• 제목/요약/키워드: combustion products

검색결과 331건 처리시간 0.026초

자전연소합성법에 의한 TiB2 분말의 제조에 있어 반응성에 대한 반응변수의 고찰 (The Investigation of Reaction Parameters on the Reactivity in the Preparation of TiB2 by SHS)

  • 신창윤;박영철;이혁희;;원창환
    • 한국세라믹학회지
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    • 제43권1호
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    • pp.16-21
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    • 2006
  • The preparation of $TiB_2$ by SHS in $B_2O_3-Mg-TiO_2$ system was investigated in this study. In the preparation of $TiB_2$, the effect on reactivity and reaction products of the initial pressure of inert gas in reactor, the content of Mg and $TiO_2$ in mixture was investigated. The minimum initial pressure of inert gas in reactor for SHS reaction in this system was 5atm, and as the pressure increased, the concentration of unreacted Mg decreased and combustion temperature increased. At the initial inert gas pressure in reactor of 50atm, the optimum composition for the preparation of pure $TiB_2$ was $B_2O_3+5Mg+TiO_2$. The $TiB_2$ synthesized in this condition had an irregular shape and the particle size of $1\~3{\mu}m$.

혼합시멘트 수화모델을 이용한 콘크리트의 단열온도상승 예측에 관한 연구 (The Evaluation of Adiabatic Temperature rise in Concrete by Using Blended Cement Hydration Model)

  • 왕소용;조형규;이한승
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2011년도 추계 학술논문 발표대회
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    • pp.31-32
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    • 2011
  • Granulated slag from metal industries and fly ash from the combustion of coal are industrial by-products that have been widely used as mineral admixtures in normal and high strength concrete. Due to the reaction between calcium hydroxide and fly ash or slag, the hydration of concrete containing fly ash or slag is much more complex compared with that of Portland cement. In this paper, the production of calcium hydroxide in cement hydration and its consumption in the reaction of mineral admixtures is considered in order to develop a numerical model that simulates the hydration of concrete containing fly ash or slag. The heat evolution rates of fly ash- or slag-blended concrete is determined by the contribution of both cement hydration and the reaction of the mineral admixtures. Furthermore, the temperature distribution and temperature history in hardening blended concrete are evaluated based on the degree of hydration of the cement and the mineral admixtures. The proposed model is verified through experimental data on concrete with different water-to-cement ratios and mineral admixture substitution ratios.

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자전연소합성법에 의한 FeB 분말의 제조 (Preparation of FeB by SHS (Self Propagating High Temperature Synthesis))

  • 신창윤;원창환
    • 한국세라믹학회지
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    • 제45권7호
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    • pp.418-422
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    • 2008
  • The preparation of FeB by SHS in $B_2O_3-Mg-Fe-Fe_3O_4$ system was investigated in this study. In the preparation of FeB, the effects of the initial pressure of inert gas in reactor, the content of Mg and $Fe_3O_4$ in mixture on the reactivity and reaction products was investigated. The minimum initial pressure of inert gas in reactor for SHS reaction in this system was 25 atm, and as the pressure increased, the concentration of unreacted Mg decreased and combustion temperature increased. At the initial inert gas pressure in reactor of 25 atm, the optimum composition for the preparation of pure FeB was $1.5B_2O_3$+3.43Mg+ 1.7Fe+$0.1Fe_3O_4$. The FeB synthesized in this condition had an irregular shape and the particle size of $5\;{\mu}m$.

회체가스중합모델에 기초한 연소가스의 파장별 복사 성질 (WSGGM-Based Spectral Modeling for Radiation Properties of Combustion Products)

  • 김옥중;송태호
    • 대한기계학회논문집B
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    • 제23권5호
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    • pp.628-636
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    • 1999
  • This work describes the low-resolution spectral modeling of the water vapor, carbon dioxide and their mixtures by applying the weighted-sum-of-gray-gas-gases model (WSGGM) to each narrow band. Proper modeling scheme of gray gas absorption coefficients vs temperature relation is suggested. Comparison between the modeled emissivity calculated from this relation and the 'true' emissivity obtained from the high temperature statistical narrow band parameters is made for a few typical narrow bands. Low resolution spectral intensities from one-dimensional layers are also obtained and examined for uniform, parabolic and boundary layer type temperature profiles using the obtained WSGGM's with several gray gases. The results are compared with the narrow band spectral intensities obtained by a narrow band model-based code with Curtis-Godson approximation. Good agreement is found between them. Data bases including optimized modeling parameters and total and low-resolution spectral weighting factors are developed for water vapor, carbon dioxide and their mixtures. This model and obtained data bases, available from the authors' Internet site, can be appropriately applied to any radiative transfer equation solver.

미생물의 분화와 그 생화학적 기구 (Microbial Differentiation and its Biochemical Bases)

  • 김종협
    • 미생물학회지
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    • 제11권2호
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    • pp.101-106
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    • 1973
  • microwave oven의 배지 처리에의 이용에 고나한 실험에서 다음 결론을 얻었다. 1)배지 융해에 이용함으로써 시간을 단축하고, 푸로판 불꽃 사용시의 실내 공기 오염을 막을 수 있었다, 2)혐기성 배지에서의 공기 저게는 wire barsket에 넣은 시험관을 물이 든 beaker에서 가열하므로써 끓어 넘는것을 막을 수 있었다. 3)배지 중의 E.coli 살균효과는 불꽃처리의 경우와 비슷하였으며 고압멸균을 대치할 수는 없을 것으로 판단되었다, 저자들의 실험실에서는 매일 5~6종의 배지를 만들기 위해 융해하며, 혐기성 세균동정을 위해 40~50개의 반유동 배지에서 공기를 제거하는바 이를 위해 지난 수개월간 microwave oven을 이용하고 있고 편리함을 경험하고 있다.

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승용차 디젤 엔진 소음에 대한 음질 평가 기법 연구 (Study on the Sound Quality Evaluation Method for the Vehicle Diesel Engine Noise)

  • 권요섭;김찬묵;김기창;김진택
    • 한국소음진동공학회논문집
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    • 제21권10호
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    • pp.883-889
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    • 2011
  • The brand sound of vehicle diesel engine is recently one of the important advantage strategies in the automotive company. Because various noise components masked under high frequency level can be audible in quieter driving situation. Many researches have been carried out for subjective and objective assessments on vehicle sounds and noises. In particular, the interior sound quality has been one of research fields that can give high quality feature to vehicle products. Vehicle interior noise above 500 Hz is usually controlled by sound package parts. The materials and geometries of sound package parts directly affect on this high frequency noise. This paper describes the sound quality evaluation method for the vehicle diesel engine noise to establish objective criteria for sound quality assessment. Considering the sensitivity of human hearing to impulsive sounds such as diesel noise, the human auditory mechanism was simulated by introducing temporal masking in the time domain. Furthermore, each of the human auditory organs was simulated by computer codes, providing reasonable analytical explanations of typical human hearing responses to diesel noise. This method finally provides the sound quality index of vehicle diesel engine noise that includes high frequency intermittent offensive sounds caused by impacting excitations of combustion and piston slap.

플라스틱 폐기물의 건류 및 열분해 (Gasification and Pyrolysis Technology for the Treatment of Plastics Waste)

  • 김영성
    • 공업화학
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    • 제3권2호
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    • pp.201-206
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    • 1992
  • Annual amount of plastics waste including rubber and leather waste, generated in 1990 was about 2,600,000 tons. Amount of generation of plastics waste has rapidly increased, but fractions of recycling and incineration have gradually decreased. Recently, two-stage incinerator, consisting of gasifier and gas combustor, draws much attention in Korea. Plastics are gasified in the starved air condition in the gasifier and produced gas is fired in the combustor. Combustion of produced gas is much easier than that of solid plastics, and produces a little pollutants. Standardzation of technology and process automation are still needed, but this incineration technology is in the commercial stage. Next topic concerned with this two-stage incineration will be how to treat complex plastics waste including toxic substances generated from automobiles and household appliances. Pyrolysis, realized by indirect heating in inert atmosphere, can provide high-quality products with minimum emissions. Many plastics are easily decomposed into oil in pyrolysis conditions, which can be utilized as chemical feedstocks, or gasoline or kerosene depending on feed materials and operating conditions. This has been demonstrated in several pilot-scale tests performed in Japan, Germany, etc. Easy removal of HCl from PVC is one of the most decisive merits of pyrolysis process. But in general, further efforts should be made for the process to obtain marketability. The future of pyrolysis process depends on public concern about environmental problems and oil prices.

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난연도료를 도장한 바탕재의 화재 위험성평가 (A Fire Risk Assessment of Substrate for Fire Resistant Painted)

  • 박영근;이두형;윤명오;현성호
    • 한국화재소방학회논문지
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    • 제19권1호
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    • pp.51-58
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    • 2005
  • 본 연구는 새로 개발된 난연도료를 바탕재(FRP PVC, AL, 스테인레스 스틸)에 도장한 실험체에 대하여 난연성. 화염전파. 산소지수. 가연성, 연기밀도, 독성지수를 평가하였다 연구결과 실험체(AL, 스테인레스 스틸)의 난연1급실험은 적합하였으며, 실험체(FRP, AL, 스테인레스 스틸)의 화염전파실험에서 착화되지 않았고, 실험체 모두의 산소지수는 약 $50\%$, 가연성실험은 V-0급으로 나타났다. 또한 연기밀도 챔버를 이용한 Flaming mode에서 최대연기밀도는 43-338 및 덕성지수는 0.57-1.12인 것으로 나타났다.

토양 중 브롬화다이옥신류의 분석법 고찰

  • 김태승;신선경;이정희
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2003년도 총회 및 춘계학술발표회
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    • pp.413-417
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    • 2003
  • The last few decades have seen drastic growth in the use of brominated flame retardants(BFRs). There is the problems of polybrominated dibenzo-p-dioxins(PBDDS) and polybrominated dibenzofurans(PBDFs) generation as by-products in combustion process of BFRs. PBDDs/PBDFs are highlighted the new pollutants of environmental contamination, recently. In this study, the 10 kinds of PBDDs/PBDFs standards were used to perform the experiments of recoveries. The analysis of PBDDs/PBDFs in soil environmental samples. was carried out. In silica gel column cleanup, PBDDs/PBDFs eluted until 80mL of n-hexane, and the recovery was obtained 73∼105%. In multi-layer silica gel column cleanup, the recovery was obtained 56∼125% with various elution solvents. In alumina clean process, the standard mixture(PBDES, PBDDs/PBDFs) eluted the first fraction of 2% dichloromethane with n-hexane in the range of 0∼100mL, PBDEs compounds eluted in the second fraction of 50% dichloromethane with n-hexane. In activated carbon column cleanup, the PBBEs eluted to the first fraction(n-hexane) and second fraction(toluene), but PBDDs/PBDFs only eluted to the second fraction. The analytical methods of PBDDs/PBDFs for soil was established based on the experimental results of the environmental samples.

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CURRENT RESEARCH AND DEVELOPMENT ACTIVITIES ON FISSION PRODUCTS AND HYDROGEN RISK AFTER THE ACCIDENT AT FUKUSHIMA DAIICHI NUCLEAR POWER STATION

  • NISHIMURA, TAKESHI;HOSHI, HARUTAKA;HOTTA, AKITOSHI
    • Nuclear Engineering and Technology
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    • 제47권1호
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    • pp.1-10
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    • 2015
  • After the Fukushima Daiichi nuclear power plant (NPP) accident, new regulatory requirements were enforced in July 2013 and a backfit was required for all existing nuclear power plants. It is required to take measures to prevent severe accidents and mitigate their radiological consequences. The Regulatory Standard and Research Department, Secretariat of Nuclear Regulation Authority (S/NRA/R) has been conducting numerical studies and experimental studies on relevant severe accident phenomena and countermeasures. This article highlights fission product (FP) release and hydrogen risk as two major areas. Relevant activities in the S/NRA/R are briefly introduced, as follows: 1. For FP release: Identifying the source terms and leak mechanisms is a key issue from the viewpoint of understanding the progression of accident phenomena and planning effective countermeasures that take into account vulnerabilities of containment under severe accident conditions. To resolve these issues, the activities focus on wet well venting, pool scrubbing, iodine chemistry (in-vessel and ex-vessel), containment failure mode, and treatment of radioactive liquid effluent. 2. For hydrogen risk: because of three incidents of hydrogen explosion in reactor buildings, a comprehensive reinforcement of the hydrogen risk management has been a high priority topic. Therefore, the activities in evaluation methods focus on hydrogen generation, hydrogen distribution, and hydrogen combustion.