• 한국연소학회지
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• 제1권2호
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• pp.9-20
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• 1996

We construct a mobile broadband coherent anti-Stokes Raman spectroscopy system to measure the temperature of combustion gases. To improve the accuracy of CARS temperatures due to Stokes lasers, a modeless dye laser is constructed. A monochromator to disperse CARS spectra is also constructed in the spectrometer for easy portability. The accuracy of CARS temperature, measured in graphite tube furnace in reference to a radiation pyrometer, is better than 2 % from 1000 K to 2400 K. The CARS temperature error due to the variation of the spectral distribution of the modeless laser is measured to be less than 1.5 % during five hours operation. As a demonstration of combustion diagnosis, we applied the spectrometer to measure the temperature distribution of the propane air premixed flame.

• Molecules and Cells
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• 제26권6호
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• pp.530-535
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• 2008

Optical signals based on Raman scattering, coherent anti-Stokes Raman scattering (CARS), and harmonic generation can be used to image biological molecules in living cells without labeling. Both Raman scattering and CARS signals can be used to detect frequencies of molecular vibrations and to obtain the molecular distributions in samples. Second-harmonic optical signals can also be generated in structured arrays of noncentrosymmetric molecules and can be used to detect structured aggregates of proteins, such as, collagen, myosin and tubulin. Since labeling techniques using chemical and biological reactions may cause undesirable changes in the sample, label-free molecular imaging techniques are essential for observation of living samples.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2000년도 제21회 KOSCO SYMPOSIUM 논문집
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• pp.160-167
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• 2000

We investigated a uniform temperature zone, produced by double flame structure of a coflow CH4/air partially premixed flame, to be used as a temperature calibration source for laser diagnostics. A broadband N2 CARS(coherent anti-Stokes Raman spectroscopy) system with a modeless laser was used for temperature measurement. When the stoichiometric ratio was 1.5, we found the uniform temperature zone in radial direction of the flame of which the averaged temperature was 2110 K with standard deviation 24 K. In the stoichiometric ratio range between 2.0 and 2.5, we found very stable temperature-varying zones in vertical direction at the center of the flame. The size of the zone was approximately 15 mm and it covered a temperature range from 300 K to 1900 K. We also suggest that this zone can be used as a calibration source for 2-D PLIF(planar laser induced flurescence) temperature measurement.

• 한국광학회지
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• 제3권4호
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• pp.266-272
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• 1992

화염내부의 온도분포를 측정하기 위하여 코헤런트 라만분광 기술을 연구하였다. 측정의 공간분해능을 높이기 위하여 상자형 위상정합 방법을 사용하여 CARS 신호를 측정하였다. 측정된 CARS신호를 이용하여 화염의 온도를 계산하는 프로그램을 연구하였다. 섭동이론을 이용하여 에너지 간격법칙으로 기술되는 질소 분자의 라만 Q-가지 분광선의 선폭확대 효과를 온도계산 프로그램에 삽입하였다. 에너지 간격법칙을 이용하여 계산된 화염내부의 온도 분포가 열전대로 측정된 오도와 계산에 의해 구해진 단열 화염 온도와 적절히 일치함을 확인하였다.

• 대한기계학회논문집B
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• 제20권10호
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• pp.3355-3360
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• 1996

To provide standard data of temperature and species concentration in a flame for calibrating the laser based combustion diagnostics, we investigated combustion characteristics of a flat flame burner(Mckennar Product). For various stoichiometric ratios we measured temperature and concentration of OH in the premixed methane/air flame with Coherent anti-Stokes Raman spectroscopy and laser induced fluorescence technique, respectively. Assuming the chemical equilibrium condition at the measured temperature, the mole fraction of the OH radical in the flame was obtained and compared with numerical analysis.

• Journal of Mechanical Science and Technology
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• 제19권6호
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• pp.1366-1377
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• 2005

Experimental study was carried out in an atmospheric pressure, laboratory-scale dump combustor showing features of combustion instabilities. Flame structure and heat release rates were obtained from OH emission spectroscopy. Qualitative comparisons were made between line-integrated OH chemiluminescence image and Abel-transformed one. Local Rayleigh index distributions were also examined. Mean temperature, normalized standard deviation and temperature fluctuations were measured by coherent anti-Stokes Raman spectroscopy (CARS). To see the periodic behavior of oscillating flames, phase-resolved measurements were performed with respect to the pressure wave in the combustor. Results on system damping and driving characteristics were provided as a function of equivalence ratio. It also could be observed that phase resolved temperatures have been changed in a well-defined manner, while its difference between maximum and minimum reached up to 280K. These results would be expected to play an important role in better understanding of driving mechanisms and thermo-acoustic interactions.

• 대한기계학회논문집B
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• 제24권11호
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• pp.1464-1469
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• 2000

The effects of SiCl$_4$addition on flame structures have been studied in flame hydrolysis deposition (FHD) processes using Coherent anti-Stokes Raman spectroscopy (CARS) and planar laser induced fluorescence (PLIF) to measure temperatures and OH concentrations, respectively. The results demonstrate that even a small amount of SiCl$_4$ addition can change thermal and chemical structures of H$_2$/O$_2$ diffusion flames. When SiCl$_4$ is added to a flame temperature decreases in non-reacting zone due to the increases in both specific heat and density of the gas mixture, while flame temperature increase in particle formation zone due to the heat release through hydrolysis and oxidation reactions of SiCl$_4$. It is also found that OH concentration decreases dramatically in particle formation zone where temperatures increase. This can be attributed to consumption of oxidative species and generation of HCl during silica formation.

• 한국연소학회지
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• 제5권1호
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• pp.91-98
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• 2000

We investigated a uniform temperature zone, produced by double flame structure of a co flow CH4/air partially premixed flame, to be used as a temperature calibration source for laser diagnostics. A broadband N2 CARS(coherent anti-Stokes Raman spectroscopy) system with a modeless laser was used for temperature measurement. When the stoichiometric ratio was 1.5, we found the uniform temperature zone in radial direction of the flame of which the averaged temperature was 2110 K with standard deviation 24 K. In the stoichiometric ratio range between 2.0 and 2.5, we found very stable temperature-varying zones in vertical direction at the center of the flame. The size of the zone was approximately 15 mm and it covered a temperature range from 300 K to 1900 K. We also suggest that this zone can be used as a calibration source for 2-D PLIF(planar laser induced flurescence) temperature measurement.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2014년도 제49회 KOSCO SYMPOSIUM 초록집
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• pp.357-358
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• 2014

Coherent anti-Stokes Raman spectroscopy is one of the best tools to measure temperature distributions in the flame. Since it does not disturb the flow field, it could be used to study anchoring mechanism especially in the lifted flame. However, the length of probe volume is, normally, much greater than flame thickness. This weak point was overcome with lens combination in this study. It was found out that no peculiar temperature changes was happened near tribrachial point and heat transfer to the upstream was minimal near the flame anchoring position.

• 한국광학회:학술대회논문집
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• 한국광학회 2002년도 하계학술발표회
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• pp.222-223
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• 2002

3차 비선형 광학현상을 이용한 레이저 분광학은 코헤런트 반스톡스 라만산란(Coherent Anti-Stokes Raman Scattering, CARS)이나 축퇴 사광자혼합(Degenerate Four-Wave Mixing, DFWM)이 기계공학의 연소진단이나 화학분야에 응용된 이래 활발히 연구되어져왔다.[1] 비선형 광학현상의 특성상, 발생한 신호는 입사 레이저광들과의 위상정합조건이 만족되는 특정한 방향으로만 진행하고 레이저광처럼 가간섭성을 갖는다. (중략)