• Bulletin of the Korean Chemical Society
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• v.32 no.12
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• pp.4205-4209
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• 2011

The $Li_2Mn_{0.5}Fe_{0.5}SiO_4$ silicate was prepared by blending of $Li_2MnSiO_4$ and $Li_2FeSiO_4$ precursors with same molar ratio. The one of the silicates of $Li_2FeSiO_4$ is known as high capacitive up to ~330 mAh/g due to 2 mole electron exchange, and the other of $Li_2FeSiO_4$ has identical structure with $Li_2MnSiO_4$ and shows stable cycle with less capacity of ~170 mAh/g. The major drawback of silicate family is low electronic conductivity (3 orders of magnitude lower than $LiFePO_4$). To overcome this disadvantage, carbon composite of the silicate compound was prepared by sucrose mixing with silicate precursors and heat-treated in reducing atmosphere. The crystal structure and physical morphology of $Li_2Mn_{0.5}Fe_{0.5}SiO_4$ was investigated by X-ray diffraction, scanning electron microscopy, and high resolution transmission electron microscopy. The $Li_2Mn_{0.5}Fe_{0.5}SiO_4$/C nanocomposite has a maximum discharge capacity of 200 mAh/g, and 63% of its discharge capacity is retained after the tenth cycles. We have realized that more than 1 mole of electrons are exchanged in $Li_2Mn_{0.5}Fe_{0.5}SiO_4$. We have observed that $Li_2Mn_{0.5}Fe_{0.5}SiO_4$ is unstable structure upon first delithiation with structural collapse. High temperature cell performance result shows high capacity of discharge capacity (244 mAh/g) but it had poor capacity retention (50%) due to the accelerated structural degradation and related reaction.

• The Journal of Engineering Geology
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• v.23 no.4
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• pp.409-425
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• 2013

This study presents a prediction of a time-series of the area inundated by effluent from Heavenly Lake caused by ground behavior prior to a volcanic eruption. A GIS-based hydrological algorithm that considers the multi-flow direction of effluent, the absorption and storage capacity of the ground soil, the storage volume of the basin or the depression terrain, was developed. To analyze the propagation pattern, four hypothetical collapse zones on the cheonji ground were set, considering the topographical characteristics and distributions of volcanic rocks at Mt. Baekdu. The results indicate that at 3 hours after collapse, for both scenarios 1 and 2 (collapses of the entire/southern boundary of cheonji), a flood hazard exists for villages in China, but not for those on the North Korean side of the mountain, due to the topographical characteristics of Mt. Baekdu. It is predicted that villages in both North Korea and China would be significantly damaged by flood inundation at 3 hours elapsed time for both scenarios 3 and 4 (collapses on the southern boundary of cheonji and on the southeastern-peak area).

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 2008.11a
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• pp.479-483
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• 2008

There are no International Standards or Criteria pertaining to fires inside tunnels at the moment, but there are some fire-related regulations in some advanced countries such as Germany and the Netherlands where some fire-related studies have been expedited. Germany has established regulations related to the safety of structures by stipulating Fire Curves of RABT and EBA Tunnels. Also, the Netherlands has established the resistance capacity of structures by stipulating RWS curve so that they can prevent the adjacent area from being damaged due to a tunnel collapse. Hydrocarbon Fire Curve is the standard assessing the behaviour of a structure in a serious fire, by increasing the heating speed and the maximum temperature of ISO 834 Curve, while MHC Fire Curve, which was established in France, realizes more serious fire conditions. In this study, we aimed to develop the basis of full-sized experiments, with which you can assess the fire-resisting capacity against the fire strength of concrete PC panel lining, through the realization of various tunnel fire curves as mentioned above, by developing the heating furnace suitable for the requirements of Fire-Resisting Standards, with which you can assess the fire damage of tunnel concrete lining. We have developed various conditions of the heating furnace and the method to install a thermo couple within the furnace based on EFNARC and KS F2257-1. We have also conducted a calibrating experiment in order to secure its reliability.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.23 no.4
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• pp.387-394
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• 2010

The alternative load path method based on a column removal scenario has been commonly used to protect building structures from being progressively collapsed due to probable blast loading. However, this method yields highly conservative result when the columns still have substantial load resisting capacity after blast. In this study, the behavior of RC columns with rectangular and circular sections under the blast loading was investigated and the remaining capacity of the partially damaged columns was compared. AUTODYN which is a hydrocode for the analysis of the structure on the impact and blast loading was used for this study. The blast loading was verified with the experiment results. The analysis results showed that the circular columns are preferable to the rectangular ones in respect of the blast resistance performance.

• Journal of the Korean GEO-environmental Society
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• v.7 no.1
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• pp.5-18
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• 2006

Stone column or granular compaction pile have been used in widely during the several decades as a technique to reinforce soft cohesive soils and increase bearing capacity, accelerate consolidation settlement of the foundation soil. The bearing capacity of the granular compaction pile is governed mainly by the lateral confining pressure mobilized in the native soft soil to restrain bulging collapse of the granular pile. Therefore, the technique becomes unfeasible in soft, compressible clayey soils that do not provide sufficient lateral confinement. This paper presents the main results of numerical study of granular compaction pile which is partly mixed with lean concrete. 3D finite element analyses are performed with composite reinforced foundations by both granular compaction pile and partly mixed granular compaction pile with lean-mixed concrete. Finally, a regression formula for calculating settlement reduction coefficients is proposed in this study by using numerical analysis results and applicability of the proposed method is identified by a series of parametric study about settlement reduction coefficients.

• Journal of Korean Society of Steel Construction
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• v.21 no.5
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• pp.461-470
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• 2009

A column resisting axial load and seismic load is one of the main members in a structural system. The heated column by event of a fire can lose its strength and it may damage its structural system or cause the collapse of the entire structural system. In this study, the fire resistance capacity of internally confined hollow concrete filled tube (ICH CFT) column was investigated. In an ICH CFT column, the yield strength of the external tube is important as a concrete filled tube (CFT) column because the external tube confines the filled concrete and the strength of the column depends on the confined effect. A study was performed by finite element analyses considering the confined effect and material nonlinearity as the temperature changes by the fire. The hollow ratio, the thickness of the external tube, and the strength of concrete were selected as the parameters for the analyses. The analyses were performed by using a commercial FEA program (ABAQUS) and nonlinear concrete model program. The analysis results showed that the hollow ratio and the strength of concrete mainly affect the fire resisting capacity of an ICH CFT column.

• Computers and Concrete
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• v.12 no.2
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• pp.211-228
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• 2013

The structure analyzed in this paper has particular building style and special structural system. It is a rigid-connected twin-tower skyscraper with asymmetrical distribution of stiffness and masses in two towers. Because of the different stiffness between the north and the south towers, the torsion seismic vibration is significant. In this paper, in order to study the seismic response of the structure under both frequent low-intensity earthquakes as well as rare earthquakes at the levels of intensity 7, the analysis model is built and analyzed with NosaCAD. NosaCAD is an nonlinear structure analysis software based on second-development of AutoCAD with ObjectARX. It has convenient modeling function, high computational efficiency and diversity post-processing functions. The deformations, forces and damages of the structure are investigated based on the analysis. According to the analysis, there is no damage on the structure under frequent earthquakes, and the structure has sufficient capacity and ductility to resist rare earthquakes. Therefore the structure can reach the goal of no damage under frequent earthquakes and no collapse under rare earthquakes. The deformation of the structure is below the limit in Chinese code. The time sequence and distribution of damages on tubes are reasonable, which can dissipate some dynamic energy. At last, according to forces, load-carrying capacity and damage of elements, there are some suggestions on increasing the reinforcement in the core tube at base and in stiffened stories.

• Structural Engineering and Mechanics
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• v.72 no.5
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• pp.631-642
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• 2019

The objective of the present study is to examine the flexural behavior of two-span post-tensioned lightweight aggregate concrete (LWAC) beams using unbonded tendons and the reliability of the design provisions of ACI 318-14 for such beams. The parameters investigated were the effective prestress and loading type, including the symmetrical top one-point, two third-point, and analogous uniform loading systems. The unbonded prestressing three-wire strands were arranged with a harped profile of variable eccentricity. The total length of the beam, measured between both strand anchorages, was 11000 mm. The test results were compared with those compiled from simply supported LWAC one-way members, wherever possible. The ultimate load capacity of the present beam specimens was evaluated by the collapse mechanism of the plasticity theorem and the nominal section moment strength calculated following the provision of the ACI 318-14. The test results showed that the two-span post-tensioned LWAC beams had lower stress increase (Δf_ps) in the unbonded tendons than the simply supported LWAC beams with a similar reinforcement index. The effect of the loading type on Δf_ps and displacement ductility was less significant for two-span beams than for the comparable simply supported beams. The design equations for Δf_ps and Δf_ps proposed by ACI 318-14 and Harajli are conservative for the present two-span post-tensioned LWAC beams, although the safety decreases for the two-span beam, compared to the ratios between experiments and predictions obtained from simply supported beams.

• Journal of the Korea Concrete Institute
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• v.18 no.6 s.96
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• pp.729-736
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• 2006

It has been shown that many Reinforced Concrete(RC) structures designed without seismic details have experienced brittle shear failures in the beam-column joint area and resulted in large permanent deformations and structural collapse. In this study, experimental investigations into the performance of exterior reinforced concrete beam-column joints strengthened with the carbon fiber-reinforced polymer(CFRP) under cyclic loading were presented. The CFRP has been applied by choosing different combinations and locations to determine the effective way to improve structural performances of joints. Eight beam-column joints were tested to investigate behaviors of each specimen under cyclic load and to compare performances of seismic retrofit. According to the experimental study, the retrofit strengthened with the CFRP provides significant improvements of flexural capacity and ductility of beam-column joints originally built without seismic details.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.24 no.11
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• pp.2866-2874
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• 2000

This paper is concerned with the optimum design for external reinforcement of a nuclear reactor pressure vessel(RPV) in a severe accident. During the severe reactor accident of molten core, the temperature and the pressure in the nuclear reactor rise to a certain level depending on the initial and subsequent condition of a severs accident. The reis of the temperature and the internal pressure cause deterioration of the load carrying capacity and could cause failure of the RPV lower head. The deterioration of failure can be mitigated by the external cooling or the reinforcement of the lower head with additional structures. While the external cooling forces the temperature of an RPV to drop to the desired level, the reinforcement of the lower head can attain both the increase of the load carrying capacity and the temperature drop. The reinforcement of the lower head can be optimized to have the maximum effect on the collapse pressure and the temperature at the inner wall. Optimization results are compared to both the result without the reinforcement and the result with the designated reinforcement.