• Korean Chemical Engineering Research
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• v.56 no.3
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• pp.327-334
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• 2018

Water-repellent coating solutions were prepared by sol-gel method using tetraethoxysilane (TEOS) and methyltrimethoxysilane (MTMS) as precursors. The solutions were spin-coated on a cold-rolled steel sheet and thermally cured to prepare a non-fluorine water-repellent coating films. The effects of molar ratios of MTMS/TEOS, water concentration and ammonia concentration on the hydrophobic properties of the coating films were studied. The contact angle of water on coating films prepared by varying the molar ratio of MTMS/TEOS to 1~20 showed a maximum value of $108^{\circ}$ when the MTMS/TEOS molar ratio was 10. With increasing water content, the coating films showed the larger contact angles and the better the water repellency. As the amount of ammonia added was increased, the contact angles of coating films were increased, showing the better the water repellency. It is considered that the larger the amount of ammonia added, the larger the size of the silica particles generated, which increases the surface roughness of the silica particles, thereby increasing the water repellency.

• Kyungpook Mathematical Journal
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• v.57 no.4
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• pp.651-665
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• 2017

Some computational fluid dynamics problems concerning the thin films flow of viscous fluid with a free surface and draining or coating fluid-flow problems can be delineated by third-order ordinary differential equations. In this paper, the aim is to introduce the numerical solutions of the boundary value problems of such equations by variational iteration method. In this paper, it is shown that the third-order boundary value problems can be written as a system of integral equations, which can be solved by using the variational iteration method. These solutions are gleaned in terms of convergent series. Numerical examples are given to depict the method and their convergence.

• Korean Chemical Engineering Research
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• v.55 no.6
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• pp.830-836
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• 2017

Hydrophilic coating solutions were prepared by reacting a silane coupling agent, GPTMS (3-glycidoxypropyl trimethoxysilane) with colloidal silica. Hydrophilic coating films were also obtained by depositing the hydrophilic coating solutions on polycarbonate substrates by spin-coating and subsequently by thermal curing at $120^{\circ}C$. During this process, the effect of average particle sizes of colloidal silica was studied on the properties of coating films. As a result, coating film, prepared from colloidal silica with average particle size of 25 nm, showed a low contact angle of $20^{\circ}$ and a good pencil hardness of H. On the other hand, coating films, prepared from colloidal silica with average particle sizes of 15 nm and 45 nm, exhibited high contact angles of $27^{\circ}$ and $36^{\circ}$ and pencil hardness of H and B, respectively.

• Korean Chemical Engineering Research
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• v.55 no.2
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• pp.247-252
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• 2017

Hydrophilic coating solutions were prepared by reacting a silane coupling agent, aminosilane with colloidal silica (15~20 nm in diameter). Hydrophilic coating films were also obtained by depositing the hydrophilic coating solutions on polycarbonate substrates by dip-coating and subsequently by thermal curing at $120^{\circ}C$. During this process, the effect of types of aminosilane was studied on the properties of coating films. As a result, coating films, prepared with 3-aminopropyltriethoxysilane (APTES) as aminosilane, showed contact angles of $25{\sim}44^{\circ}$ and a poor pencil hardness of B. On the other hand, coating films, prepared with 3-aminopropyltrimethoxysilane (APTMS) as aminosilane, exhibited contact angles of $26{\sim}37^{\circ}$ and a good pencil hardness of 2H.

• Journal of the Korean Ceramic Society
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• v.30 no.11
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• pp.897-904
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• 1993

CdS doped SiO2 glass coating films which are good candidates for the nonlinear optical materials were prepared by the Sol-Gel method. TEOS, C2H5OH, H2O and HCl were used as starting materials to obtain SiO2 matrix solutions. Then Cd(NO3)2.2H2O and CS(NH2)2 were dissolved into the SiO2 matrix solutions. Coating was performed several times in order to increase the thickness of coated film by the dip-coating method. Then heat treatments were carried out to control the size of CdS microcrystals doped in SiO2 glass matrix with respect to temperatures and times. CdS-doped SiO2 transparent coating films were successfully obtained. CdS crystals were changed from cubic to hexagonal type about $600^{\circ}C$.

• Korean Chemical Engineering Research
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• v.57 no.1
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• pp.124-132
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• 2019

Water-repellent coating solutions were synthesized by hydrolysis and polycondensation reactions with water using tetraethoxysilane (TEOS) and chlorotrimethylsilane (CTMS) as precursors. The solutions were coated on a PMMA sheet and thermally cured to prepare non-fluorinated water-repellent coating films. Coating films were characterized by water contact angles, UV-Vis transmittance and surface morphology. The contact angle of coating films prepared by varying the molar ratio of CTMS/TEOS to 0.6~1.0 exhibited a maximum value of $107^{\circ}$ when the CTMS/TEOS molar ratio was 0.8. The coating films showed a high transmittance over the visible range up to 90% when the CTMS/TEOS molar ratios were 0.6~0.8. However, when the molar ratios of CTMS/TEOS were 0.9~1.0, the transmittance of coating films was lower than 70% due to an uneven shape of the rough surface.

• Korean Chemical Engineering Research
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• v.46 no.2
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• pp.274-278
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• 2008

Hard coating solutions were prepared from glycidoxypropyl trimethoxysilane (GPTMS) and methacryloxypropyl trimethoxysilane (MPTMS) precursors with different molar ratios of 10:0, 9:1, 7:3, 5:5, 3:7, and 0:10, respectively, by the sol-gel method. The polycarbonate (PC) sheets were spin-coated, and cured at $130^{\circ}C$ for 3 h. The effect of the GPTMS:MPTMS molar ratios of the mixture was investigated on the properties of coating films. The highest pencil hardness and adhesion to PC sheets of coating films were found for solution with GPTMS:MPTMS molar ratio of 5:5. Also, the pencil hardness of coating films was increased with increasing the $H_2O$ content in the coating solutions.

• Korean Chemical Engineering Research
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• v.51 no.1
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• pp.73-79
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• 2013

Waterborne polyurethane dispersion (WPUD) was synthesized from polycarbonate diol (PCD), isophorone diisocyanate (IPDI) and dimethylol propionic acid (DMPA) as starting materials. Then, waterborne acrylic polyurethane dispersion (AUD) was synthesized by reacting the WPUD with an acrylate monomer, methyl methacrylate (MMA). Subsequently, the AUD was mixed with multi-walled carbon nanotube (MWCNT) to yield a conductive coating solution, and the mixture was coated on the polycarbonate substrate. With increasing the amount of MMA in the AUD, the pencil hardness, abrasion resistance and chemical resistance of the coating films were improved, but the electrical conductivity of the coating films was decreased. On the other hand, the pencil hardness, abrasion resistance and chemical resistance of coating films were decreased, but the electrical conductivity was enhanced with increasing the amount of MWCNT in the conductive coating solutions.

• Korean Chemical Engineering Research
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• v.50 no.3
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• pp.427-434
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• 2012

Waterborne polyurethane dispersions (PUD) were synthesized from poly (carbonate diol), isophrone diisocyanate and dimethylol propionic acid at different NCO/OH molar ratios. Subsequently, the PUD was mixed with different types of alkali metal salts ($LiClO_4$, $NaClO_4$, and $KClO_4$) to prepare antistatic waterborne polyurethane coating solutions. Effects of the types and amounts of alkali metal salts were investigated on the surface resistances of the resulting coating films. The surface resistances of coating films were decreased with increasing the amounts of alkali metal salts added in the PUD. The coating films prepared with the same amount of alkali metal salts showed increased ionic conductivity with the order of $LiClO_4$ > $NaClO_4$ > $KClO_4$. Also, the surface resistances of coating films were increased with increasing the molar ratios of NCO/OH in the PUD.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.9 no.1
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• pp.55-59
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• 1999

The Rapid Expansion of Supercritical fluid Solutions (RESS) process was applied to particles coating. Microcapsules prepared by spray drying were used as the core particles, and two kinds of paraffin were used as the coating materials. Supercritical $CO_{2}$ solutions of paraffin were expanded through the short nozzle into the bed that was fluidized by air. Extraction temperature and pressure were varied at $50~120^{\circ}C$, $150~200\;kg/\textrm{cm}^2$, respectively. The thickness of theoritical coating layer ws measured, and precipitate coating layer on surface was analyzed by using SEM, FT-IR. The release behaviors of $Mg^{2+}$ ions were inspected by atomic absorbance spectrophtometer.