• Bulletin of the Korean Chemical Society
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• v.33 no.6
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• pp.1967-1971
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• 2012

A hexavalent chromium (Cr (VI)) is one of the hazardous substances regulated by the RoHS. The determination of Cr (VI) in various polymers and printed circuit board (PCB) has been very important. In this study, the three different analytical methods were investigated for the determination of a hexavalent chromium in Acrylonitrile Butadiene Styrene copolymer (ABS) and PCB. The results by three analytical methods were obtained and compared. An analytical method by UV-Visible spectrometer has been generally used for the determination of Cr (VI) in a sample, but a hexavalent chromium should complex with diphenylcarbazide for the detection in the method. The complexation did make an adverse effect on the quantitative analysis of Cr (VI) in ABS. The analytical method using diphenylcarbazide was also not applicable to printed circuit board (PCB) because PCB contained lots of irons. The irons interfered with the analysis of hexavalent chromium because those also could complex with diphenylcarbazide. In this study, hexavalent chromiums in PCB have been separated by ion chromatography (IC), then directly and selectively detected by inductively coupled plasma atomic emission spectrometry (ICP-AES). The quantity of Cr (VI) in PCB was 0.1 mg/kg.

• YAKHAK HOEJI
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• v.9 no.1_2
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• pp.14-17
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• 1965

It has been known that the organic base complexes formed with the anionic acid base indicators are highly soluble in non-polar solvents but relatively insoluble in water. In the work reported here the formation of the complex between chloropromazine and bromothymol blue was studied and applied it to the determination of the base. The values to determine the binding ratio of the base with the indicator at pH 3.5 obtained from the application of Job's method of continuous variation and mol ratio method were both 1:1. From the application of this reaction to the determination of the base with carbon tetrachloride as the solvent for the extraction, fairy good results have been obtained.

• Transactions of the Korean Society of Automotive Engineers
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• v.5 no.3
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• pp.171-171
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• 1997

Sound intensity distributions and energy flow in the near field of dipole source system and flat plate were investigated. First, the effectiveness of complex acoustic intensity was proved by using mathmatical and experimental methods in order to indentify noise sources and transmission paths of dipole field which is effected by the presence of neighbouring coherent sources. Next, analytical complex acoustic intensity method was discussed and the characteristics and energy flow of sound induced from the plate are clarified. The velocity of plate obtained from Finite Element Method was used for calculation of complex acoustic intensity in the near field. Finally experimental complex acoustic intensity method was applied to a passenger car. It can be seen that complex acoustic intensity method using both of active and reactive intensity is vital in devising a strategy for the identification and the reduction of vibration and noise.

• Steel and Composite Structures
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• v.17 no.1
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• pp.123-131
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• 2014

In this paper we have considered the vibration of parametrically excited oscillator with strong cubic positive nonlinearity of complex variable in nonlinear dynamic systems with forcing based on Mathieu-Duffing equation. A new analytical approach called homotopy perturbation has been utilized to obtain the analytical solution for the problem. Runge-Kutta's algorithm is also presented as our numerical solution. Some comparisons between the results obtained by the homotopy perturbation method and Runge-Kutta algorithm are shown to show the accuracy of the proposed method. In has been indicated that the homotopy perturbation shows an excellent approximations comparing the numerical one.

• Journal of the Korean Society of Clothing and Textiles
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• v.24 no.3
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• pp.422-428
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• 2000

At present, analytical methods available for determining the amount of cationic surfactants(DSDMAC) on the fabrics are spectrophotometric method based on formation and extraction of the colored ion pair with anionic dye, radiochemical analysis and HPLC analysis. This study presents new analytical methods based on the formation of cationic surfactant(DSDMAC)-disulfine blue complex on the cotton fabric. Test methods for determining the amount of DSDMAC-disulfine blue complex on the cotton fabrics are measuring the reflectance of the colored fabric and the absorbance of the methanol solution of DSDMAC-disulfine blue complex extracted from dyed cotton fabric. Linear relationships between the K/S value of the fabric treated with DSDMAC followed by disulfine blue and the amount of DSDMAC sorbed by cotton fabric were obtained. Thus, the amount of DSDMAC sorbed by cotton fabric can be determined by K/S value of the fabric. DSDMAC-disulfine blue complex on the cotton fabric was extracted with methanol. The amount of DSDMAC sorbed by cotton fabric was estimated by measuring the absorbance of the methanol solution extracted from dyed cotton fabric.

• Transactions of the Korean Society of Automotive Engineers
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• v.5 no.3
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• pp.159-171
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• 1997

Sound intensity distributions and energy flow in the near field of dipole source system and flat plate were investigated. First, the effectiveness of complex acoustic intensity was proved by using mathmatical and experimental methods in order to inden- tify noise sources and transmission paths of dipole field which is effected by the presence of neighbouring coherent sources. Next, analytical complex acoustic intensity method was discussed and the characteristics and energy flow of sound induced from the plate are clarified. The velocity of plate obtained from Finite Element Method was used for calculation of complex acoustic intensity in the near field. Finally experimental complex acoustic intensity method using both of active and reactive intensity is vital in devising a strategy for the identification and the reduction of vibration and noise.

• Analytical Science and Technology
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• v.36 no.2
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• pp.70-79
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• 2023

The synthesis of the Mannich base as a ligand (L) N-(morpholino (phenyl) methyl) acetamide is the subject of this study. Elemental analyses, FT-IR spectra, UV-vis, ¹H-NMR, and magnetic measurements were used to confirm the synthesis of the [Ni(L)₂]Cl₂ complex, thermal analysis (TG/DTG), atomic absorption, and scanning, and structurally explained as electron microscopy (SEM), and X-ray powder diffraction (XRD) methods. The melting point of the complex and its molar conductivity were also measured. The suggested geometries of the complexes formed have a tetrahedral structure, according to the data acquired using various techniques. Theoretical approaches to the complex formation have been investigated. For molecular mechanics and semi-empirical calculations, the HYPERCHEM6 program had been used. The effect of the novel Ni(II) complex on the cancer cell Hepa-2 (human hepatocellular ademocarcinoma), that is the human laryngeal cancer, was studied. It has been found that these ligand and complex have potent effects on the cancer cell. The antibacterial activity of the free ligand and its complex was evaluated against two kinds of human pathogenic bacteria. The first category is Gram-positive (Staphylococcus aureas, epiderimids), whereas the second group is Gram-negative (Psedamonas aeruginosa, Escherichia coli) (from the diffusion method). Finally, it was discovered that various chemicals had varied growth-inhibiting effects on bacteria.

• Analytical Science and Technology
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• v.37 no.5
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• pp.271-279
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• 2024

Bisphenols and phthalates are endocrine-disrupting chemicals that are commonly used in packaging and as plasticizers. However, they pose health risks through ingestion, inhalation, and dermal contact. Accurate analysis of these pollutants is challenging owing to their low concentration and their presence in complex oil matrices. Therefore, they require efficient extraction and detection methods. In this study, an analytical method for the simultaneous quantification of bisphenols and phthalates in corn oil is developed. The dynamic multiple reaction monitoring mode of liquid chromatography-tandem mass spectrometry is used according to the different polarities of bisphenols and phthalates. The method is validated by assessing system suitability, linearity, accuracy, precision, homogeneity, and stability. The determination coefficients are higher than 0.99, which is acceptable. The percentage recovery and coefficient of variation of the accuracy and precision confirm that this analytical method is capable of simultaneously quantifying bisphenols and phthalates in corn oil. The bisphenols and phthalates in the formulations and pretreatment samples are stable for 7 d at room temperature and 24 h in an auto-sampler. Therefore, this validated analytical method is effective for the simultaneous quantification of bisphenols and phthalates in oils.

• Journal of Pharmaceutical Investigation
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• v.41 no.1
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• pp.25-30
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• 2011

Recently, Korean Food and Drug Administration (KFDA) has focused on developing quality control guidelines for all commercial products in Korea to enforce regulations, improve the quality control, and protect consumers by developing prevalently used and efficient analytical tools to determine and quantify target compounds. Because the Korean Pharmacopeia (KP) presents microbiological assays for biotin, which is laborious and time-consuming, this study is focused on applying HPLC-UV to detect and quantify biotin in complex drugs and dietary supplements like multi-vitamin. Biotin in complex drugs was extracted from methanol and analyzed using mobile phase with 10 mM potassium phosphate (monobasic, pH=3.0) in distilled water and acetonitrile. Gradient condition was used to successfully detect and quantify biotin within 20 minutes. Validation result for linearity was significant that average $r^2$ was 0.999 (n=3) and its relative standard deviation (RSD) was 0.0578% which was less than 2%. Using this method, quantification of biotin in complex drugs was completed successfully and recovery tests were finished that recovery percentage greater than 95% with relative standard deviation less than 2%.

• Proceedings of the Korea Water Resources Association Conference
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• 2009.05a
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• pp.905-908
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• 2009

In the management of groundwater in coastal areas, saltwater intrusion associated with extensive groundwater pumping, is an important problem. The groundwater optimization model is an advanced method to study the aquifer and decide the optimal pumping rates or optimal well locations. Cheng and Park gave the analytical solutions to the optimization problems basing on Strack's analytical solution. However, the analytical solutions have some limitations of the property of aquifer, boundary conditions, and so on. A simulation-optimization numerical method presented in this study can deal with non-homogenous aquifers and various complex boundary conditions. This simulation-optimization model includes the sharp interface solution which solves the same governing equation with Strack's analytical solution, therefore, the freshwater head and saltwater thickness should be in the same conditions, that can lead to the comparable results in optimal pumping rates and optimal well locations for both of the solutions. It is noticed that the analytical solutions can only be applied on the infinite domain aquifer, while it is impossible to get a numerical model with infinite domain. To compare the numerical model with the analytical solutions, calculation of the equivalent boundary flux was planted into the numerical model so that the numerical model can have the same conditions in steady state with analytical solutions.