• Title/Summary/Keyword: commensurate surface

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Ultrasensitive metal-oxide gas sensors obtained using colloidal templates

  • Kim, Il-Doo;Rothschild Avner;Hyodo Takeo;Tuller Harry L..
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.247-247
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    • 2006
  • Chemical and physical synthesis routes were combined to prepare macroporous thin films of semiconducting metal-oxides such as $CaCu_{3}Ti_{4}O_{12}\;and\;TiO_{2}$ by sputtering onto (PMMA) microsphere templated substrates. Subsequently, the colloidal templates were removed by thermal decomposition. The remaining inorganic films comprised a monolayer of hollow hemispheres with diameter commensurate with that of the microspheres. This unique morphology increases the surface area and reduces the interfacial area between film and substrate. Consequently, the surface activity is markedly enhanced while deleterious interfacial effects between film and substrate are significantly reduced. Both effects are highly advantageous for gas sensing applications.

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A Robust Sliding Mode Controller for Unmatched Uncertain Severe Sate Time-Delay Systems (큰 상태변수 시간 지연 부정합조건 불확실성 시스템을 위한 강인한 슬라이딩 모드 제어기)

  • Lee, Jung-Hoon
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.59 no.10
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    • pp.1894-1899
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    • 2010
  • This note is concerned with a robust sliding mode control(SMC) for a class of unmatched uncertain system with severe commensurate state time delay. The suggested method is extended to the control of severe state time delay systems with unmatched uncertainties except the matched input matrix uncertainty. A transformed sliding surface is proposed and a stabilizing control input is suggested. The closed loop stability together with the existence condition of the sliding mode on the proposed sliding surface is investigated through one Lemma and two Theorems by using the Lyapunov direct method with the concept of the control Lyapunov function instead of complex Lyapunov-Kravoskii functionals. Through an illustrative example and simulation study, the usefulness of the main results is verified.

Friction and Wear Simulation of Suspended Silicon Asperity Moving over a Plate at Microscale

  • Cho, Sung-San;Kim, Jung-Soo;Park, Seung-Ho
    • International Journal of Safety
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    • v.5 no.1
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    • pp.10-16
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    • 2006
  • A suspended hemispherical silicon asperity moving over a silicon plate was simulated. The simulation results on friction and wear in the interface between the two can help obtain more durable miscroscale structures. Silicon structures were constructed with Tersoff three-body potential. Dependence of friction and wear of the asperity on both the atomic arrangement in the plate and the moving direction was investigated under the condition that the asperity is subject to the attractive normal force due to the plate. The results show that the variation of friction force with the movement of asperity, and the occurrence of adhesive wear are attributed to the formation and rupture of asperity, junction between the asperity and the plate. The friction force and wear are smaller when the asperity is incommensurate with the plate, and they also depend on the moving direction of the asperity over the plate.

Comparative Study of Tetrahydrothiophene and Thiophene Self Assembled Monolayers on Au(111): Structure and Molecular Orientation

  • Ito, Eisuke;Hara, Masahiko;Kanai, Kaname;Ouchi, Yukio;Seki, Kazuhiko;Noh, Jaegeun
    • Bulletin of the Korean Chemical Society
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    • v.30 no.8
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    • pp.1755-1759
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    • 2009
  • Surface structure and molecular orientation of self-assembled monolayers (SAMs) formed by the spontaneous adsorption of tetrahydrothiophene (THT) and thiophene (TP) on Au(111) were investigated by means of scanning tunneling microscopy (STM) and carbon K-edge near edge X-ray absorption fine structure (NEXAFS) spectroscopy. STM imaging revealed that THT SAMs have a commensurate (3 ${\times}\;2\sqrt[]{3}$) structure containing structural defects in ordered domains, whereas TP SAMs are composed of randomly adsorbed domains and paired molecular row domains that can be described as an incommensurate packing structure. The NEXAFS spectroscopy study showed that the average tilt angle of the aliphatic THT ring and $\pi$-conjugated TP ring in the SAMs were calculated to be about $30^o\;and\;40^o$, respectively, from the surface normal. It was also observed that the $\pi$* transition peak in the NEXAFS spectrum of the TP SAMs is very weak, suggesting that a strong interaction between $\pi$-electrons and the Au surface arises during the self-assembly of TP molecules. In this study, we have clearly demonstrated that the surface structure and adsorption orientation of organic SAMs on Au(111) are strongly influenced by whether the cyclic ring is saturated or unsaturated.

Valve actuation effects on discrete monopropellant slug delivery in a micro-scale fuel injection system

  • McDevitt, M. Ryan;Hitt, Darren L.
    • Advances in aircraft and spacecraft science
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    • v.1 no.4
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    • pp.409-425
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    • 2014
  • Converging flows of a gas and a liquid at a microchannel cross junction, under proper conditions, can result in the formation of periodic, dispersed microslugs. This microslug formation phenomenon has been proposed as the basis for a fuel injection system in a novel, 'discrete' monopropellant microthruster designed for use in next-generation miniaturized satellites. Previous experimental studies demonstrated the ability to generate fuel slugs with characteristics commensurate with the intended application during steady-state operation. In this work, numerical and experimental techniques are used to study the effect of valve actuation on slug characteristics, and the results are used to compare with equivalent steady-state slugs. Computational simulations of a valve with a 1 ms valve-actuation cycle show that as the ratio of the response time of the valve to the fully open time is increased, transient effects can increase slug length by up to 17%. The simulations also demonstrate that the effect of the valve is largely independent of surface tension coefficient, which is the thermophysical parameter most responsible for slug formation characteristics. Flow visualization experiments performed using a miniature valve with a 20 ms response time showed less than a 1% change in the length of slugs formed during the actuation cycle. The results of this study indicate that impulse bit and thrust calculations can discount transient effects for slower valves, but as valve technology improves transient effects may become more significant.

A analysis of friction relation between tennis outsole and tennis playing surfaces (테니스화겉창과 테니스 스포츠바닥재간의 마찰관계상관 분석)

  • Kim, Jung-Tae
    • Korean Journal of Applied Biomechanics
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    • v.12 no.2
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    • pp.361-380
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    • 2002
  • The purposes of this study were to a analysis of friction relation between tennis outsole and tennis playing surfaces. Tennis footwear is an important component of tennis game equipment. It can support or damage players performance and comfort. Most importantly athletic shoes protect the foot preventing abrasions and injuries. Footwear stability in court sports like tennis is incredibly important since it is estimated that as many as 45% of all lower extremity injuries occur in the foot and ankle. The friction force is the force exerted by a surface as an object moves across it or makes an effort to move across it. The friction force opposes the motion of the object. Friction results when two surfaces are pressed together closely, causing attractive intermolecular forces between the molecules of the two different surfaces. The outsole provides traction and reduces wear on the midsole. Today's outsoles address sport specific movements (running versus pivoting) and playing surface types. Different areas of the outsole are designed for the distinct frictional needs of specific movements. Traction created by the friction between the outsole and the surface allows the shoe to grip the surface. As surfaces, conditions and player motion change, traction may need to vary. An athletic shoe needs to grip well when running but not when pivoting. Laboratory tests have demonstrated force reductions compared to impact on concrete. There is a correlation between pain, injury and surface hardness. These are a variety of traction patterns on the soles of athletic shoes. Traction like any other shoe characteristic must be commensurate and balanced with the sport. The equal and opposite force does not necessarily travel back up your leg. The surface itself absorbs a portion of the force converting it to other forms of energy. Subsequently, tennis court surfaces are rated not only for pace but also for the percentage of force reduction.

A Study on Implementation of Indoor Positioning Simulator through Indoor Positioning API Development (실내측위 API개발을 통한 실내측위 시뮬레이터 구현에 관한 연구)

  • Shin, Chang Soo;Kim, Sung Su
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.43 no.6
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    • pp.873-881
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    • 2023
  • The evolution of civil engineering technology, exemplified by recent milestones like the completion of the Gangnam Global Business Center (GBC), has fostered the construction of expansive civil and architectural structures both above and below the earth's surface. This surge in construction necessitates a commensurate advancement in research and technology pertaining to safety protocols applicable to these vast edifices. Such protocols encompass a spectrum of concerns, ranging from the preemptive mitigation of accidents to the effective management of exigencies such as fires. As the trajectory of construction endeavors continues unabated, encompassing both subterranean and elevated domains, a concomitant imperative emerges to refine the methodologies underpinning precise indoor positioning. To address this need, an innovative web-based simulator has been devised to emulate indoor positioning scenarios for rigorous testing. This research further entails the development of an indoor positioning data Application Programming Interface (API) fortified by Geographic Information System (GIS) spatial operation techniques. This API is anchored in the construction of intricate test data, centered on the spatial layout of building 13 at the Electronics and Telecommunications Research Institute (ETRI). Consequently, the study renders feasible the expeditious provisioning of diverse signal-based and image-based spatial information, pivotal for enhancing the navigational acumen of mobile devices. Path delineation, cellular signal mapping, landmark identification, and ancillary navigational aids are among the manifold datasets promptly furnished by the indoor positioning data API. In summation, this study engenders a crucial leap towards the fortification of safety protocols and navigational precision within the expansive confines of modern architectural wonders.