• Title/Summary/Keyword: complex analytical method

Search Result 431, Processing Time 0.026 seconds

The Use of Phenanthraquinone Monophenyl Thiosemicarbazone for Preconcentration, Ion Flotation and Spectrometric Determination of Zinc(II) in Human Biofluids and Pharmaceutical Samples

  • Akl, Magda Ali
    • Bulletin of the Korean Chemical Society
    • /
    • v.27 no.5
    • /
    • pp.725-732
    • /
    • 2006
  • A rapid flotation methodology for zinc(II) separation and enrichment from human biofluids is established. At pH 6.0 and ambient temperature, using oleic acid (HOL) as a foaming reagent, zinc(II) was separated with phenanthraquinone monophenyl thiosemicarbazone (PPT) as a new flotation collector for Zn(II). The floated red colored 1 : 2 Zn(II)-PPT complex was measured spectrophotometrically at 526 nm with a molar absorptivity of $1.83 \;{\times}\; 10^5\; L$ mol $L ^{-1}\;cm ^{-1}$. Beer's law was obeyed over a concentration range 0.05-1.0 mg $L ^{-1}$ in the aqueous as well as in the scum layers. The proposed preconcentration flotation methodology was applied to determine Zn(II) in human biofluids. Application was, also, extended to determine Zn(II) in pharmaceutical samples and natural water samples spiked with known amounts of Zn(II) with a preconcentration factor of 100 and a detection limit of 10 ng m$L ^{-1}$. The method was verified by comparison of the spectrophotometric results with flame atomic absorption spectrometric (AAS) measurements. Moreover a postulation for the mechanism of flotation is proposed.

Quantification of Plant Safety Status

  • Cho, Joo-Hyun;Lee, Gi-Won;Kwon, Jong-Soo;Park, Seong-Hoon;Na, Young-Whan
    • Nuclear Engineering and Technology
    • /
    • v.28 no.5
    • /
    • pp.431-439
    • /
    • 1996
  • In the process of simplifying the complex fate of the plant into a binary state, the information loss is inevitable. To minimize the information loss, the quantification of plant safety status has been formulated through the combination of the probability density function arising from the sensor measurement and the membership function representing the expectation of the state of the system. Therefore, in this context, the safety index is introduced in an attempt to quantify the plant status from the perspective of safety. The combination of probability density function and membership function is achieved through the integration of the fuzzy intersection of the two functions, and it often is not a simple task to integrate the fuzzy intersection due to the complexity that is the result of the fuzzy intersection. Therefore, a methodology based on the Algebra of Logic is used to express the fuzzy intersection and the fuzzy union of the arbitrary functions analytically. These exact analytical expressions are then numerically integrated by the application of Monte Carlo method. The benchmark tests for rectangular area and both fuzzy intersection and union of two normal distribution functions have been performed. Lastly, the safety index was determined for the Core Reactivity Control of Yonggwang 3&4 using the presented methodology.

  • PDF

A Study on Distribution Property of Micropollutants in Gwang-Yang Bay Sediment (광양만 저질에서의 미량오염물질 분포특성에 관한 연구)

  • Han Sang-Kuk;Park Ji-Young
    • Journal of Environmental Science International
    • /
    • v.15 no.7
    • /
    • pp.643-651
    • /
    • 2006
  • This study investigated the distributive property of micropollutants in sediment around Gwang-yang bay using simultaneous analytical method of 310 chemicals. In the results, the major micropollutants detected were CH type chemicals such as aliphatic, polycyclic compounds, benzenes, and CHN(O) type chemicals aromatic amines, and pesticides. Insecticides of pesticide type were frequently detected at all sampling site. The total concentration of micropollutants were higher in summer than in winter and measured within the range of $ND{\sim}36.50{\mu}g/L$. Also, because of effect of seomjin river, GY6 of all sampling site detected by the highest concentration, GY10 and 11 located in Gwang-yang outside bay were not detected the micropollutants. From the result of this study, we should estimated that the industrial complex located in Gwang-yang inside bay and an inflow of fresh water through the Seomjin river are major pollution sources of Gwang-yang bay.

Pareto Optimized EDCA Parameter Control for Wireless Local Area Networks

  • Kim, Minseok;Oh, Wui Hwan;Chung, Jong-Moon;Lee, Bong Gyou;Seo, Myunghwan;Kim, Jung-Sik;Cho, Hyung-Weon
    • KSII Transactions on Internet and Information Systems (TIIS)
    • /
    • v.8 no.10
    • /
    • pp.3458-3474
    • /
    • 2014
  • The performance of IEEE 802.11e enhanced distributed channel access (EDCA) is influenced by several interactive parameters that make quality of service (QoS) control complex and difficult. In EDCA, the most critical performance influencing parameters are the arbitration interframe space (AIFS) and contention window size (CW) of each access category (AC). The objective of this paper is to provide a scheme for parameter control such that the throughput per station as well as the overall system throughput of the network is maximized and controllable. For this purpose, a simple and accurate analytical model describing the throughput behavior of EDCA networks is presented in this paper. Based on this model, the paper further provides a scheme in which a Pareto optimal system configuration is obtained via an appropriate CW control for a given AIFS value, which is a different approach compared to relevant papers in the literature that deal with CW control only. The simulation results confirm the effectiveness of the proposed method which shows significant performance improvements compared to other existing algorithms.

Earthquake risk assessment methods of unreinforced masonry structures: Hazard and vulnerability

  • Preciado, Adolfo;Ramirez-Gaytan, Alejandro;Salido-Ruiz, Ricardo A.;Caro-Becerra, Juan L.;Lujan-Godinez, Ramiro
    • Earthquakes and Structures
    • /
    • v.9 no.4
    • /
    • pp.719-733
    • /
    • 2015
  • Seismic risk management of the built environment is integrated by two main stages, the assessment and the remedial measures to attain its reduction, representing both stages a complex task. The seismic risk of a certain structure located in a seismic zone is determined by the conjunct of the seismic hazard and its structural vulnerability. The hazard level mainly depends on the proximity of the site to a seismic source. On the other hand, the ground shaking depends on the seismic source, geology and topography of the site, but definitely on the inherent earthquake characteristics. Seismic hazard characterization of a site under study is suggested to be estimated by a combination of studies with the history of earthquakes. In this Paper, the most important methods of seismic vulnerability evaluation of buildings and their application are described. The selection of the most suitable method depends on different factors such as number of buildings, importance, available data and aim of the study. These approaches are classified in empirical, analytical, experimental and hybrid. For obtaining more reliable results, it is recommends applying a hybrid approach, which consists of a combination between methods depending on the case. Finally, a recommended approach depending on the building importance and aim of the study is described.

Optimal Design of Lightweight Two-Speed Transmission of Electric Vehicles (전기자동차용 2속 변속기의 경량 최적 설계)

  • Choi, Jaehoon;Suh, Junho;Park, Nogil
    • Tribology and Lubricants
    • /
    • v.36 no.2
    • /
    • pp.96-104
    • /
    • 2020
  • The electric vehicle industry is rapidly developing because of enforced environmental regulations, and several studies have been conducted on the multispeed transmission to improve the fuel efficiency of electric vehicles. Among these studies, research on the power density improvement of electric vehicle transmission is critical. Thus, the optimal design of the gear train is necessary to enhance transmission efficiency. In this study, an optimal design methodology for the lightweight two-speed transmission of electric vehicles is proposed. Because a multispeed transmission has many operating conditions and equality and inequality constraints, a new gear design method that combines analytical and iterative methods is applied without using complex optimization algorithms. Sets of possible design variables are generated considering the operating conditions and various design variables. The modules and face width ratios of each stage gear that satisfy the corresponding operating conditions are analytically calculated. The volume of the gear train is calculated, evaluated, and arranged using these values to determine the optimal solution for minimizing the volume, and the proposed methodology is applied to the actual model to verify its effectiveness. The design of a two-speed transmission with multiple operating conditions and constraints without complicated optimization algorithms can be optimized.

A Study of Vibration Analysis Due to Structual Changes of Dynamic Structure (동적 구조물의 구조변화에 의한 진동해석 연구)

  • 현천성;이기형;정인성
    • Transactions of the Korean Society of Mechanical Engineers
    • /
    • v.16 no.11
    • /
    • pp.2033-2048
    • /
    • 1992
  • This paper presents the theoretical development and qualitative evaluation of a new concept in the mathematical modeling of dynamic structures. We use both test data and analytical approximations to identify the parameters of an incomplete model. The model has the capability of predicting the response of the points of interest on the structure over the frequency range of interest and can be used to predict the changes in natural frequencies and normal modes due to structural changes. The theory was tested by running simulated tests on a relatively simple structure, identifying the parameters of the incomplete model, and using this model to predict the effects on frequency and mode shapes of several mass and stiffness changes. The conditions of the tests were varied by selecting different numbers of points of measurement, varying the frequency range, and by including assumed measurement error. It is recommended that the theoretical development be continued and that applications to more complex structures be carried out in order to develop a better understanding of the limitations and capabilities of the method. A successful, more definitive sevaluation could lead to immediate practical applications.

Fatigue Life Estimation of Welding Details by Using a Notch Strain Approach (노치변형률법을 적용한 용접구조상세의 피로수명평가)

  • Han, Jeong-Woo;Han, Seung-Ho;Shin, Byung-Chun;Kim, Jae-Hoon
    • Transactions of the Korean Society of Mechanical Engineers A
    • /
    • v.28 no.7
    • /
    • pp.977-985
    • /
    • 2004
  • An evaluation of fatigue life of welded components is complicated due to various geometrically complex welding details and stress raisers in vicinity of weld beads, ego under cuts, overlaps and blow holes. These factors have a considerable influence on the fatigue strength of welded joints, as well as the welding residual stress which is relaxed depending on the distribution of local stress at the front of the stress raisers. To reasonably evaluate fatigue life, the effect of geometries and welding residual stress should be taken into account. The several methods based on the notch strain approach have been proposed in order to accomplish this. These methods, however, result in differences between analytical and experimental results due to discrepancies in estimated amount of relaxed welding residual stress present. In this paper, an approach that involves the use of a modified notch strain approach considering geometrical effects and a residual stress relaxation model based on experimental results was proposed. The fatigue life for five types of representative welding details, ego cruciform, cover plate, longitudinal stiffener, gusset and side attachment joint, are evaluated using this method.

Interval finite element analysis of masonry-infilled walls

  • Erdolen, Ayse;Doran, Bilge
    • Structural Engineering and Mechanics
    • /
    • v.44 no.1
    • /
    • pp.73-84
    • /
    • 2012
  • This paper strongly addresses to the problem of the mechanical systems in which parameters are uncertain and bounded. Interval calculation is used to find sharp bounds of the structural parameters for infilled frame system modeled with finite element method. Infill walls are generally treated as non-structural elements considerably to improve the lateral stiffness, strength and ductility of the structure together with the frame elements. Because of their complex nature, they are often neglected in the analytical model of building structures. However, in seismic design, ignoring the effect of infill wall in a numerical model does not accurately simulate the physical behavior. In this context, there are still some uncertainties in mechanical and also geometrical properties in the analysis and design procedure of infill walls. Structural uncertainties can be studied with a finite element formulation to determine sharp bounds of the structural parameters such as wall thickness and Young's modulus. In order to accomplish this sharp solution as much as possible, interval finite element approach can be considered, too. The structural parameters can be considered as interval variables by using the interval number, thus the structural stiffness matrix may be divided into the product of two parts which correspond to the interval values and the deterministic value.

Shear stress indicator to predict seismic performance of residential RC buildings

  • Tekeli, Hamide;Dilmac, Hakan;Demir, Fuat;Gencoglu, Mustafa;Guler, Kadir
    • Computers and Concrete
    • /
    • v.19 no.3
    • /
    • pp.283-291
    • /
    • 2017
  • A large number of residential buildings in regions subjected to severe earthquakes do not have enough load carrying capacity. The most of them have been constructed without receiving any structural engineering attention. It is practically almost impossible to perform detailed experimental evaluation and analytical analysis for each building to determine their seismic vulnerability, because of time and cost constraints. This fact points to a need for a simple evaluation method that focuses on selection of buildings which do not have the life safety performance level by adopting the main requirements given in the seismic codes. This paper deals with seismic assessment of existing reinforced concrete residential buildings and contains an alternative simplified procedure for seismic evaluation of buildings. Accuracy of the proposed procedure is examined by taking into account existing 250 buildings. When the results of the proposed procedure are compared with those of the detailed analyses, it can be seen that the results are quite compatible. It is seen that the accuracy of the proposed procedure is about 80% according to the detailed analysis results of existing buildings. This accuracy percentage indicates that the proposed procedure in this paper can be easily applied to existing buildings to predict their seismic performance level as a first approach before implementing the detailed and complex analyses.