• 한국응용과학기술학회지
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• 제29권1호
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• pp.129-140
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• 2012

우리나라에서 건축물 내장재의 화재안전성능은 국토해양부 고시 제2011-39호에 의한 평가방법에 의해 불연성시험(KS F ISO 1182), 열방출률시험(KS F ISO 5660) 및 가스유해성시험(KSF 2271)을 실시하여 그 결과로서 분류하도록 되어 있다. 그 중 연기 및 연소독성가스에 대한 시험인 가스 유해성 시험은, 건축재료 및 내장재의 연소시 발생하는 가스의 유해성을 마우스의 평균 행동정지시간으로 측정하는 방법으로 사용하여 왔다. 이 중 연소 독성가스 4종(HCl, HF, HCN, $SO_2$) 흡입독성시험방법의 확립을 위하여 ICR계 mouse와 전신흡입노출장치를 이용하여, 독성가스 노출 및 병리검사를 수행하였다. 그 결과 호흡기관지와 가까운 폐포에서 대식세포(Macrophage)의 침윤을 유발하는 것으로 나타났고, 4종의 물질에 대한 조직의 병리검사로 전체적으로 충혈과 울혈은 확인되었다. 조직 중 폐와 신장에서 조직손상이 심하였고, 물질로는 HCN이 가장 많은 병리소견을 보였다.

• 대한기계학회논문집B
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• 제27권9호
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• pp.1209-1219
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• 2003

The dynamic behaviors of the single vortex interacting with $CH_4-Air$ jet diffusion flame are investigated numerically. The numerical method is based on a predict-corrector scheme for a low Mach number flow. A two-step global reaction mechanism is adopted as a combustion model. Studies are conducted in fixed initial velocities for the three cases according as where $CO_2$ is added; (1) without dilution, (2) dilution in fuel stream and (3) dilution in oxidizer stream. A single vortex is generated by an axisymmetric jet, which is made by an impulse of a cold fuel when a flame is developed entirely in a computational domain. The simulation shows that $CO_2$ dilution in fuel stream results in somewhat larger vortex radius, and greater amount of entrainment of surrounding fluid than in other cases. Thus, the dilution of $CO_2$ in fuel stream enhances the mixing in single vortex and increases the stretching of the flame surface. The budgets of the vorticity transport equation are examined to reveal the mechanism of vortex formation when $CO_2$ is added. It is found that, in the case of $CO_2$ dilution in fuel stream, the vortex destruction due to volumetric expansion and the vortex production due to baroclinic torque are more dominant than in other cases.

• 자원리싸이클링
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• 제27권3호
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• pp.93-99
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• 2018

본 연구에서는 디스플레이 산업의 백금 폐스크랩을 용해, 용매추출을 통하여 백금족 성분을 효율적으로 추출하고, 추출된 백금용액을 디젤자동차 배가스 정화촉매용 전구체 용액으로서 제조하고, 그 촉매활성을 실험하였다. 용액화학적 이론 연구를 통하여 백금 화학종의 수용액상 거동을 조사하였고, 화학종들의 존재영역 및 거동을 근거로 추출 및 분리 가능방안을 수립하였다. 전기화학적 방법에 의해 폐스크랩을 용해시킴으로써, 용해시간 단축 및 추출효율을 높였으며, 로듐 성분을 분리 제거, TBP에 의한 용매추출, 염산에 의한 탈거 공정을 거쳐 Pt-Chloride-$H_2O$ 계 백금용액을 용액을 제조하고, 이 용액을 원료로 액상 아민화 반응을 통해 아민산 백금용액을 제조한 다음, 카본블랙의 연소반응에 대한 촉매 활성을 실험함으로써, 백금족 폐스크랩으로부터 고부가 백금족 화합물의 제조가능성을 연구하였다.

• 한국자동차공학회논문집
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• 제22권3호
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• pp.42-49
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• 2014

The gasoline direct injection (GDI) system is considerably spreading in automotive market due to its advantages. Nevertheless, since GDI system emit higher particle matter (PM) due to its combustion characteristics, it is difficult to meet strengthened emission regulation in near future. For this reason, a combined GDI with MPI system, so-called, dual injection (DUI) system is being investigated as a supplemental measure for the GDI system. This paper focused on power and fuel consumption effect by injection mode strategy of DUI system in part load and idle engine operating condition. In this study, port fuel injectors are installed on 2.4 liters GDI production engine in order to realize DUI system. And, at each injection mode, DOE (design of experiment) method is used to optimize engine control parameters such as dual injection ratio, start of injection timing, end of injection timing, CAM position and so on. As a consequence, DUI mode shows slightly better or equivalent fuel efficiency compared to conventional GDI engine on 9 points fuel economy mode as well as MPI mode shows less fuel consumption than GDI mode during idle operation. Furthermore, DUI system shows improvement potential of maximum 2.0% fuel consumption and 1.1% performance compared to GDI system in WOT operating condition.

• 한국자동차공학회논문집
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• 제22권4호
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• pp.1-9
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• 2014

The vast stores of biomass available in the worldwide have the potential to displace significant amounts of petroleum fuels. Fast pyrolysis of biomass is one of several paths by which we can convert biomass to higher value products. The wood pyrolysis oil (WPO) has been regarded as an alternative fuel for petroleum fuels to be used in diesel engine. However, the use of WPO in a diesel engine requires modifications due to low energy density, high water contents, high acidity, high viscosity, and low cetane number of the WPO. One possible method by which the shortcomings may be circumvented is to co-fire WPO with other petroleum fuels. WPO has poor miscibility with light petroleum fuel oils; the most suitable candidates fuels for direct fuel mixing are methanol or ethanol. Early mixing with methanol or ethanol has the added benefit of significantly improving the storage and handling properties of the WPO. For separate injection co-firing, a WPO-ethanol blended fuel can be fired through diesel pilot injection in a dual-injection dieel engine. In this study, the performance and emission characteristics of a dual-injection diesel engine fuelled with diesel (pilot injection) and WPO-ethanol blend (main injection) were experimentally investigated. Results showed that although stable engine operation was possible with separate injection co-firing, the fuel conversion efficiency was slightly decreased due to high water contents of WPO compare to diesel combustion.

• Tribology and Lubricants
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• 제28권6호
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• pp.315-320
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• 2012

For proper functioning, general machines usually need lubricant oil as a cooling, cleaning, and sealing agent at points of mechanical contact. The quality of lubricant oil can deteriorate during operation owing to various causes such as high temperature, combustion products and extraneous impurities. In this study, a heavy load stopped during operation, and the oil was analyzed to check whether any impurities were added. Extraction using acetonitrile followed by reaction with BSTFA(bistrimethylsilyl trifluoroacetamide) showed that, trimethylsilylated ethylene glycol was present in the lubricant oil. To quantify the ethylene glycol in the oil, deuterium-substituted ethylene glycol, which acted as an internal standard, was added to the sample and then extracted with the solvent. Next, the extract was reacted with the derivatizing agent(BSTFA) and then analyzed with GC/MS. The detection limit of this method was found to be $0.5{\mu}g/g$ and the recovery of oil containing $20,000{\mu}g/g$ of ethylene glycol was measured to be 94.8%. A damaged O-ring and eroded cylinder liner were found during the overhaul, which implied the leakage of coolant containing ethylene glycol into the lubricating system. The erosion of the cylinder liner was assumed to be due to cavitation of the coolant in the cooling system.

• 대한기계학회논문집B
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• 제25권4호
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• pp.600-609
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• 2001

WSGGM based low-resolution spectral model for calculating radiation transfer in combustion gases is applied to estimate self-absorption of radiation energy in one-dimensional opposed flow flames. Development of such a model is necessary in order to enable detailed chemistry-radiation interaction calculations including self-absorption. Database of band model parameters which can be applied to various one-dimensional opposed flow diffusion and partially premixed flames is created. For the validation of the model and database, low resolution spectral intensities at fuel exit side are calculated and compared with the results of a narrow band model with those based on the Curtis-Godson approximation. Good agreements have been found between them. The resulting radiation model is coupled to the OPPDIF code to calculate the self-absorption of radiant energy and compared with the results of an optically thin calculation and the results of a discrete ordinates method in conjunction with the statistical narrow band model. Significant self-absorption of radiation is found for the flames considered here particularly for the fuel side of the reacting zone. However, the self-absorption does not have significant effects on the flame structure in this case. Even in the case of the low velocity diffusion flame and the partially premixed flame of low equivalence ratio, the effects of self-absorption of radiation on the flame temperature and production of minor species are not significant.

• 한국화재소방학회논문지
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• 제28권6호
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• pp.8-12
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• 2014

현행 건축법은 건축물의 규모, 용도에 따라 화재확산방지와 재실자의 보호를 위하여 실내 마감 재료를 불연, 준불연, 난연재료로 시공하도록 규정하고 있으며, 가스 유해성 시험(KS F 2271)에 따라 해당 시료의 연소 생성물에 노출된 실험용 쥐의 평균행동정지시간을 측정하여 연소 생성물의 유해성을 평가하고 있다. 실험용 쥐를 대상으로 가스상, 입자상 물질의 복합적 유해효과를 분석한 결과인 평균행동정지시간이 15분의 노출 시험 중 9분 이내로 측정된 경우, 연소 유해성 평가 결과가 부적합한 것으로 판정한다. 이에 본 연구에서는 연소 생성물에 포함된 가스상, 입자상 물질 중에서 실험용 쥐의 행동정지에 미치는 영향이 큰 요소를 규명하기 위하여 연소 생성물에 포함된 입자상 물질의 입도 분석을 실시하여 위험도의 상관관계를 밝혔다.

• 한국소음진동공학회:학술대회논문집
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• 한국소음진동공학회 2006년도 춘계학술대회논문집
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• pp.197-202
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• 2006

The low-altitude earth observation satellite is generally equipped with high performance camera as a main payload which is vulnerable to vibration environment. During the launch process of a satellite, the combustion and jet noise of launch vehicle produce severe acoustic environment and the acoustic loads induced may damage the critical equipments of the satellite including the camera. Therefore to predict and simulate the effect of the acoustic environment which the satellite has to sustain at the lift-off event is very important process to support the load-resistive design and test-qualification of components. Statistical Energy Analysis(SEA) has been widely used to estimate the vibro-acoustic responses of the structures and gives statistical but reliable results in the higher frequency region with less modeling efforts and calculation time than the standard FEA. In this study, SEA technique has been applied to a 3-Dimensional model of a low-altitude earth observation satellite to predict the acceleration responses on the structural components induced by the high level acoustic field in the launch vehicle fairing. In addition, the expected response on each critical component panel was calculated by the classical method in consideration of the mass loading and imposed sound pressure level, and then compared with SEA results.

• 한국자동차공학회논문집
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• 제8권1호
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• pp.148-156
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• 2000

For the in-line three cylinder engine whose crankshaft has a phase of 120 degrees, the total sum of unbalanced inertia forces occurring in each cylinder will be counterbalanced among three cylinders. However, parts of inertia forces generated at the No.1 and No.3 cylinders will cause a primary moment about the No.2 cylinder. In order to eliminate this out-of-balance moment, a single balance shaft has been attached to the cylinder block so that the engine durability and riding comfort may be further improved. Accordingly, the forced vibration analysis of the in-line three cylinder engine must be implemented to meet the required targets at an early design stage. In this paper, a method to reduce noise and vibration in the 800cc, in-line three cylinder LPG engine is suggested using the multibody dynamic simulation. The static and dynamic balances of the in-line three cylinder engine are investigated analytically. The multibody dynamic model of the in-line three cylinder engine is developed where the inertia properties of connecting rod, crankshaft, and balance shaft are extracted from their FE-models. The combustion pressure within the No.1 cylinder in three significant operating conditions(1500rpm-full load, 4000rpm-full load and 7000rpm-no load)is measured from the actual tests to excite the engine. The vibration velocities at three engine mounts with and without balance shaft are evaluated through the forced vibration analysis. Obviously, it is shown that the vibration of the in-line three cylinder engine with balance shaft is reduced to the acceptable level .