• Bulletin of the Korean Chemical Society
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• 제28권1호
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• pp.59-62
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• 2007

A quantitative analysis method of halogen elements in volatile organohalogen compounds was established by the Wickbold combustion pretreatment in an enclosed system and ion chromatography. The sample pretreatment parameters of Wickbold combustion were experimentally optimized, and using the determined optimal pretreatment parameters, the reproducibility was estimated by ion chromatography. As a comparison for real samples, NIST certified reference materials (CRMs) were analyzed for the recovery efficiency and reproducibility.

• 한국분무공학회지
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• 제27권1호
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• pp.36-41
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• 2022

In this study, the combustion instability characteristics according to the change in the hydrogen ratio in the fuel in the single nozzle system of the hydrogen-natural gas mixed gas turbine for power generation was analyzed using a three-dimensional finite element analysis-based Helmholtz solver. This combustor shows the instability characteristics in which mode transition occurs from a mode having a low amplitude near 70 Hz to a mode having a high amplitude of 250 Hz or higher as the hydrogen fraction in the fuel increases. The current modeling results are found to reasonably predict the main characteristics of the change in measured instability frequency and growth rate with the change in fuel composition.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2006년도 제33회 KOSCO SYMPOSIUM 논문집
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• pp.137-144
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• 2006

Oil-fired power plants usually use several burners and the combustion air is supplied to each burner through the complicated duct which is called windbox. A windbox should be designed to supply combustion air to each burner evenly but, due to the complicated duct shape, flow distribution in the windbox is unbalanced and uneven supplies of combustion air to each burner are induced by these unbalanced flow distribution in the windbox. These flow patterns tend to make flame unstable, increase the formation of pollutants and lower the overall combustion efficiency. To prevent these disadvantages, flow patterns in the windbox should be investigated for the uniform flow distribution. In this study, computational simulation method was used to investigate the flow distribution in the windbox and measured the velocities at the exit of burners in the real windbox to compare with CFD results. The results show two significant flow patterns. One is that the flow rates of each burner are different from each other and this means that all burners operate in different conditions of air to fuel ratio. The other is that the flow distribution at the exit of each burner is not axi-symmetric although the burner shape is axi-symmetric and this increases the pollutant products like CO.

• 대한기계학회논문집
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• 제15권1호
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• pp.328-340
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• 1991

본 연구에서는 혼합기를 연소실 내로 공급하기 전에 필터를 이용하여 일정 크 기의 미립자를 제거함으로서 가능한 Mie산란의 영향을 감소시키고, 또 화학 발광의 영 향을 제거하기 위하여 광학장치의 개선 및 광학 필터를 사용하였다. 뿐만 아니라 연 소실 내의 배경광 및 반사산란광을 제거하기 위한 방법으로 입사창 및 연소실 내를 모 두 코팅을 하였다. 따라서 레이저 레일레이 산란을 이용하여 지금까지 나타난 문제 점들을 위와 같은 방법으로 개선하였을 뿐만 아니라 측정기술을 향상시켜 정적연소실 내에서의 온도를 측정함으로서 정적연소실 내에서의 온도측정이 가능하다는 것을 확인 하고, 또 그 적응성을 조사하는데 중점을 두어 실험을 하였다.

• 한국연소학회지
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• 제7권4호
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• pp.29-35
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• 2002

[$CO_2$] is a well-known greenhouse gas, which is the major source of global warming. Many researchers have studied to reduce $CO_2$ emission in combustion processes. The central method of low $CO_2$ emission is Oxygen/CxHy combustion. Theoretically Oxygen/CxHy combustion only produces $CO_2\;and\;H_2O$ and allows convenient recovery of $CO_2$. The combustion characteristics, flame stability, composition in the flame zone and temperature profile were studied experimentally for various compositions of oxidant by substituting $CO_2\;for\;N_2$ with the constant $O_2$ concentration. Results showed that flame became unstable due to the high heat capacity, low transport rate and strong radiation effect of $CO_2$ in comparison with those of $N_2$. The reaction zone was quenched and broadened, as the ratio of $CO_2\;to\;N_2$ was increased. The emission of NOx in flue gas decreased due to the decreased temperature of the reaction zone. As the conversion ratio of $CO_2\;to\;N_2$ was increased, the emission of CO and the higher temperature zone increased due to decrease of reaction rate by the a quenching effect.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2005년도 제31회 KOSCO SYMPOSIUM 논문집
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• pp.85-92
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• 2005

Oil-fired power plants usually use several burners and the combustion air is supplied to each burner through the complicated duct which is called windbox. A windbox should be designed to supply combustion air to each burner evenly but, due to the complicated duct shape, flow distribution in the windbox is unbalanced and uneven supplies of combustion air to each burner are induced by these unbalanced flow distribution in the windbox. These flow patterns tend to make flame unstable, increase the formation of pollutants and lower the overall combustion efficiency. To prevent these disadvantages, flow patterns in the windbox should be investigated for the uniform flow distribution. In this study, computational simulation method was used to investigate the flow distribution in the windbox and measured the velocities at the exit of burners in the real windbox to compare with CFD results. The results show two significant flow patterns. One is that the flow rates of each burner are different from each other and this means that all burners operate in different conditions of air to fuel ratio. The other is that the flow distribution at the exit of each burner is not axi-symmetric although the burner shape is axi-symmetric and this increases the pollutant products like CO.

• Journal of Advanced Marine Engineering and Technology
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• 제27권7호
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• pp.889-898
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• 2003

The soot yield is studied by a premixed propane-oxygen-inert gas combustion in a specially designed disk-type constant-volume combustion chamber to investigate the effect of turbulence on soot formation. Premixtures are simultaneously ignited by eight spark plugs located on the circumference of chamber at 45 degree intervals in order to observe the soot formation under high pressures and high temperatures. The eight flames converged compress the end gases to a high pressure. The laser schlieren and direct flame photographs for observation field with 10 mm in diameter are taken to examine into the behaviors of flame front and gas flow in laminar and turbulent combustion. The soot volume fraction in the chamber center during the final stage of combustion at the highest pressure is measured by the in situ laser extinction technique and simultaneously the corresponding burnt gas temperature by the two-color pyrometry method. It is found that the soot yield of turbulent combustion decreases in comparison with that of laminar combustion because the burnt gas temperature increases with the drop of heat loss.

• 대한기계학회논문집B
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• 제25권12호
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• pp.1905-1910
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• 2001

Pressure resonance frequency that is caused in the combustion chamber can be interpreted by acoustic analysis. Until now the pressure resonance has been assumed and calculated to a disc type combustion chamber that neglected the combustion chamber height because the knock occurs near the TDC(top dead center). In this research FEM(finite element method) has been used to calculate the pressure resonance frequency inside the experimental engine combustion. The error of the resonance frequency obtained by FEM has decreased about 50% compared to the calculation of Draper's equation. Due to the asymmetry in the shape of the combustion chamber that was neglected in Draper's equation we could find out that a new resonance frequency could be generated. To match the experimental results, the speed of sound that satisfies Draper's equation is selected 13% higher than the value for pent-roof type combustion chamber.

• 한국자동차공학회논문집
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• 제9권4호
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• pp.1-9
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• 2001

The soot yield has been studied by a premixed propane-oxygen-inert gas combustion in a specially designed disk-type constant-volume combustion chamber to investigate the effects of pressure, temperature and turbulence on soot formation. Premixtures are simultaneously ignited by eight spark plugs located on the circumference of chamber at 45 degree intervals in order to observe the soot formation under high pressures. The eight flames converged compress the end gases to a high pressure. The laser schlieren and direct flame photographs for observation field with 10 mm in diameter are taken to examine into the behaviors of flame front and gas flow in laminar and turbulent combustion. The soot volume fraction in the chamber center during the final stage of combustion at the highest pressure is measured by the in situ laser extinction technique and simultaneously the corresponding burnt gas temperature by the two-color pyrometry method. The pressure and temperature during soot formation are changed by varying the initial charge pressure and the volume fraction of inert gas compositions, respectively. It is found that the soot yield increases with dropping temperature and rising pressure at constant equivalence ratio, and that the soot yield of turbulent combustion decreases in comparison with that of laminar combustion because the burnt gas temperature increases with the drop of heat loss.

• 한국자동차공학회논문집
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• 제5권1호
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• pp.27-37
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• 1997

Internal combustion engine is the main source of environmental pollutants and therefore better technology is required to reduce harmful elements from the exhaust gases all over the world. Especially, harmful elements from the exhaust gases are caused by incomplete combustion of mixture inside the engine cylinder and this abnormal combustion like misfire or partial burning is the direct cause of the air pollution and engine performance degradation. the object of this research is to detect abnormal combustion like misfire and to keep the engine performance in the optimal operating state. Development of a new system therefore could be applied to a real car. To realize this, the spark-plug in a conventional ignition system is used as a misfire detection sensor and breakdown voltage is analyzed. In this research, bias voltage(about 3kV) was applied to the electrodes of spark-plug and breakdown voltage signal is obtained. This breakdown voltage signal is analyzed and found that a combustion phenomena in engine cylinder has close relationship with harmonic coefficient K which was introduced in this research. Newly developed combustion diagnostic method( breakdown voltage signal analysis) from this research can be used for the combustion diagnostic and combustion control system in an real car.