• Title/Summary/Keyword: coating properties

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Fabrication and characterization of perovskite CH3NH3Pb1-xSbxI3-3xBr3x photovoltaic devices

  • Yamanouchi, Jun;Oku, Takeo;Ohishi, Yuya;Fukaya, Misaki;Ueoka, Naoki;Tanaka, Hiroki;Suzuki, Atsushi
    • Advances in materials Research
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    • v.7 no.1
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    • pp.73-81
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    • 2018
  • $TiO_2/CH_3NH_3Pb_{1-x}Sb_xI_{3-3x}Br_{3x}-based$ photovoltaic devices were fabricated by a spin-coating method using mixture solutions with $SbBr_3$. Effects of $SbBr3$, CsI or RbBr addition to $CH_3NH_3PbI_3$ precursor solutions on the photovoltaic properties where investigated. The short-circuit current densities and photoconversion efficiencies were improved by adding a small amount of $SbBr_3$, CsI or RbBr to the perovskite phase, which would be due to the doping effect of Sb, Br and Cs/Rb atom at the Pb, I and $CH_3NH3$ sites, respectively.

Design and Analysis for Loss Reduction of High-Speed Permanent Magnet Motor using a Soft Magnetic Composite

  • Lee, Sung-Ho;Kim, Yong-Jae;Lee, Kyu-Seok;Kim, Sung-Jin
    • Journal of Magnetics
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    • v.20 no.4
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    • pp.444-449
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    • 2015
  • Soft magnetic composites (SMCs) are especially suitable for the construction of low-cost, high-performance motors with 3-D magnetic fields. The main advantages of SMCs is that the iron particles are insulated by the surface coating and adhesive used for composite bonding, the eddy-current loss is much lower than that in laminated steels, especially at higher frequencies, and the hysteresis loss becomes the dominant component of core losses. These properties enable machines to operate at higher frequencies, resulting in reduced machine size and weight. In this paper, 3-D topologies are proposed that enable the application of SMCs to effectively reduce losses in high-speed permanent magnet (PM) motors. In addition, the electromagnetic field characteristics of the motor topologies are evaluated and compared using a non-linear finite element method (FEM) based on 3-D numerical analysis, and the feasibility of the motor designs is validated.

Preparation and Properties of UV Curable Urethane Acrylates for Ink Binder (Ink Binder용 UV 경화형 조성물의 제조 및 특성)

  • Park, Hyun-Ju;Han, Chang-Duk;Oh, Sang-Taek
    • Journal of Adhesion and Interface
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    • v.14 no.4
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    • pp.167-174
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    • 2013
  • In this study, Ultraviolet (UV) curable urethane acrylates for ink binder was prepared by reaction of IPDI, polyether polyol and HEA. The UV curing behavior of compositions with HEA/PETA ratio on UV irradiation time was investigated by FT-IR spectrophotometer, probe tack tester and Photo-DSC. Conversion % and gel content were increased with increasing UV irradiation time, but probe tack was decreased. Storage modulus, tensile strength and decomposition temperature were increased as PETA content increased. In case of HEA/PETA ratio was 30/70, adhesion property of UV-cured composition on PMMA sheet was excellent.

Physicochemical Characterization of PET Fabrics Treated with Chitosan after Exposure to $O_2$ Low Temperature Plasma - Especially by KES evaluation - (저온 플라즈마 처리한 폴리에스테르 직물의 키토산 처리에 따른 물리화학적 특성변화 -KES평가를 중심으로-)

  • Koo Kang;Kim Sam Soo;Park Young Mi;Yu Jae Yeong;Koo Bon Shik;Yoo Seung Chun
    • Textile Coloration and Finishing
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    • v.17 no.5 s.84
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    • pp.26-36
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    • 2005
  • This study was carried to evaluate mechanical characteristics of Poly(ethylene terephthalate) fabrics (by Kawabata evaluation system(KES)) which was systematically treated with $O_2$ low temperature plasma and chitosan acetate solution. Furthermore, surface structure was investigated by SEM, AFM, air permeability and wettability. Tensile energy(WT), shear rigidity(G) and surface roughness(MIU) properties calculated by KES-FB have increased with increasing plasma treatment time, while bending rigidity(G) and energy of compression(WC) value were decreased compared with those of the untreated. SEM photographs showed the identification of chitosan coating but did not confirm the plasma etching structure. Air permeability was decreased according to plasma treatment time with increasing concentrations of chitosan. The water absorption rate made rapid progress by chitosan treatment.

Characterizations of Ti-Al-V-N Films Deposited by DC and RF Reactive Magnetron Sputtering (직류 및 고주파 마그네트론 스퍼터링법으로 증착한 Ti-Al-V-N 박막의 특성)

  • Sohn, Yong-Un;Chung, In-Wha;Lee, Young-Ki
    • Journal of the Korean Society for Heat Treatment
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    • v.13 no.6
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    • pp.398-404
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    • 2000
  • The Ti-Al-V-N films have been deposited on various substrates by d.c and r.f reactive magnetron sputtering from a Ti-6Al-4V alloy target in mixed $Ar-N_2$ discharges. The films were investigated by means of XRD, AES, SEM/EDX, microhardness, TG and scratch test. The XRD and SEM results indicated that the films were of single B1 NaCl phase having dense columnar structure with the (111) preferred orientation. The composition of Ti-Al-V-N film was the Ti-7.1Al-4.3V-N(wt%) films. Adhesion and microhardness of Ti-Al-V-N films deposited by r.f magnetron sputtering method were better than those deposited by d.c magnetron sputtering method. The anti-oxidation properties of Ti-Al-V-N films were also superior to that of Ti-N film deposited by the same deposition conditions.

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The Effect of Oxide Layer Thickness to the Scale Defects Generation during Hot finish Rolling (열연사상 압연시 스케일 결함발생에 미치는 산화피막 두께의 영향)

  • 민경준
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 1999.08a
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    • pp.412-422
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    • 1999
  • Scale defects generated on the strip surface in a tandem finishing mill line are collected from the strip trapped among the production mills by freezing the growing scale on the strip by the melt glass coating and shutting down the line simultaneously. The samples observed of its cross sectional figure showed the process of scale defect formation where the defects are formed at the base metal surface by thicker oxidized scale during each rolling passes. The properties of the oxidized layer growth both at rolling and inter-rolling are detected down sized rolling test simulating carefully the rolling condition of the production line. The thickness of the oxidized layer at each rolling pass are simulated numerically. The critical scale thickness to avoid the defect formation is determined through the expression of mutual relation between oxidized layer thickness and the lanks of the strip called quality for the scale defects. The scale growth of scale less than the critical thickness and also to keep the bulk temperature tuning the water flow rate and cooling time appropriately. Two units of Inerstand Cooler are designed and settled among the first three stands in the production line. Two units of scale defect is counted from the recoiled strip and the results showed distinct decrease of the defects comparing to the conventionaly rolled products.

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Electromagnetic Interference Shielding Properties of CO2 Activated Carbon Black Filled Polymer Coating Materials

  • Hu, Quanli;Kim, Myung-Soo
    • Carbon letters
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    • v.9 no.4
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    • pp.298-302
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    • 2008
  • Carbon blacks could be used as the filler for the electromagnetic interference (EMI) shielding. The poly vinyl alcohol (PVA) and polyvinylidene fluoride (PVDF) were used as the matrix for the carbon black fillers. Porous carbon blacks were prepared by $CO_2$ activation. The activation was performed by treating the carbon blacks in $CO_2$ to different degrees of burnoff. During the activation, the enlargement of pore diameters, and development of microporous and mesoporous structures were introduced in the carbon blacks, resulting in an increase of extremely large specific surface areas. The porosity of carbon blacks was an increasing function of the degree of burn-off. The surface area increased from $80\;m^2/g$ to $1142\;m^2/g$ and the total pore volume increased from $0.14073\;cc{\cdot}g^{-1}$ to $0.9343\;cc{\cdot}g^{-1}$. Also, the C=O functional group characterized by aldehydes, ketones, carboxylic acids and esters was enhanced during the activation process. The EMI shielding effectiveness (SE) of raw N330 carbon blacks filled with PVA was about 1 dB and those of the activated carbon blacks increased to the values between 6 and 9 dB. The EMI SE of raw N330 carbon blacks filled with PVDF was about 7 dB and the EMI SE increased to the range from 11 to 15 dB by the activation.

Photovoltaic Properties of Organic Photovoltaic cell (유기물을 이용한 Photovoltaic cell의 광기전력 특성)

  • Kim, S.K.;Lee, H.D.;Chung, D.H.;Oh, H.S.;Hong, J.I.;Park, J.W.;Kim, T.W.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.04a
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    • pp.123-126
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    • 2003
  • Recently, there is a growing concern on the photovoltaic effects using organic materials. This is a phenomena which converts the solar energy into the electrical one. We have fabricated a device structure of $ITO/PEDOT:PSS/CuPc/C_{60}/BCP/AI$. The PEDOT:PSS layer is made by spin coating, and the other organic layers are made by thermal vapor deposition. By measuring the current-voltage characteristics with an illumination of light, we have obtained value of Voc=0.38V, Jsc=$0.5mA/cm^{2}$. And a fill factor and efficiency are about 0.314 and 0.083%, respectively. A 500W xenon lamp(ORIEL) is used for a light source, and the light intensity illuminated into the device was about 10mW.

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StructuralElectrtonic Properies of $Pb(Zr_{x}Ti_{1-x})O_3$ Heterolayerd Thick Films with Variation of Sintering Temperature (소결온도에 따른 $Pb(Zr_{x}Ti_{1-x})O_3$ 이종층 후막의 구조적.전기적 특성)

  • Lee, Sung-Gap;Lee, Young-Hie;Nam, Sung-Pil;Bae, Sun-Gi
    • Proceedings of the KIEE Conference
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    • 2005.11a
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    • pp.71-73
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    • 2005
  • Ferroelectric PZT heterolayered thick films were fabricated by the alkoxide-based sol-gel method. PZT(20/80) and PZT(80/20) paste were made and alternately screen-printed on the alumina substrates. The coating and drying procedure was repeated 4 times to form the heterolayered thick films. The thickness of the PZT heterolayered thick films was approximately 60 mm. All PZT thick films showed the typical XRD patterns of a perovskite polycrystalline structure. The relative dielectric constant and the dielectric loss of the PZT thick films sintered at $1050^{\circ}C$ were 1382 and 1.90%, respectively. The remanent polarization and coercive field of the PZT thick films sintered at $1050^{\circ}C$ were $14.15{\mu}C/cm^2$ and 19.13kV/cm, respectively.

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Surface Adhesion and Strength Properties of PAI-Nano CS Hybrid Insulation Coating (PAI-Nano CS 하이브리드 절연코팅의 표면접착 및 강도특성)

  • Han, Se-Won;Kim, Suk-Jun;Jang, He-Mi;Kang, Dong-Pil;Lee, Jong-Ho
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.04b
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    • pp.59-60
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    • 2009
  • PAI-CS 나노하이브리드 절연코팅의 표면접착과 기계적 강도 및 내아크 내구성에 대하여 실험 분석하였다. 졸-겔법으로 PAI의 강화입자로 선택한 나노 CS는 메트릭스 수지와의 상안정성이 잘 이루어졌다. 나노경도를 측정한 결과 순수 PAI수지와 비교하여 CS첨가량이 증가함에 따라 경도와 탄성율 그리고 강성이 개선되고 있다. 한편 실란처리 방법에 따라 경 도와 탄성율의 개선폭이 달라지는 경향이 있어 제조시 적절한 실란처리에 의한 표면제어가 필요한 것으로 나타났다. 전기적 표면 내아크시험에서 순수 수지와 비교하여 우수한 내구성을 가지고 있어서 이는 서지와 부분방전 등에 노출되는 전력용 절연 코팅으로 사용이 기대된다.

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