• 제목/요약/키워드: combustion products

검색결과 331건 처리시간 0.025초

성층화 혼합기의 연소 모델링 (Combustion Modeling for Stratified Charge)

  • 김용태;배상수;민경덕
    • 한국자동차공학회논문집
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    • 제9권4호
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    • pp.50-55
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    • 2001
  • To simulate the combustion process under stratified charged conditions, like GDI engines, the new combustion model is proposed, which is based on Welter's FAE model and Peters' PDF model for considering primary reactions. In addition to these models, the new laminar burning velocity correlation and diffusion flame model are also included in the proposed model. The former can be applicable to much wider range of equivalence ratio, pressure and temperature than the others, such as Keck's and Guilder's models, and the latter has been derived from water-gas shift reaction and hydrogen oxidation, by which the secondary reactions can be considered after primary reactions. 3-D computation has been performed by using STAR-CD v3.05 in the simple cylindrical geometry under stratified charged condition. Judging from the calculated results, the present model proves to be reasonable to simulate the characteristics of flame propagation and concentrations of products in burned regions.

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燃燒氣體의 熱力學的 平衡組成計算에 관한 硏究 (Calculation of thermodynamical equilibrium composition of combustion gases)

  • 허병기;이청종
    • 대한기계학회논문집
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    • 제11권1호
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    • pp.177-188
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    • 1987
  • 본 논문에서는 연소기체의 열력학적 평형조성 계산을 위한 수식을 Gibbs의 자 유에너지 최소화법에 의하여 유도하고 이를 컴퓨터 프로그램화하여, Table 1의 특성을 지닌 연료에 대하여 ⅰ) 연소공기량에 따른 평형조성 및 단열불꽃온도, ⅱ) 연소온도 변화에 따른 평형조성의 변화를 계산함으로써 연소기체의 생성기구를 열력학적으로 해 석하였다.

상세화학반응식을 이용한 HCCI 엔진의 성능 해석기법 연구 (A Cycle Simulation Method for an HCCI Engine using Detailed Chemical Kinetics)

  • 송봉하;김동광;조남효
    • 한국자동차공학회논문집
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    • 제11권6호
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    • pp.51-58
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    • 2003
  • A cycle simulation method is developed by coupling a commercial code, Ricardo's WAVE, with the SENKIN code from CHEMKIN packages to predict combustion characteristics of an HCCI engine. By solving detailed chemical kinetics the SENKIN code calculates the combustion products in the combustion chamber during the valve closing period, i.e. from IVC to EVO. Except the combustion chamber during the valve closing period the WAVE code solves thermodynamic status in the whole engine system. The cycle simulation of the complete engine system is made possible by exchanging the numerical solutions between the codes on the coupling positions of the intake port at IVC and of the exhaust port at EVO. This method is validated against the available experimental data from recent literatures. Auto ignition timing and cylinder pressure are well predicted for various engine operating conditions including a very high ECR rate although it shows a trend of sharp increase in cylinder pressure immediate after auto ignition. This trend is overpredicted especially for EGR cases, which may be due to the assumption of single-zone combustion model and the limit of the chemical kinetic model for the prediction of turbulent air-fuel mixing phenomena. A further work would be needed for the implementation of a multi-zone combustion model and the effect of turbulent mixing into the method.

ACTIVATION ANALYSIS OF ENVIRONMENTAL SAMPLES USING THE MT-25 MICROTRON OF THE FLNR

  • Maslov, O.D.;Belov, A.G.;Starodub, G.Ya.;Dmitriev, S.N.
    • 분석과학
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    • 제8권4호
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    • pp.815-820
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    • 1995
  • Instrumental neutron and gamma activation analysis of coal and combustion products, determination of platinum content in natural samples by radiochemical gamma activation analysis and high-sensitive track method of thorium determination has been studied with the use of the MT-25 microtron.The optimal conditions for complete elemental analysis of coal and combustion products, isolation and determination of platinum and thorium are recommended.

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알칼리 자극제 NaOH의 첨가율에 따른 고로슬래그 기반 경화체의 강도 특성 (Strength Properties of Blast Furnace Slag-based Hardened Materials with Addition Rate of Alkali Stimulant NaOH)

  • 경석현;최병철;이상수
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2019년도 추계 학술논문 발표대회
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    • pp.135-136
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    • 2019
  • Recently, as the interest in environmental issues increases, the construction industry needs to recycle blast furnace slag, circulating fluidized bed Combustion fly ash, etc. to solve industrial by-products, and to develop artificial stone. In this study, the strength characteristics based on blast furnace slag according to the addition rate of alkali stimulant NaOH are investigated. The experimental results showed that the flexural and compressive strengths increased with the addition of alkali stimulants. Based on these results, it will be presented as a basic research data for the manufacture of artificial stone and will be tested later.

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정적연소기에서 라디칼 유도분사를 이용한 희박혼합기의 연소특성에 관한 연구 (1) (A Study on the Combustion Characteristics of Lean Mixture by Radicals Induced Injection in a Constant Volume Combustor (1))

  • 박종상;이태원;하종률;정성식
    • 한국자동차공학회논문집
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    • 제12권2호
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    • pp.45-53
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    • 2004
  • An experimental study was carried out to obtain the fundamental data about the effects of radicals induced injection on premixture combustion. A constant volume combustor divided to the sub-chamber and the main chamber was used. The volume of the sub-chamber is set up to occupy less than 1.5% of that of whole combustion chamber. Radial twelve narrow passage holes are arranged between the main chamber and the sub-chamber. The products including radicals generated by spark ignition in the sub-chamber will derive the simultaneous multi-point ignition in the main chamber. While the equivalence ratio of pre-mixture in the main chamber and the sub-chamber is uniform. We have examined the effects of the sub-chamber volume, the diameter of passage hole, and the equivalence ratio on the combustion characteristics by means of burning pressure measurement and flame visualization. In the case of radical ignition method(RI), the overall turning time including the ignition delay became very short and the maximum burning pressure was slightly increased in comparison with those of the conventional spark ignition method(SI), that is, single chamber combustion without the sub-chamber. The combustible lean limit by RI method is extended to more ER=0.25 than that by SI method. Therefore the decrease of every emission including NOx and the improvement of fuel consumption is anticipated due to lean burn.

MDF합판의 방염 및 연소특성에 관한 연구 (A Study on the Flame Resistance and Combustion Characteristics of MDF Plywood)

  • 김인범
    • Korean Chemical Engineering Research
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    • 제52권2호
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    • pp.256-260
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    • 2014
  • 건축물 내부의 장식을 위해 사용되는 MDF합판은 화염의 착화를 지연시키기 위해 방염처리하도록 규정하고 있어 일반적으로 방염도료나 방염액 또는 방염필름 등을 적용하여 착화를 지연시키는데 이 때 적용하는 시료에 따라 방염성능과 연소 시 발생되는 가스의 유독성의 차이가 발생할 수 있어 본 연구에서는 MDF에 적용된 방염시료들의 방염성능 및 연소특성에 대해 비교분석하였으며 그 결과 방염성능에 부합하는 제품이 확인되었으나 방염처리방법에 따라 방염성능의 차이가 존재함을 확인할 수 있었으며 연소과정에서 발생되어지는 여러 종류의 유독가스의 영향도 함께 고려해야 할 요소임을 확인할 수 있었다.

연소합성법을 이용한 방사성폐기물 고화체 Hollandite 분말 합성 (Synthesis of Hollandite Powders as a Nuclear Waste Ceramic Forms by a Solution Combustion Synthesis)

  • 정충환;정수지
    • 한국재료학회지
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    • 제33권10호
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    • pp.385-392
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    • 2023
  • A solution combustion process for the synthesis of hollandite (BaAl2Ti6O16) powders is described. SYNROC (synthetic rock) consists of four main titanate phases: perovskite, zirconolite, hollandite and rutile. Hollandite is one of the crystalline host matrices used for the disposal of high-level radioactive wastes because it immobilizes Sr and Lns elements by forming solid solutions. The solution combustion synthesis, which is a self-sustaining oxi-reduction reaction between a nitrate and organic fuel, generates an exothermic reaction and that heat converts the precursors into their corresponding oxide products in air. The process has high energy efficiency, fast heating rates, short reaction times, and high compositional homogeneity. To confirm the combustion synthesis reaction, FT-IR analysis was conducted using glycine with a carboxyl group and an amine as fuel to observe its bonding with metal element in the nitrate. TG-DTA, X-ray diffraction analysis, SEM and EDS were performed to confirm the formed phases and morphology. Powders with an uncontrolled shape were obtained through a general oxide-route process, confirming hollandite powders with micro-sized soft agglomerates consisting of nano-sized primary particles can be prepared using these methods.

폐쇄공간 화재 발생시 온도 및 연소산화물의 분포에 관한 모델 해석 (A Numerical Analysis of the Distribution of Temperature and Combustio Products I case of Compartment Fire)

  • 차형석;이희근
    • 터널과지하공간
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    • 제8권1호
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    • pp.8-16
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    • 1998
  • The first purpose of this study is to verify the application of computer modelling to a enclosed space fire. The second one is to determine temperature distribution for the three different ventilation types in case of a enclosed space fire. The third one is to find out the ventilation direction and ventilation quantity to remove effectively heat and combustion products generated by a fire in variable air volume(VAV) system. Firstly, compared with experimental results of Lawrence Livermore National Laboratory(LLNL), numerical results show good agreements. Secondly, among three different ventilation types, the numerical analyses show the highest temperature distribution in occupied zone(up to 1.8 m from bottom) from firing moment to 100 sec. when supply ducts are placed in ceiling and extract duct is placed close to the bottom on side walls. This is due to disadvantageous position of extract duct in ventilating high temperature air which rise because of buoyancy force. Thirdly, this study finds out effective ventilation direction and ventilation quantity to remove heat and combustion products generated by a fire by using VAV system. $CO_2$ concentration is used as a fire fume removal index. As soon as a fire happens, ventilation direction is changed in order to gather and drive out fire fumes. In case of three times ventilation quantity of ordinary one, $CO_2$ concentration and temperature have begun to decrease at 120 sec. after firing, i.e.fire fumes have begun to be removed.

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연소합성법에 의한 $MoSi_2-Al_2O_3$ 복합재료의 특성에 미치는 $Mo/MoO_3$ 몰비의 영향 (Influences of the Molar Ratio of $Mo/MoO_3$ on Characteristics of $MoSi_2-Al_2O_3$ composites by SHS Methods)

  • 장윤식;이윤복;김용백;김인술;박흥채;오기동
    • 한국세라믹학회지
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    • 제33권11호
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    • pp.1209-1216
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    • 1996
  • MoSi2-Al2O3 composites were prepared by thermal explosion mode of self-propagating high temperature syn-thesis (SHS) using element powders of MoO3 Mo Si and Al. The combustion products of MoSi2 which have 10, 20, 30 and 40 wt% Al2O3 showed the molten state in the range of Mo to MoO3 6:1-9.5:1, 2:1-8:1, 1:1-5:1, and 1:1-3:1 (molar ratio) respectively. The combustion products which made least seperation the molten phase from the slag phase were in Mo/MoO3=9, 5:1, 8:1, 5:1 and 3:1 (molar ratio) respectively. Particles size of MoSi2 and Al2O3 in the combustion product were decreased as the molar ratio of Mo to MoO3 increase. By XRD analysis only MoSi2 and $\alpha$-Al2O3 peaks were identified in the combusion products, In case of MoSi2 containing 20wt% Al2O3 5.1wt% Al existed into MoSi2 grains and 30.7wt% Si and 7.7wt% Mo existed into Al2O3 grains. The relative density of MoSi2 containing 10, 20, 30 and 40 wt% Al2O3 were 82.7, 85.2, and 81.9% respectively. The fracture strength of MoSi2-Al2O3 composites increased with increasing Al2O3 and that of MoSi2-20wt% Al2O3 composite was 195 MPa.

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