• 한국수소및신에너지학회논문집
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• 제27권5호
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• pp.562-570
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• 2016

At the carbon dioxide capture process using the aqueous amine solution, degradation of absorbents is main factor to reducing the process performance. Also, degradation mechanism of absorbent is important for understanding the environmental risk, route of degradation products, health risk etc. In this study, the degradation products of MEA were studied to clarify mechanism in thermal degradation process. The degradation products were analyzed using a $^1H$ NMR (nuclear magnetic resonance) and $^{13}C$ NMR. The analysis methods used in this study provide guidelines that could be used to develop a degradation inhibitor of absorbent and a corrosion inhibitor.

• Journal of the Korean Wood Science and Technology
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• 제31권3호
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• pp.1-10
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• 2003

Shredded waste newspapers, waste acrylic raw fibers, and urea-formaldehyde (UF) adhesives, at 10% by weight on raw material, were used to produce recycled waste paper-waste acrylic raw fiber composite boards in laboratory scale experiments. The physical and mechanical properties of fire retardant treated recycled waste paper-waste acrylic raw fiber composite boards were examined to investigate the possibility of using the composites as internal finishing materials with specific gravities of 0.8 and 1.0, containing 5, 10, 20, and 30(wt.%) of waste acrylic raw fiber and 10, 15, 20, and 25(wt.%) of fire retardant (inorganic chemical, FR-7^®) using the fabricating method used by commercial fiberboard manufacturers. The bending modulus of rupture increased as board density increased, decreased as waste acrylic raw fiber content increased, and also decreased as the fire retardant content increased. Mechanical properties were a little inferior to medium density fiberboard (MDF) or hardboard (HB), but significantly superior to gypsum board (GB) and insulation board (IB). The incombustibility of the fire retardant treated composite board increased on increasing the fire retardant content. The study shows that there is a possibility that composites made of recycled waste paper and waste acrylic raw fiber can be use as fire retardant internal finishing materials.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2006년도 제33회 KOSCO SYMPOSIUM 논문집
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• pp.86-94
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• 2006

This paper investigates the effects of acoustic forcing on NOx emissions and mixing process in the near field region of turbulent hydrogen nonpremixed flames. The resonance frequency was selected to force the coaxial air jet acoustically, because the resonance frequency is effective to amplify the forcing amplitude and reduce NOx emissions. When the resonance frequency is acoustically excited, a streamwise vortex is formed in the mixing layer between the coaxial air jet and coflowing air. As the vortex develops downstream, it entrains both ambient air and combustion products into the coaxial air jet to mix well. In addition, the strong vortex pulls the flame surface toward the coaxial air jet, causing intense chemical reaction. Acoustic excitation also causes velocity fluctuations of coaxial air jet as well as fuel jet but, the maximum value of centerline fuel velocity fluctuation occurs at the different phases of $\Phi$=$180^{\circ}$ for nonreacting case and $\Phi$=$0^{\circ}$ for reacting case. Since acoustic excitation enhances the mixing rate of fuel and air, the line of the stoichiometric mixture fraction becomes narrow. Finally, acoustic forcing at the resonance frequency reduces the normalized flame length by 15 % and EINOx by 25 %, compared to the flame without acoustic excitation.

• 한국안전학회지
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• 제27권5호
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• pp.9-15
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• 2012

The ignition characteristics in a confined axisymmetric coflow $CH_4$ jet were investigated numerically with the Fire Dynamics Simulator(FDS). The $CH_4$ fuel stream was diluted with main combustion product gases, such as $O_2$, $N_2$, CO, $CO_2$, and $H_2O$, and the mixed fuel stream was heated up to the sufficient temperature where a supplying fuel stream can be ignited. For the calculation of chemical reaction in the simulation, a 2-step global finite chemistry model was considered. Boundary condition for confined wall was optimized by investigating the effects of wall temperature on the ignition characteristics of fuel stream. In addition, the effects of composition of diluents in the fuel stream and fuel stream temperature on the ignition of fuel steam were investigated. The ignition characteristics of $CH_4$ stream with diluents were very sensitive to the wall temperature, composition of diluents in the fuel stream and fuel stream temperature.

• 오토저널
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• 제5권1호
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• pp.45-53
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• 1983

There exist many kinds of frictions in internal combustion engine such as piston ring and skirt, cam and tappet, bearing friction etc. Among them, the frictions between piston ring, skirt and cylinder are particular. These frictions for motoring test are differ from that of firing test even though the temperature of cooling water and lubricating oil keep identically. The frictions for firing test are increased due to combustion pressure and products. The precise calculation of the friction is difficult. But we can assume that the friction is governed by the viscosity of lubricating oil and gas pressure of cylinder. And the viscosity of lubricating oil is dependant on gas temperature of cylinder, so the piston friction may be governed by gas pressure and temperature of cylinder. In this treatise, we propose the method of evaluating piston friction under the condition of constant engine speed, and we analyzed the behaviours and influence of factors concerned with the piston friction for output correction when the inlet pressure and temperature were varied. The main results are as follows: 1) The behaviours on the inlet conditions for the contact force of the piston rings and the viscosity of the lubricating oil concerned with piston friction are found. 2) The essential point the these behaviours is dependant on the cyclic variation following to the inlet conditions. 3) According to our analysis, It was observed that the viscosity of lubricating oil is more effective than the contact force to the piston rings.

• 유통과학연구
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• 제18권9호
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• pp.67-75
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• 2020

Purpose: The purpose of this study is to enhance sales promotion efficiency for using solid refuse fuel facilities. Renewable energy technology using Solid Refuse Fuel (SRF) is an economic efficiency technology that recovers waste by burning various wastes. A survey on the pollutants discharged from the solid fuels facilities was investigated so that the SRF facilities could be expanded, distributed and reflected in the policy. Research design, data, and methodology: In this study, 9 business sites using SRF and Bio-SRF as main raw materials were investigated for 2 years. The characteristics of target business sites such as the type of fuel used, combustion method, combustion temperature, daily fuel consumption and environmental prevention facilities were studied. Results: The average pollution & ammonia concentration of Bio-SRF facilities was found to be 88.15% higher than that of SRF facilities. But the average acetaldehyde concentration of SRF facilities was found to be 88.15% higher than that of Bio-SRF facilities. Conclusions: The main issue is how much electric power generation using combustible materials affects air pollution. The waste recycling law provides the standard value according to the fuel property, but there is a considerable gap with the mixed fuel. Therefore, for efficient utilization of facilities using solid fuel products, additional research is needed to improve the distribution structure of exhaust pollutants is needed.

• 한국연소학회지
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• 제15권3호
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• pp.32-39
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• 2010

An experimental study was conducted to investigate the relationship between global equivalence ratio(GER) and fire characteristics in an ISO 9705 room. Heptane fuel was burned with different fuel flow rates and doorway widths in order to force the room to be placed in different GER conditions. It was observed that after the onset of under-ventilated fire conditions, temperature and unburned fuel components such as CO and soot increased with increasing heat release rate (HRR), regardless of the doorway width. From the analysis of local mixture fraction, it was reconfirmed that the inclusion of soot production in the product composition was very important to predict accurately the chemical conditions inside the compartment, particularly for the under-ventilated fire conditions. In addition, the local equivalence ratio (LER) was directly proportional to the GER with a unit gradient regardless of doorway width when the soot production was included in the chemical products. This finding provided an important potential that the GER could be used to correlate the local thermal and chemical environment measured at the upper layer of a full-scale enclosure when soot was included.

• 한국세라믹학회지
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• 제34권11호
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• pp.1165-1172
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• 1997

ZrB2 powders were prepared from a mixture of ZrO2, B2O3 and Mg by self-propagating high temperature synthesis method. The combustion product was successfully obtained from a mixture of ZrO2:B2O3:Mg=1:2:8.5 molar ratio. By-product, MgO was effectively removed by leaching with 1M HCl solution at 9$0^{\circ}C$ for over 5hours. After leaching, the Mg content was 0.86~1.42 wt%, and the mean particle size was 4.72${\mu}{\textrm}{m}$. The addition of 7.5 wt%(14Ni:1.0C) as a sintering aid greatly densified ZrB2 bodies compared with that of only Ni. The ZrB2 sintered bodies containing 7.5 wt%(14Ni:1.0C) was 94.3% of the theoretical density. In this case, ZrB2 existed as a major phase and had a bend strength of 300 MPa and a vickers hardness of 2000 kg/$\textrm{mm}^2$.

• 대한기계학회논문집
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• 제19권2호
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• pp.559-567
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• 1995

The combustion process within a porous inert medium (PIM) burner is numerical studied. A detailed chemical reaction scheme including thermal and prompt NO$_{x}$ reactions is used to predict the formation and destruction of pollutants such as NO$_{x}$ and CO. The reaction paths for NO$_{x}$ formation are divided to quantify the amount of NO$_{x}$ formed through thermal NO$_{x}$ reaction or through prompt NO$_{x}$ reaction. Emission index is calculated to compare the actual mass of NO$_{x}$ or CO produced through the combustion of unit mass of fuel. It is found NO formation in PIM burner is confined in flame zone and formation is suppressed due to heat loss at down-stream of the flame. Higher production of NO through prompt NO reaction path is observed due to the higher concentration of fuel derivative species and its higher diffusion at flame front. For all equivalence ratios, CO emission within PIM burner is lower than that from the one-dimensional freely-propagating flame. PIM burner flame has better NO$_{x}$ emission index from .psi. = 0.75 to .psi. = 1.1. to .psi. = 1.1.

• Journal of the Korean Wood Science and Technology
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• 제36권2호
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• pp.1-8
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• 2008

This study was performed to evaluate the burning characteristics of wood-based materials and the effect of surface treatment of fire retardant using cone calorimeter. Four types of wood-based materials, such as Plywood, Oriented Strand Board (OSB), Particle Board (PB) and Medium Density Fiberboard (MDF), were tested at a constant heat flux of $50kW/m^2$ to investigate the time to ignition, mass loss rate, heat release rate, effective heat of combustion, etc. In addition, each type of wood-based material was tested at the same heat flux after fire retardant treatment on the surface to evaluate the effect of this treatment on the burning characteristics. The surface treatment of fire retardant, by the amount of $110g/m^2$, delayed the time to ignition almost twice. However, it was indicated that heat release rate, mass loss rate, and effective heat of combustion were not significantly affected by fire retardants treatment for all types of wood-based materials.