• Journal of the Korea Concrete Institute
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• v.17 no.2 s.86
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• pp.255-261
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• 2005

Immense quantities of coal combustion by-products are produced every year, and only a small fraction of them are currently utilized. The purpose of this study is to investigate reused techniques of coal ash in the construction field, which may contribute to the savings of building materials and conservation of environment. From the results of the compressive strength test, the elastic modulus was experimentally proposed. Also, based on the three- point-bending test, the fracture parameters - notch sensitivity, fracture energy, and initial compliance were experimentally proposed. As a result, the strength and fracture characteristics were lower than those of concrete or mortar. Also, the study showed that the deflection at a fracture decreased as the age increased and as the notch depth rate decreased. However, it was judged that its use as a building material could be expected if further research is carried out.

• Journal of the Korean Institute of Gas
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• v.20 no.1
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• pp.29-39
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• 2016

Electrical apparatuses for use in the presence of explosive gas atmospheres have to be special designed to prevent them from igniting the explosive gas. Flameproof design implies that electrical components producing electrical sparks are contained in enclosures and withstand the maximum pressure of internal gas or vapours. In addition, any gaps in the enclosure wall have to designed in such a way that they will not transmit a gas explosion inside the enclosure to an explosive gas or vapours atmosphere outside it. In this study, we explained some of the most important physical mechanism of Maximum Experimental Safe Gap(MESG) that the jet of combustion products ejected through the flame gap to the external surroundings do not have an energy and temperature large enough to initiate an ignition of external gas or vapours. We measured the MESG and maximum explosion pressure of propane and acetylene by the test method and procedure of IEC 60079-20-1:2010.When the minimum MESG is measured, the concentration of propane, acetylene in the air is higher than the stoichiometric point and their explosion pressure is the highest value.

• Fire Science and Engineering
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• v.32 no.3
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• pp.8-13
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• 2018

It was conceived from the realization that there was a lack of studies on the fire risk compared to utility and importance of plastic which is widely used. In this study, the fire hazard of five types of plastic products was measured by Cone Calorimeter (ISO 5660-1). As a result, the time to ignition (TTI) of polyvinyl Chloride (PVC) plate delayed TTI (196 s), and polystyrene (PS) plate had the shortest TTI of 19 s. The total heat release (THR) of PS plate was measured at 213.07 % higher than the lowest measured PVC plate. Also, the PS plate will have 1.45 to 4.21 times higher $CO_2$ than other plastics, resulting in the highest incomplete combustion and the greatest possible damage of life. Thus, assessing the risk of fire revealed that PS plate is the most dangerous and PVC is the safest.

• Journal of the Korean Society of Propulsion Engineers
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• v.13 no.2
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• pp.42-53
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• 2009

Gas turbine engine simulation program has been developed. In compressor and turbine, 2-D NS implicit code is used with k-$\omega$ SST turbulent model. In combustor, 0-D lumped method chemical equilibrium code is adopted under the limitations, the products are only 10 species of molecular and air-fuel is perfectly mixed state with 100% combustion efficiency at constant pressure. Fluid properties are shared on interfaces between engine components. The outlet conditions of compressor have been used as the inlet condition of combustor. The inlet condition of turbine comes from the compressor The back pressure in compressor outlet is transferred by the inlet pressure of turbine. Unsteady phenomena at rotor-stator in compressor and turbine is covered by mixing-plane method. The state of engine can be determined only by given inlet condition of compressor, outlet condition of turbine, equivalence ratio and rotating speed.

• Resources Recycling
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• v.32 no.6
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• pp.79-89
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• 2023

One of the foremost environmental challenges, alongside the contemporary focus on achieving carbon neutrality, pertains to the pervasive issue of plastic waste. Thermochemical recycling technology, operating under high-temperature conditions to covert organic matter and recycle it into raw materials and energy, represents a transformative approach surpassing the conventional bounds of material recycling predominantly applied in plastic waste management. The thermochemical recycling paradigm is emerging as a pivotal technology within the circular economy, capable of transforming waste plastics into raw materials for producing original plastics. Its significance extends beyond national borders, garnering global attention due to its versatility as a chemical or energy recycling method, contingent upon the subsequent processes and final products. This study aims to scrutinize three quintessential thermochemical recycling technologies: combustion, gasification, and pyrolysis. Furthermore, the study discusses the recent major technology trends of these technologies.

• Journal of the Korean Applied Science and Technology
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• v.34 no.2
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• pp.327-337
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• 2017

A continuous low temperature ($510^{\circ}C{\sim}530^{\circ}C$) pyrolysis experiment in a pilot-scale of 85.3 kg/hr was carried out by the mixed feedstock of half dried digested sewage sludge and waste plastics. As a result, the amount of pyrolysis gas generated was maximum 68.3% of input dry mass and scored $40.9MJ/Nm^3$ of lower heating value (LHV), and the percentage of air inflow caused by continuous pyrolysis was 19.6%. The oil was produced 4.2% of the input dry mass, and the LHV was 32.5 MJ/kg. The sulfur and chlorine contents, which could cause corrosion of the facility, were found to be 0.2% or more respectively. The carbide generated was 27.5% of the input dry mass which shows LHV of 10.2 MJ/kg, and did not fall under designated waste from the elution test. The concentration of carbon monoxide, sulfur oxides and hydrogen cyanide of emitted flu gas from pyrolysis gas combustion was especially high, and dioxin (PCDDs/DFs) was within the legal standards as $0.034ng-TEQ/Sm^3$. Among the 47 water pollutant contents of waste water generated from dry flue gas condensation, several contents such as total nitrogen, n-H extract and cyanide showed high concentration. Therefore, the merge treatment in the sewage treatment plants after pre-treatment could be considered.

• Journal of Bio-Environment Control
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• v.19 no.4
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• pp.177-183
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• 2010

Bum-type $CO_2$ generators are widely used in greenhouses for the purpose of $CO_2$ supply for photosynthesis and greenhouse heating. However harmful gases included in the air might give severe effects on the plant growth. For investigating the possible emission of harmful gases from commercial bum-type $CO_2$ generators, we carried out the analysis of the harmful by-products (NO, NOx, $NO_2$, CO, and VOCs) and $CO_2$ caused by using a bum-type $CO_2$ generator in greenhouses. And the harmful by-products from different type of fuels such as kerosene, LPG, and LNG were quantified. In order to minimize the uncertainties from a $CO_2$ generator, 4 different $CO_2$ generators were utilized in four plastic greenhouses and a glasshouse located at different places during the experimental works. The results showed that the concentration of NOx is proportional to $CO_2$ concentration. Levels of harmful gases in the most of greenhouses, where the new bum-type $CO_2$ generators were installed, were lower than 1.0 ppm when $CO_2$ concentration was set at 1,000 ppm. In case of LNG combustion, the concentration of CO reached out up to 300 ppm and pre-treatment for CO reduction, such as the adsorption process, would be inevitable to abate the adverse effects on plant growth.

• Journal of Radiation Industry
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• v.10 no.4
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• pp.173-179
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• 2016

Coals and coal ashes, raw materials and by-products, in coal-fired power plants contain naturally occurring radioactive materials (NORM). They may give rise to internal exposure to workers due to inhalation of airborne particulates containing radioactive materials. It is necessary to characterize radioactivity concentrations of the materials for assessment of radiation dose to the workers. The objective of the present study was to analyze radioactivity concentrations of coals and by-products at four coal-fired plants in Korea. High purity germanium detector was employed for analysis of uranium series, thorium series, and potassium 40 in the materials. Radioactivity concentrations of $^{226}Ra$, $^{228}Ra$, and $^{40}K$ were $2{\sim}53Bq\;kg^{-1}$, $3{\sim}64Bq\;kg^{-1}$, and $14{\sim}431Bq\;kg^{-1}$ respectively in coal samples. For coal ashes, the radioactivity concentrations were $77{\sim}133Bq\;kg^{-1}$, $77{\sim}105Bq\;kg^{-1}$, and $252{\sim}372Bq\;kg^{-1}$ in fly ash samples and $54{\sim}91Bq\;kg^{-1}$, $46{\sim}83Bq\;kg^{-1}$, and $205{\sim}462Bq\;kg^{-1}$ in bottom ash samples. For flue gas desulfurization (FGD) gypsum, the radioactivity concentrations were $3{\sim}5Bq\;kg^{-1}$, $2{\sim}3Bq\;kg^{-1}$, and $22{\sim}47Bq\;kg^{-1}$. Radioactivity was enhanced in coal ash compared with coal due to combustion of organic matters in the coal. Radioactivity enhancement factors for $^{226}Ra$, $^{228}Ra$, and $^{40}K$ were 2.1~11.3, 2.0~13.1, and 1.4~7.4 for fly ash and 2.0~9.2, 2.0~10.0, 1.9~7.7 for bottom ash. The database established in this study can be used as basic data for internal dose assessment of workers at coal-fired power plants. In addition, the findings can be used as a basic data for development of safety standard and guide of Natural Radiation Safety Management Act.

• Asian Journal of Atmospheric Environment
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• v.6 no.2
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• pp.83-95
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• 2012

China has been a top producer and exporter of refined lead products in the world since the year 2000. After the phasing-out of leaded gasoline in the late 1990s, non-ferrous metallurgy and coal combustion have been identified as potential major sources of aerosol lead in China. This paper presents the single particle analytical results of ambient aerosol particles collected near a lead smelter using a scanning electron microscopy- energy dispersive x-ray spectroscopy (SEM-EDX). Aerosol particle samples were collected over a 24-hour period, starting from 8 pm on 31 May 2002, using a high volume TSP sampler. For this near source sample, 73 particles among 377 particles analyzed (accounting for 19.4%) were lead-containing particles mixed with other species (S, Cl, K, Ca, and/or C), which probably appeared to be from a nearby lead smelter. Lead-containing particles of less than $2{\mu}m$ size in the near source sample were most frequently encountered with the relative abundances of 42%. SEM-EDX analysis of individual standard particles, such as PbO, PbS, $PbSO_4$, $PbCl_2$, and $PbCO_3$, was also performed to assist in the clear identification of lead-containing aerosol particles. Lead-containing particles were frequently associated with arsenic and zinc, indicating that the smelter had emitted those species during the non-ferrous metallurgical process. The frequently encountered particles following the lead-containing particles were mineral dust particles, such as aluminosilicates (denoted as AlSi), $SiO_2$, and $CaCO_3$. Nitrate- and sulfate-containing particles were encountered frequently in $2-4{\mu}m$ size range, and existed mostly in the forms of $Ca(NO_3,SO_4)/C$, $(Mg,Ca)SO_4/C$, and $AlSi+(NO_3,SO_4)$. Particles containing metals (e.g., Fe, Cu, and As) in this near source sample had relative abundances of approximately 10%. Although the airborne particles collected near the lead smelter contained elevated levels of lead, other types of particles, such as $CaCO_3$-containing, carbonaceous, metal-containing, nitrates, sulfates, and fly-ash particles, showed the unique signatures of samples influenced by emissions from the lead smelter.

• Korean Journal of Soil Science and Fertilizer
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• v.45 no.2
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• pp.253-259
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• 2012

Disposal of high amount of coal combustion by-products, such as fly ash and bottom ash, is of a great concern to the country, due to the huge treatment cost and land requirement. On the other hand, those coal-ash wastes are considered to have desirable characteristics that may improve physical, chemical, and biological properties of soils. Especially, compared with fly ash, bottom ash has a larger particle size, porous surface area, and usable amount of micronutrients. In the present study, we examined bottom as a soil amendment for mitigating $CO_2$ emission and enhancing carbon sequestration in soils fertilized with organic matter (hairy vetch, green barely, and oil cake fertilizer). Through laboratory incubation, $CO_2$ released from the soil was quantitatively and periodically monitored with an enforced-aeration and high-temperature respirometer. We observed that amendment of bottom ash led to a marked reduction in $CO_2$ emission rate and cumulative amount of $CO_2$ released, which was generally proportional to the amount of bottom ash applied. We also found that the temporal patterns of $CO_2$ emission and C sequestration effects were partially dependent on the relative of proportion labile carbon and C/N ratio of the organic matter. Our results strongly suggest that amendment of bottom ash has potential benefits for fixing labile carbon as more stable soil organic matter, unless the bottom ash contains toxic levels of heavy metals or other contaminants.