• Title/Summary/Keyword: color reaction

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Electrochemical Study on the Coumarin Derivatives

  • Kim, Il Kwang;Chun, Hyun Ja;Paik, Soon Ok;Park, Sung Woo
    • Analytical Science and Technology
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    • v.8 no.4
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    • pp.655-661
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    • 1995
  • The electrochemical reduction of coumarin derivatives in 0.1M TEAP acetonitrile solution was investigated by the direct current, differential pulse polarography, cyclic voltammetry and controlled potential coulometry. The electrochemical reduction of 7-acetoxy-4-bromomethyl-coumarin(ABMC) was proceeded as an irreversible three steps(-0.58, -1.63 and -2.25 volts) of electrochemical transfer before chemical reaction. The solution color turned to yellow after the carboxyl group was reduced at 2nd step(-1.63 volts vs. Ag-AgCl) and the change in color was independant to the bromo group. Upon the basis of the results on the products analysis and the interpretaton of polarograms, a possible electrochemical reaction mechanism was suggested.

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Study on the Bioflocculant by Bacillus megaterium. #2 Characteristic of Production Condition for Bioflocculant by Bacillus megaterium (Bacillus megaterium 이 생산하는 응집제에 관하여 제 2보 Bacillus megaterium에 의한 응집제 생산특성)

  • 김도영
    • The Korean Journal of Food And Nutrition
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    • v.12 no.3
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    • pp.240-245
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    • 1999
  • The purpose of this study was to develop the new microbial bioflocculant available in a food and fer-mentation industal. This study was reported the results of the composition for optimum culture medium and elemental characteristic of crude purification bioflocculant following the previous report(I). The maximum production of the flocculant from Bacillus megaterium was observated in the culture medium containing 2% sucrose 0.3% NaNO3 0.01% tryptone 0.01% beef extract 0.05% MgSO4 ·7 H2O 0.005% CaCO3 Addition of the sucrose as carbon sources and inorganic salt such as MgSO4, CaCO3 significantly increased the production of flocculant more than nitrogen sources. In the result of color reaction of the crude purified bioflocculant it was investgated that anthrone was positive and benedict burette and nin-hydrin was negative. These result were indicated that the flocculant produced from Bacillus megaterium was a kind of exopolysaccharide.

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Preparation of Indium Oxide Particles by Spary Pyrolysis of Indium Nitrate (질산 인듐 수용액의 초음파 분무열분해에 의한 산회인듐 입자의 제조)

  • 김기영;박승민
    • Journal of the Korean Ceramic Society
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    • v.35 no.6
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    • pp.529-534
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    • 1998
  • Agglomeration-free indium oxide particles were produced by ultrasonic pyrolysis of indium nitrate(3 hy-drate) solution. Th mean size of particles was increased from 3 $\mu\textrm{m}$ to 11$\mu\textrm{m}$ with increasing intial con-centrations of indium nitrate from 0.05mol% to 4.83 mol% When the input rate of indium nitrate solution was increased from 0.1 cm3/min to 0.8cm3/min the size of particles remained same and only the pro-duction rate of particles was increased. At 300$^{\circ}C$ the particles were white color with low crystallinity. But the color turned into yellow with increasing reaction temperature. The change of particle size was not ob-served with increasing temperatuer up to 700$^{\circ}C$ IR spectrum and TGA analysis confirmed that the purity of indium oxide was increased with temperature of reaction.

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A Study on Gemmological Characters and Identificational Methods of Coral (산호의 보석학적 특성 및 감별 방법)

  • Kim, Kyung-Jin
    • The Journal of the Korea Contents Association
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    • v.5 no.6
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    • pp.146-151
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    • 2005
  • The coral is precious and organic gemstone. It is Beautifully Red color. Coral jewelry have been used for a long time in Asia. Especially in Korea, The Coral is an traditional and popular gemstone. It is significant to get the base data for the purpose of distinguishing natural coral from imitation coral by comparing about gemmological character in this study. Color, luster, transparency, streak color, refractive index, hardness, chemical reaction, ultraviolet fluorescence, specific gravity, observation of microscope and XRD analysis were conducted for identification of natural and imitation coral. As a result, natural coral has usually $CaCO_3$ composition and calcite structure. But, it is known that imitation coral impregnate calcic and dyeing materials with pigment. And they were distinguished also from not only XRD analysis but also a few simple experiments like specific gravity, refractive index and chemical reaction. Natural coral is harder and luster then imitation coral. In breaking method, the streak color is used certification.

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Characterization of Edible Film Fabricated with Channel Catfish Ictalurus punctatus Gelatin by Cross-Linking with Transglutaminase

  • Oh, Jun-Hyun
    • Fisheries and Aquatic Sciences
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    • v.15 no.1
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    • pp.9-14
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    • 2012
  • The objectives of this research were to improve the film-forming properties of Channel Catfish Ictalurus punctatus skin gelatin (CSG) by cross-linking with transglutaminase (TG), determine and optimize the TG reaction time, and characterize the mechanical and barrier properties of CSG edible film. Cross-linking of CSG was performed by TG for 0, 10, 20, 30, and 40 min at $50^{\circ}C$, and the reaction was confirmed by sodium dodecyl sulfate-polyacrylamide gel electrophoresis (SDS-PAGE). The color and mechanical and barrier properties of edible films fabricated with CSG cross-linked with TG were characterized. Gelatin yields from the extraction ranged from 18.2% to 23.3%. SDS-PAGE exhibited dark bands at 120 and 250 kDa, indicating successful TG-mediated cross-linking. The color of CSG film was not affected by TG cross-linking. The tensile strength of CSG films cross-linked with TG decreased from 42.59 to 21.73 MPa and the percent elongation increased from 42.92% to 76.96% as reaction times increased from 0 to 40 min. There was no significant difference in water vapor permeability of CSG films.

A new nano-ZnO/perlite as an efficient catalyst for catalytic ozonation of azo dye

  • Shokrollahzadeh, Soheila;Abassi, Masoud;Ranjbar, Maryam
    • Environmental Engineering Research
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    • v.24 no.3
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    • pp.513-520
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    • 2019
  • In this investigation, nano ZnO was sonochemically synthesized by a novel method using a methionine precursor. A narrow size distribution (41-50 nm) of nano ZnO was achieved that was immobilized on perlite and applied as a catalyst in catalytic ozonation. The catalyst was characterized by fourier transform infrared spectroscopy, BET surface area, and field emission scanning electron microscope. The ozonation of recalcitrant Remazol black 5 (RB5) di-azo dye solution by means of the synthesized catalyst was investigated in a bubble column slurry reactor. The influence of pH values (7, 9, 11), catalyst dosage (8, 12, 15, $20g\;L^{-1}$) and reaction time (10, 20, 30, 60 min) was investigated. Although the dye color was completely removed by single ozonation at a higher reaction time, the applied nanocatalyst improved the dye declorination kinetics. Also, the degradation of the hazardous aromatic fraction of the dye was enhanced five-times by catalytic ozonation at a low reaction time (10 min) and a neutral pH. The second-order kinetics was best fitted in terms of both RB5 color and its aromatic fraction removal. The total organic carbon analysis indicated a significant improvement in the mineralization of RB5 by catalytic ozonation using the nano-ZnO/perlite catalyst.

Photocatalytic-Photochemical Reaction of Wastewater Dyes in aqueous Solution (염료폐수 용액의 광축매-광화학 반응)

  • 김삼혁;최칠남;정오진
    • Journal of Environmental Science International
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    • v.8 no.2
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    • pp.241-248
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    • 1999
  • The photocatalytic decolorization and photodegradation of wastewater contamininated with dyes such as methyleneblue tetrahydrate(MBT), methyl orange(MO), phenol red(PR) and the mixed dyes have been studied using a batch reactor in the presence of aerotropic and titania. Degussa P25 titanium oxide was used as the photocatalyst and proved to be effective for the dyes-degradation when irradiated with UV-light source emitting the wavelength of 253.7 nm in the presence of air. In addition to removing the color from the wastewater, the photocatalytic reaction simultaneously reduced the COD and optical density which suggests that the dissolved organic compounds have been photooxidized. The reaction rate of disappearance of the dyes were measured as a function of the irradiation times. The photooxidative procedure of the aquatic solution have the first order reaction-kinetics. The rate constants were increased in the order of PR < MBT < $gL^{-1}-TiO_2$ powder were irradiated with the UV -light source.

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Color Evaluation of Red GinBeng Extract and its Charges during teat treatment (열처리가 홍삼엑기스의 색상변화에 미치는 영향)

  • 최진호;김우정;박길동;성현순
    • Journal of Ginseng Research
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    • v.4 no.2
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    • pp.165-174
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    • 1980
  • The concentrated red ginseng extract (RGE) which was prepared from water extract of red ginseng tails was investigated for its changes in color intensity, sugar contents and during storage at various temperatures. In order to evaluate the color of RCE, a spectrophotometric measurement in ultraviolet and visible range was applied. The concentrated RGE was divided into three fractions of aqueous, butanol and benzene layers. It was found that : (1) Increase in RCE color during heat treatment was considered to be due to nonezymatic browning reaction. Water soluble layer showed approximately 100 times higher color intensity than those of organic solvent layers (2) The RCE stored at 8$0^{\circ}C$ showed an increase in fructose and glucose content while a rapid decrease was resulted at 10$0^{\circ}C$. (3) A rapid increase in absorbances at 400 and 460nm was shown at 90 and 10$0^{\circ}C$ after an initial induction period and slowed down after 50 hours . (4) A significant relationship was found between decrease in sugar content and increase in color intensity. (5) Absorbance ratio of 400nm/460nm indicated that benzene layer has about two times higher value in violet color than those of butanol and aqueous layers.

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Chemical Precipitation Treatment for the Disperse Dyes Removal (분산성 염료의 제거를 위한 응집처리)

  • 한명호;박종득;허만우
    • Textile Coloration and Finishing
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    • v.14 no.2
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    • pp.40-50
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    • 2002
  • In order to remove the pollutants effectively in the dye wastewater by chemical precipitation process, coagulation arid flocculation test were carried out using several coagulants on various reaction conditions. It was found that the Ferrous sulfate was the most effective coagulant for the removal of disperse dye(B79), and we could get the best result lot the removal of disperse dye(B56) in the aspects of TOC removal efficiency and sludge field. When the Ferrous sulfate dosage was $800mg/\ell$, the sludge settling velocity was very fast>, and the color was effectively removed in the disperse dye(B79) solution. Although the color removal was ineffective when the Alum was used as a coagulant, the sludge field was decreased in comparison with the Ferrous sulfate or the Ferric sulfate was used in the disperse dye(B56) solution. The general color removal effect for the disperse dye(B56 and B79) solutions, the Ferric sulfate was more proper coagulant than the Alum. It was showed that TOC removal was improved 5% and over by the addition of Calcium hydroxide, and $30mg/\ell$ of sludge yield was decreased(B79). When Alum or Ferric sulfate was used as a coagulant, pH condition for most effective color removal was 5 in B56 solution. In case of Ferrous sulfate as a coagulant, most effective pH condition for color removal was 9. When Ferric sulfate or Ferrous sulfate was used as a coagulant, pH condition for most effective color removal was 9 in B79 solution.

Quantitative Analysis for the Effect of Sensory Information on the Motor (감각정보의 차이가 운동에 미치는 영향에 대한 정량적 분석)

  • 홍철운;심해영;박찬희;김남균
    • Journal of Biomedical Engineering Research
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    • v.23 no.2
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    • pp.165-170
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    • 2002
  • The aim of this study was to analyze the effect of different sensory information on the motor function which is resulted from visual stimuli. Particularly, it was focused on the effect of complementary color stimuli on reaction time. Twenty volunteers(10 men & 10 women), between the age of 20 and 25 yearn participated in this experiment. Experiments were carried out in a light & sound-attenuated chamber, and the overall system consisted of a PC. interface card. LEDs. key board switch, and display panel. Although many measurements of sensory-motor integration has been studied the quantitative analysis of sensory-motor integration has not been developed well. Quantitative analyses were performed to investigate the effect of the different sensory information on the arm motor system in the point of view sensory-motor integration. The result showed that the reaction time for visual stimuli of complementary colors was faster than that under same color environments : and, in same color environments and the reaction speed was varied inversely with respect to the magnitude of the light wavelength.