generated for numerical analysis. Then, this paper simulates the flow field of exhaust jets to evaluate its impact on the Jet Blast Deflector (JBD) and the flight deck, when four carrier-based aircrafts are ready to start off in the bow. The standard k-${\varepsilon}$ equations, three-dimension N-S equations and the Computational Fluid Dynamics (CFD) theory are used in the analysis process. To solve the equations, the thermal coupling of the wind and the jet flow are also considered. The velocity and temperature distributions are provided with the simulation of the CFD software, FLUENT. The results indicate that: (1) this analytical method can be used to simulate aerodynamic problems with complex geometrical models, and the results are of high reliability; (2) the safety working area, the installation scheme of the JBD and the arrangement of the take-off position can be optimized through analysis.

Determination of Fermentation Specific Carcinogen, Ethyl Carbamate, in Kimchi (김치에서 발효 식품의 고유 발암원 Ethyl Carbamate 검출)

  • Koh, Eun-Mi;Kwon, Hoon-Jeong
    • Korean Journal of Food Science and Technology
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    • v.28 no.3
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    • pp.421-427
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    • 1996
  • Ethyl carbamate is an animal carcinogen and a suspected human carcinogen found in fermented foods and beverages. For the determination of ethyl carbamate in typical Korean diet, an analytical method was established for the food as complex as Kimchi. Kimchi samples collected from various locations in the country were homogenized and extracted four times with ethyl acelate. Following concentration and reconstitution with water, the extract was loaded onto $C_{18}$ column. Fraction containing ethyl carbamate was eluted with methanol, while most of the red pigment of the sample was retained on the column. The eluent was further purified with alumina, followed by Florisil column. The final eluent was analyzed by gas chromatography mass spectrometry in the selected ion monitoring mode. None of the twenty Kimchi samples showed ethyl carbamate level higher than 4.6 ppb without correction for the recovery. The concentration of ethyl carbamate in Kimchi increased as pH decreased, suggesting fermentation dependent formation of ethyl carbamate.

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