• Journal of Korean Society of Environmental Engineers
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• v.27 no.2
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• pp.170-176
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• 2005

This study was conducted to investigate the level of PCBs and distribution of PCB congeners in the ambient air of Korea and Japan. The source of PCBs were also studied by a statistical method. The TEQ concentration of PCB in the ambient air of Korea and Japan were between 0.003 and $1.01\;pgTEQ/m^3$(mean value : $0.22\;pgTEQ/m^3$) and between 0.002 and $0.014\;pgTEQ/m^3$ (mean value: $0.007\;pgTEQ/m^3$), respectively. The ambient air of industrial area of Korea showed a fluctuation in PCB concentration than other sampling area. The isomer distribution patterns in the ambient air was more or less similar in all sampling places. In addition, highly chlorinated homologues ($7{\sim}10CB$) were detected in the only Korea industrial area. This observation suggests that there is a possibility of specific source of PCBs in the industrial area. The source identification of PCB in ambient air was performed using multivariate statistical analysis(principal component analysis). As a result, it is estimated that the Korean ambient air was more influenced by combustion process than the ambient air of Japan and also the effect of PCB commercial products was relatively a small.

• Korean Chemical Engineering Research
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• v.53 no.3
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• pp.333-338
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• 2015

In this study, we investigated carbonation-regeneration and agglomeration characteristics of dry sorbents. Experiment has been proceeded in the batch-type reactor, which is made of quartz: 0.05 m of I.D and 0.8 m in height. The sorbents that is collected at the cyclone of the carbonation reactor of continuous process were used in this study. The reactivity was studied at the various concentrations of water vapor, $N_2$ and $CO_2$ in the fluidizing gas at regeneration reaction. As a result, the reactivity increased as the regeneration temperature increased, the reactivity decreased as the concentration of water vapor increased. The absorption capacity showed the highest value in case of using $N_2$ 100% as regeneration gas. And decreased in order of $H_2O+N_2$, $CO_2$ 100% and $H_2O+CO_2$. The agglomeration characteristics were investigated according to the particle sizes and concentrations of water vapor at carbonation reaction. As a result, the particle with smaller size and higher concentration of water vapor showed the higher agglomeration characteristic.

• Clean Technology
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• v.20 no.1
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• pp.1-6
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• 2014

$CO_2$ is generated by the combustion reaction, when getting the energy from fossil fuel. If the carbon dioxide emissions increases more, the global warming problem will become more serious. CCS (carbon capture storage) needs to be developed for the prevention of this. When liquefied $CO_2$ is transported, BOG (boil-off gas) is generated because of several problems. In the study, by injecting liquefied $CO_2$ in two tanks which contains $40m^3$each, the amount of BOG and its composition were measured during 30 days when generating pressure changes and external heat, loading, unloading. In result, 16,040 kg of BOG was generated and the composition has been found out to be 99.95% $CO_2$ and 0.05 % $N_2$. Also, we conducted simulation process for reliquefaction of generated BOG with vapor compression cycle using the PRO/II with PROVISION version 9.2. As a result, the refrigeration cycle of the total circulation flow rate was 42.07 kg/h and the condenser utility consumption was 48.85 kg/h.

• Clean Technology
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• v.20 no.2
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• pp.179-188
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• 2014

The effect of desorption pressure on $CO_2/N_2$ breakthrough behaviors for 4 different adsorbents was studied at a fixed bed. Zeolite 3A, 4A, 5A, and 13X pellets were used as adsorbents. Cyclic operations were executed with varying desorption pressure from vacuum (0 bar) to 3 bar while other conditions such as adsorption step pressure (3 bar), temperature (293 K), composition ($CO_2:N_2=10:90$vol%) and flow rate (400 ccm) were fixed at constant values. Each adsorption and desorption step was set as 80 min, which totaled up to 160 min per a cycle. 5 cycles with adsorption and desorption steps were run overall. After the experiment, breakthrough time, saturation time, and adsorption amount were measured and compared in order to find an optimum adsorbent and a proper operating condition for a post combustion $CO_2$ capture process.

• Journal of Physiology & Pathology in Korean Medicine
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• v.23 no.6
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• pp.1332-1340
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• 2009

Moxa-combustion therapy makes use of heat stimulus and chemicals result form when cauterize the skin with moxa cones to medical cares. Despite an extensive evidence-base guiding the selection of stimulation parameters and attributes of subject, little methodologically research regarding the attributes of moxa cautery in need to provide effective stimulation. To determine moxibustion's effects of the three different moxa cautery made by three different company(as A, B, C), the small intestinal motility in rats were observed after moxibustion at ST36. Under anesthesia, each intensities(1, 5, 10 times), two regions(left and right at ST36) and a quantity(as number of 1, 5, 10 times at once) were applied to the groups divided with sex. In each intensities groups, the A product made increase with 5, 10 times in male and female group. The B and C product made increase with 10 times in male group and the B product made increase with 1, 5, 10 times and the C product made increase with 5 times in female group. In two regions(left and right at ST36) groups, the A and C product made increase with 1(right), 5(right) times and the B product made increase with 1(left), 10(left), 10(right) times in male group. In female group, the A product made increase with 5(left), 5(right), 10(right) times and the B product made increase with 1(left), 10(left), 10(right) times and the C product made increase with 5(left), 10(left) times. In a quantity(as number of 1, 5, 10 times at once) groups, the A and B product did not show any changes but the C product made increase with a quantity of 10 times in male group. In female group, The B product made increase with a quantity of 1 times and the C product made increase with a quantity of 5 times, but the A product did not show any changes. Three different moxa cautery made by three different company made differents result in each group divided with sex. With these results, it was suggested that we should consider the a process of manufacture and moxa cautery's quality for the adequate value of moxibustion.

• Journal of Korean Society of Environmental Engineers
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• v.29 no.5
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• pp.521-527
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• 2007

To investigate the relationship between PCB sources and concentration level in soil, PCBs concentration of 8 soil samples around Shiwa industrial complex were measured. The concentration of PCBs in soil samples were ranged from 2.43 to 274 ng/g dry (0.116 to 60.5 pg WHO-TEQ/g dry) md off-gas were ranged from 48.6 to $2872ng/m^3(0.00150\sim15.2ng\;WHO-TEQ/m^3)$; these are similar levels with results of previous study in Korea. The homologue patterns in soil samples were varied from sample to sample, but isomer patterns were very similar with each other. The two principal components were extracted by Principal Component Analysis(PCA) of 8 soil samples and cumulative factor loading was 95.7%. As the result of PCA, it could be expected that PCBs in soil samples of this study were more affected by PCB products than combustion process and mostly affected by already-known sources.

• Journal of the Korean Society of Safety
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• v.26 no.4
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• pp.47-58
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• 2011

Halogen free intumescent flame retardants(IFRS), such as the mixture of melamine phosphate(MP) and char forming agents(pentaerythritol(PER), di-pentaerythritol(DiPER), tris(2-hydroxyethyl) isocyanurate(THEIC)), were prepared and characterized. Polypropylene(PP)/$IFR_S$ composites were also prepared in the presence of ethylene diamine phosphate(EDAP) as a synergist and used into flame retardant PP powder coatings. Thermoplastic PP powder coatings at 20 wt% flame retardant loading were manufactured by extruded and then mechanical cryogenic crushed to bring them in fine powder form. These intumescent flame retardant powder coatings($IFRPC_S$) were applied on mild steel surface for the purpose of protection and decorative. It is a process in which a $IFRPC_S$ particles coming in contact with the preheated mild steel surface melt and form a thin coating layer. The obtained MP flame retardant was analyzed by utilizing FTIR, solid-state $^{31}P$ NMR, ICP, EA and PSA. The mechanical properties as tensile strength, melt flow index(MFI) and the thermal property as TGA/DTA and the fire safety characteristics as limiting oxygen index(LOI), UL94 test, SEM were used to investigate the effect of $IFRPC_S$. The experimental results show that the presence of $IFR_S$ considerably enhanced the fire retardant performances as evidenced by the increase of LOI values 17.3 vol% and 32.6 vol% for original PP and $IFRPC_S$-3(PP/MP-DiPER/EDAP), respectively, and a reduction in total flaming combustion time(under 15 sec) in UL94 test of $IFRPC_S$. The prepared $IFRPC_S$-3 have good comprehensive properties with fire retardancy 3.2 mm UL94 V-0 level, LOI value 32.6%, tensile strength $247.3kg/cm^2$, surface roughness Ra $0.78{\mu}m$, showing a better application prospect. Through $IFRPC_S$-2(PP/MP-PER/EDAP) and $IFRPC_S$-3 a better flame retardancy than that of the $IFRPC_S$-1(PP/MP/EDAP) was investigated which was responsible for the formed more dense and compact char layer, improved synergy effect of MP and PER/DiPER.

• Journal of Navigation and Port Research
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• v.39 no.6
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• pp.457-463
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• 2015

A gas turbine engine plays an important role as a prime mover that is used in the marine transportation field as well as the space/aviation and power plant fields. However, it has a complicated structure and there is a time delay element in the combustion process. Therefore, an elaborate mathematical model needs to be developed to control a gas turbine engine. In this study, a modeling technique for a gas generator, a PLA actuator, and a metering valve, which are major components of a gas turbine engine, is explained. In addition, sub-models are obtained at several operating points in a steady state based on the trial running data of a gas turbine engine, and a method for controlling the engine speed is proposed by designing an NPID controller for each sub-model. The proposed NPID controller uses three kinds of gains that are implemented with a nonlinear function. The parameters of the NPID controller are tuned using real-coded genetic algorithms in terms of minimizing the objective function. The validity of the proposed method is examined by applying to a gas turbine engine and by conducting a simulation.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2007.06a
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• pp.329-329
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• 2007

Photoconductive poly crystalline lead oxide coated on amorphous thin film transistor (TFT) arrays is the best candidate for direct digital x-ray detector for medical imaging. Thicker films with lessening density often show lower x-ray induced charge generation and collection becomes less efficient. In this work, we present a new methodology used for the high density deposition of PbO. We investigate the structural properties of the films using X-ray diffraction and electron microscopy experiments. The film coatings of approximately $200\;{\mu}m$ thickness were deposited on $2"{\times}2"$ conductive-coated glass substrates for measurements of dark current and x-ray sensitivity. The lead oxide (PbO) films of $200\;{\mu}m$ thickness were deposited on glass substrates using a wet coating process in room temperature. The influence of post-deposition annealing on the characteristics of the lead oxide films was investigated in detail. X-ray diffraction and scanning electron microscopy, and atomic force microscopy have been employed to obtain information on the morphology and crystallization of the films. Also we measured dark current, x-ray sensitivity and linearity for investigation of the electrical characteristics of films. It was found that the annealing conditions strongly affect the electrical properties of the films. The x-ray induced output charges of films annealed in oxygen gas increases dramatically with increasing annealing temperatures up to $500^{\circ}C$ but then drops for higher temperature anneals. Consequently, the more we increase the annealing temperatures, the better density and film quality of the lead oxide. Analysis of this data suggests that incorporation and decomposition reactions of oxygen can be controlled to change the detection properties of the lead oxide film significantly. Post-deposition thermal annealing is also used for densely film. The PbO films that are grown by new methodology exhibit good morphology of high density structure and provide less than $10\;pA/mm^2$ dark currents as they show saturation in gain (at approximate fields of $4\;V/{\mu}m$). The ability to operate at low voltage gives adequate dark currents for most applications and allows voltage electronics designs.

• Membrane Journal
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• v.23 no.5
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• pp.352-359
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• 2013

In the present study, $CO_2$ permeation through a hydrophilic NaY zeolite membrane was studied under permeate evacuation mode for $CO_2$ single gas, $CO_2-N_2$ and $CO_2-O_2$ binary mixtures, and $CO_2-N_2-O_2$ ternary mixture. It was reconfirmed that the $CO_2$ permeation was governed by surface diffusion and the $CO_2$ selectivity was induced from blocking effect of adsorbed $CO_2$ molecules. The $CO_2$ permeance measured in permeate evacuation mode was much lower than that done in He sweeping mode, but was comparable to that obtained under feed pressurization mode. The NaY zeolite membrane showed a considerable $CO_2$ separation for $14%CO_2-80%N_2-6%O_2$ mixture : $CO_2$ permeance was about $1{\times}10^{-7}mol/m^2secPa$ and $CO_2$ selectivity was more than 10. Therefore, it was concluded that NaY zeolite membrane was one of promising membranes for post-combustion CCS process.