• KSCE Journal of Civil and Environmental Engineering Research
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• v.13 no.4
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• pp.65-75
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• 1993

Presented is a method for nonstationary response analysis of an offshore guyed tower subjected to strong earthquake motions under moderate random waves and current loadings. By taking the time varying envelope function and the auto-correlation function of the ground acceleration in terms of complex exponential functions, an analytical procedure is developed for computing time varying variances of the tower response. The stationary responses due to small random waves are obtained by using frequency domain method, and the results are combined with the nonstationary results due to earthquakes. Finally, the expected maximum responses are estimated. Through the example analyses, the nonstationary method developed in this study is verified, and the contributions of the earthquake, wave and current loadings to the total maximum response are investigated.

• Computers and Concrete
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• v.15 no.1
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• pp.103-126
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• 2015

Thermal effects are significant loads for assessing concrete dam behaviour during operation. A new methodology to estimate thermal loads on concrete dams taking into account processes which were previously unconsidered, such as: the evaporative cooling, the night radiating cooling or the shades, has been recently reported. The application of this novel approach in combination with a three-dimensional finite element method to solve the heat diffusion equation led to a precise characterization of the thermal field inside the dam. However, that approach may be computationally expensive. This paper proposes the use of a new one-dimensional model based on an explicit finite difference scheme which is improved by means of the reported methodology for computing the heat fluxes through the dam faces. The improved model has been applied to a case study where observations from 21 concrete thermometers and data of climatic variables were available. The results are compared with those from: (a) the original one-dimensional finite difference model, (b) the Stucky-Derron classical one-dimensional analytical solution, and (c) a three-dimensional finite element method. The results of the improved model match well with the observed temperatures, in addition they are similar to those obtained with (c) except in the vicinity of the abutments, although this later is a considerably more complex methodology. The improved model have a better performance than the models (a) and (b), whose results present larger error and bias when compared with the recorded data.

• Journal of the Korean Geotechnical Society
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• v.38 no.4
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• pp.5-20
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• 2022

To analyze the flow and density variations in debris flows, a two-phase finite volume model simplified with momentum equations was constructed in this study. The Hershel-Buckley rheology model was employed in this model to account for the internal and basal friction of debris flows and was utilized to analyze complex topography and entrainments of basal soil beds. In order to numerically solve the debris flow analysis model, a finite volume model with the Harten-Lax-van Leer-Contact method was used to solve the conservation equation for the debris flow interface. Case studies of circular dam failure, non-Newtonian fluid dam failure, and multiple debris flows were analyzed using the proposed model to evaluate shock absorption capacity, numerical isotropy, model accuracy, and mass conservation. The numerical stability and correctness of the debris flow analysis of this analysis model were proven by the analysis results. Additionally, the rate of debris flow with various rheological properties was systematically simulated, and the effect of debris flow rheological properties on behavior was analyzed.

• Journal of the Korean earth science society
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• v.40 no.6
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• pp.654-670
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• 2019

From the perspective of science gifted education, the successful intelligence theory is a means to understand how the gifted education curriculum reflects the characteristics of science gifted students. The purpose of this study is to investigate if the successful intelligence is fully reflected in the teaching materials of two gifted education centers (GECDOE: Gifted Education Center affiliated with District Office of Education, GSEIU: Gifted Science Education Institute attached to University). For this study, we selectively used 143 (GECDOE) and 134 questions (GSEIU) from the teaching materials of two gifted education centers. Those questions is analyzed through the semantic network analysis method. The results are as follow. First, the teaching materials of two gifted education centers are not evenly reflected in the successful intelligence, such as analytical ability, creative ability, and practical ability. Second, the teaching materials of two gifted education centers intensively demands analytical ability for students such as 'identify problem', 'represent and organize information', and 'additional prompts for analytical thinking'. Third, the teaching materials of two gifted education centers are presented to students without linking each frame of successful intelligence to one another. As the gifted students are quick to learn and show a preference for more complex thinking, it is necessary to develop teaching materials to experience the various abilities and promote integrated thinking according to the level of the gifted students. In this respect, this study is expected to be used as useful information for developing teaching materials to support customized education for gifted students.

• Journal of the Korean Society of Groundwater Environment
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• v.3 no.2
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• pp.51-59
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• 1996

In case waste disposal site is to be constructed close to the underground facilities such as LPG storage cavern which is completely maintained by groundwater pressure, it is generally requested that the possibility on leachate contamination of cavern area be reviewed and the countermeasure, if it is estimated cavern area is severely affected by leachate, be taken into consideration. Prediction was performed and leachate control plan was made using by analytical and the numerical analysis on the leachate migration which is likely to happen at the area between the proposed waste disposal site and the underground LPG storage cavern located at the U petrochemical complex. Analytical solutions were obtained by the conservative mass advection-diffusion equation and the effect of advection and dispersion factor on the leachate migration was reviewed through peclet number calculation and the functional relationship between the factors and leachate transport velocity was established, which leads to enable us to predict the leachate transport velocity without difficulties when different parameters (factors) are used for analytical solution. Numerical solutions were obtained by FEM using AQUA2D which is for the simulation of groundwater flow and contaminant transport. 3-D discrete fracture models were simulated and fracture flow analysis was performed and feasibility study on the water-curtain system was conducted through the fracture connectivity analysis in rock mass. As results of those analyses, it was interpreted that the leachate would trespass on the LPG storage cavern area in 30 years from the proposed wate disposal site and the vertical water-curtain system was effective mathod for the prevention of leachate's migration further into the cavern area.

• Analytical Science and Technology
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• v.34 no.6
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• pp.241-250
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• 2021

Calibration curves are essential in quantitative methods and for improving the accuracy of analyte measurements in biological samples. In this study, a statistical analysis model built in the R language (The R Foundation for Statistical Computing) was used to identify a set of weighting factors and regression models based on a stepwise selection criteria. An LC-MS/MS method was used to detect the presence of urinary methamphetamine, amphetamine, and 11-nor-9-carboxy-Δ⁹ -tetrahydrocannabinol in a sample set. Weighting factors for the calibration curves were derived by calculating the heteroscedasticity of the measurements, where the presence of heteroscedasticity was determined via variance tests. The optimal regression model and weighting factor were chosen according to the sum of the absolute percentage relative error. Subsequently, the order of the regression model was calculated using a partial variance test. The proposed statistical analysis tool facilitated selection of the optimal calibration model and detection of methamphetamine, amphetamine, and 11-nor-9-carboxy-Δ⁹-tetrahydrocannabinol in urine. Thus, this study for the selection of weighting and the use of a complex regression equation may provide insights for linear and quadratic regressions in analytical and bioanalytical measurements.

• Analytical Science and Technology
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• v.22 no.6
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• pp.514-518
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• 2009

Coenzyme $Q_{10}$($CoQ_{10}$), a vitamin E-like substance, represents a components of the complex antioxidant system of the human organism. $CoQ_{10}$ levels in human plasma were determined by high performance liquid chromatography (HPLC) with UV detection. It was dissociated from lipoproteins by methanol and extracted into n-hexane with liquid-liquid extraction procedure, after centrifugation, the supernatant was dried under nitrogen gas stream. The residue was dissolved in the absolute ethanol. Determination of $CoQ_{10}$ was performed on a $C_{18}$ reversed-phase analytical column with ultraviolet detection at 275 nm and the mobile phase containing 15% (v/v) ethanol in methanol at a flow rate of 1.7 mL/min. The low limit of quantitation was 0.02 mg/L (S/N=10), the linearity between the concentration and peak height is from 0.1 to 2.0 mg/L. Twenty-four randomly selected plasma samples from apparently healthy, 27 to 44 year old individuals (males and females) were analyzed for total $CoQ_{10}$. The average level in these subjects was $0.62{\pm}0.13mg/L$ with the range of 0.41-0.98 mg/L. This method has a specific and a sufficient limit of quantitation (LOQ) for analysis of $CoQ_{10}$ in human plasma in both a clinical study and research at laboratories.

• Bulletin of the Korean Chemical Society
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• v.30 no.12
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• pp.3011-3015
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• 2009

Structural and thermo-analytical studies were carried out to understand the phase formation kinetics of the single phase $Bi_5Ti_3FeO_{15}$ (BTFO) nanocrystals in $Bi_2O_3-Fe_2O_3-TiO_2$, during the polymerized complex (PC) synthesis method. The crystallization of Aurivillius phase $Bi_5Ti_3FeO_{15}$ layered perovskite was found to be initiated and achieved under the temperature conditions in the range of ${\sim}$800 to 1050$^{\circ}C$. The activation energy for grain growth of $Bi_5Ti_3FeO_{15}$ nanocrystals (NCs) was very low in case of NCs formed by PC (2.61 kJ/mol) than that formed by the solid state reaction (SSR) method (10.9 kJ/mol). The energy involved in the phase transformation of Aurivillius phase $Bi_5Ti_3FeO_{15}$ from $Bi_2O_3-Fe_2O_3-TiO_2$ system was ${\sim}$ 69.8 kJ/mol. The formation kinetics study of $Bi_5Ti_3FeO_{15}$ synthesized by SSR and PC methods would not only render a large impact in the nanocrystalline material development but also in achieving highly efficient visible photocatalysts.

• Journal of Korean Society of Transportation
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• v.25 no.3
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• pp.145-154
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• 2007

Determining stop spacing is a very important process in transit system planning. This study is involved in an analytical approach to decide the transit stop spacing. Transit stop spacing should be longer as 1) user access speed, 2) user travel time, and 3) dwell time increase, and shorter as 1) passengers (boardings and alightings) and 2) headway increase. In this study, a methodology is proposed to determine transit stop spacing to minimize total cost (user cost plus operator cost) with irregular passenger distribution (boardings and alightings) Without considering in-vehicle passengers, the transit stop spacing should be shorter in the concentrated sections of the passenger distribution than in others to minimize total cost. Through the conceptual analysis, it is verified that the transit stop spacing could be longer as the in-vehicle passengers increase in certain sections. This study proposes a simple practical method to determine transit stop spacing and locations instead of a dynamic programming method which generally includes a complex and difficult calculation. If the space axis is changed to a time axis. the methodology of this study could be expanded to analyze a solution for the transit service (or headway) schedule problem.

• Analytical Science and Technology
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• v.30 no.6
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• pp.405-410
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• 2017

High energetic materials (HEMs) have been used in fuels, civil engineering and architecture as well as military purposes such as explosives and propellants. The essential process for the development of new energetic compounds is to accurately calculate its detonation performances. The most typical equation for calculating the explosive performance is the Kamlet-Jacobs (K-J) equation. In the K-J equation, the parameter such as the number of moles of gaseous products at the explosion, the average molar mass of gas products, and the explosion heat greatly affect the explosion performance. These depend on the product composition for the detonation reaction. In this study, detonation products of 65 high energetic molecules (HEMs) were calculated from the various rules such as Kamlet-Jacobs, Kistiakowsky-Wilson, modified Kistiakowsky-Wilson, Springall-Roberts rules to calculate more accurate detonation velocity (Dv). In addition, they were applied to five kinds of detonation velocity equations proposed by K-J, Rothstein, Xiong, Stine and Keshavarz. The mean absolute error and root mean square error of HEMs were obtained from experimental and calculated velocity value for each method. The K-J and Xiong equation that is slightly complex showed a lower mean absolute error than the simple Rothstein and Keshavarz equation. When the mod-KW rule was applied to the Xiong equation, the detonation velocities were the most accurate. This study compared the various method of calculating the detonation velocity of HEMs to obtain accurate HEMs performance.