• KSBB Journal
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• 제9권3호
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• pp.287-293
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• 1994

황화수소 산화반응에 이용할 수 있는 균주를 전남 화순 근교의 폐탄광수에서 분리하였다. 분리균주는 형태적, 생리학적 빛 화학합성 특정에 기준으로 보 면 Thiobacillus sp. IW.로 동정되어진다. 분리된 균주의 최적 배양온도는 $30^{\circ}C$였고, 최적 pH는 7이며, pH 3~pH 9 사이의 넓은 성장범위를 가지고 있었다. 액상배지에 축적된 sulfate 농도가 배지의 pH를 감소시켜 결국 균의 성장을 억제하는 작용을 하였다. 최대 비증식속도인$\mu_{max}=0.78^{-1}$이었고, 세대시 간은 0.9시간으로 나타났다. 분리균주는 질소원으로 potassium nitrate나 glutamic acid를 이용하였으나, urea나 ammonium chloride는 이용하지 못하였다. 기본배지에 첨가된 malate는 전혀 이용하지 못 하였고, Sodium thiosulfate를 에너지원으로 이용하 면 균체량은 $6.25mg/\ell.h$였으며, 대수성장기는 18 시간으로 나타났다. 이의 결과로 미루어 보아 분리 균주는 황화수소 등의 악취 제거에 유용한 균주로 사료되어 진다.

• 자원리싸이클링
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• 제28권6호
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• pp.64-72
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• 2019

플라이애시는 발전소의 탄종 및 품질에 따라 화학조성이 다르고 품질 변화가 크며 탄소함량과 입경에 따라 분류하며, 폐유리분말은 파유리를 분쇄하여 제조하고 분쇄정도에 따라 분류한다. 건축물의 외단열 공법은 경제적이면서 단열성능이 우수한 폴리스티렌 폼 단열재를 활용한 공법이 일반적이다. 하지만 유기계 단열재는 단열성능이 우수하나 화재에 취약하고 다수의 문제점이 지적되었다. 본 연구에서는 플라이애시와 폐유리분말을 사용하여 고온에서 안정한 외단열용 마감모르타르를 제작하고 고온 강도 및 난연 특성을 검토하였다. 실험 결과, 플라이애시와 폐유리분말을 이용한 마감모르타르는 고온에서의 안전성이 높았다. 하지만 강도감소의 폭이 크므로 적절한 배합조건의 선정이 필요하다.

• 환경위생공학
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• 제14권1호
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• pp.42-53
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• 1999

A study on the synthesis of zeolite from coal fly ash from power plant was carried out to reduce environmental problems and reuse industrial waste. The synthesized zeolite was proved to be Zeolite 4A type by means of the XRD and SEM analysis, and then the synthesized zeolite was used as an absorbent to remove the $NH_4^+$ ions in the wastewater and water. In the ion exchange of single $NH_4^+$ ions by the natural zeolite and the synthesized zeolite, the ion exchange reached equilibrium within 10 min. and 1hr, respectively. The amount of ion exchanged $NH_4^+$ to the unit weight of natural zeolite and zeolite 4A were 1.09 and 3.54 meq/g respectively, and the amount of $NH_4$ ion exchanged by the synthesized zeolite was higher than by the natural zeolite. The ion exchange kinetics fitted very well to the Feundlich and Langmuir isotherm. The effects of coexisting cations on the ion-exchange properties of zeolites were studied in order to apply them to water treatment. In the bisolute-system of the $NH_4^+-K^+$ and $NH_4^+-Na^+$ systems, the ion exchange capacity was smaller than the single $NH_4^+$ ion system. The effects of coexisting cations on the ion exchange system by the natural zeolite and the synthesized zeolite were found to be $K^+>Na^+$ and $Na^+>K^+>>Mg^{2+}>Ca^{2+}$, respectively.

• 환경위생공학
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• 제14권3호
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• pp.63-70
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• 1999

A study on the zeolite synthesized of bituminous coal fly ash from power plant has been carried out to reuse industrial waste. The synthesized zeolite was proved to be 4A type by means of the X-ray diffraction analysis and the degree of crystallinity was found to be higher than 90%. Then the synthesized zeolite was used as an adsorbent to remove the heavy metal ions in the CU, Pb, and Cd containing wastewater and water. Also, adsorption characteristics and kinetics of synthesized zeolite in the each metal ion solutions were studied. In each ion solutions, the adsorbed amounts of Pb, Cd, and Cu to the unit weight of synthesized zeolite were 141.6, 118.8, and 131.4mg/g respectively when each metal ion concentration was 500mg/L solution. The adsorption kinetics was fitted well to the Freundlich isotherms. The value of l/n for Pb, Cd, and Cu and 0.27, 0.50, and 0.66, respectively. Those results showed that the synthesized zeolite could be used as an adsorbent to remove single heavy metal ions in the wastewater and water. The heats of adsorption, H values of Pb, Cd, and Cu were 4.87, 14.95, and 18.23kacl/mol by the Henry-van't Hoff equation.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2001년도 총회 및 춘계학술발표회
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• pp.7-10
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• 2001

Adsorption of the pesticides (phosphamidon, fenitrothion, triadimefon and diniconazole) in natural zeolite (CL $I_{N}$) and several synthetic zeolites was incestigated. The pesticides were not adsorbed on zeolites (Na-Pl, SOD, ANA, JBW and CAN) synthesized from Jeju scoria. The distribution coefficient ( $K_{D}$) and the Freundlich constant ( $K_{F}$) decreased in the following sequences. FC $C_{W}$ (waste catalytic cracking catalyst)>FA $U_{F}$ (FAU Synthesized from coal fly ash)>(FAU+Na-Pl)$_{SF}$ (the mixture of FAU and Na-Pl synthesized from the ratio of Jeju scoria 6 to coal fly ash 4 by weight)>CL $I_{N}$ among the zeolites; diniconazole>fenitrothion> triadimefon>phosphamidon. As the temperature was increased, the amount of pesticide adsorbed per unit mass of zeolite increased for FC $C_{W}$, FA $U_{F}$ and (FAU+Na-Pl)$_{SF}$ but it decreased for CL $I_{N}$, for all the pesticides used in this study. It was independent of pH for phosphamidon, fenitrothion and triadimefon, but decresed as pH was increased for all the zeolites used in this study.y.udy.y.y.y.y.y.y.

• Carbon letters
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• 제21권
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• pp.81-85
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• 2017

The objective of this study is the removal of chromium from tannery wastewater by electrosorption on carbon prepared from lignocellulosic natural residue "peach stones' thermally treated. The followed steps for obtaining coal in chronological order were: cleaning, drying, crushing and finally its carbonization at $900^{\circ}C$. The characterization of the carbon material resulted in properties comparable to those of many coals industrially manufactured. The study of the dynamic adsorption of chromium on the obtained material resulted in a low removal rate (33.7%) without applied potential. The application of negative potentials of -0.7 V and -1.4 increases the adsorption of chromium up to 90% and 96% respectively. Whereas a positive potential of +1.4V allows desorption of the contaminant of 138%.

• 한국환경과학회지
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• 제31권12호
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• pp.1103-1115
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• 2022

The adsorption characteristics of four pesticides (phosphamidon, fenitrothion, triadimefon, and diniconazole) on natural clinoptilolite (CLI_N) and three synthetic zeolites were investigated. The synthetic zeolites included faujasite (FAU_F) synthesized from coal fly ash; the mixture of FAU and Na-P1 (FAU + Na-P1)_SF synthesized using Jeju scoria and coal fly ash at the ratio of 1.5 by weight; and waste fluid catalytic cracking catalyst (FCC_W). The distribution coefficient, K_D and the Freundlich constant, K_F decreased in the following sequence: FCC_W > FAU_F > (FAU + Na-P1)_SF > CLI_N among the zeolites and diniconazole>fenitrothion> triadimefon> phosphamidon among the pesticides. The pesticide adsorptivity increased with increasing temperature for FAU_F, (FAU+Na-P1)_SF and FCC_W, however, it decreased for CLI_N, regardless of the type of pesticide. The adsorptivity of pesticides was independent of pH for phosphamidon, fenitrothion and triadimefon, whereas it decreased with increasing pH for diniconazole, regardless of zeolite type.

• 한국대기환경학회지
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• 제32권2호
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• pp.193-207
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• 2016

This study discusses the present status of mercury emission and distribution from major anthropogenic sources in Korea and the future trend of mercury emission by activity changes and application of BATs. Atmospheric mercury emission from major anthropogenic sources based on Annex D of Minamata convention was estimated to around 4.89 tonne in 2012. Emission ratios of cement clinker production, coal-fired power plant, waste incineration and non-ferrous metal smelting were 68.68%, 24.75%, 6.29% and 0.28%, respectively. High mercury emission regions were characterized by the presence of cement clinker production facilities and coal-fired power plants. Prediction of future activities was carried out by linear regression of the previous year data. The (total) mercury emission was estimated to decrease up to 48% Under the scenario of BATs to be applied and the change of future activities. Emissions from coal-fired powerplants and cement clinkers were expected to decrease significantly.

• 한국지반공학회논문집
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• 제26권7호
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• pp.81-91
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• 2010

기존의 최종복토시스템에 대한 문제를 해결하기 위한 단층형 복토시스템의 복토재로서 석탄회(저회)의 활용성을 검토하기 위해서 현장대형토조시험을 수행하였다. 산업부산물의 관련 활용규정에 준하여 석탄회를 일반토사와 혼합하여 현장에서 설치한 대형토조에 채워 넣어 관측기간동안(2007년 7월~2008년 2월) 단층형 복토시스템의 복토재로 서 그 활용성를 일반토사만을 채운 처리구 그리고 일반토사에 건설폐기물을 혼합한 처리구와 함께 비교하였다. 그 결과 일반토사에 석탄회를 적용시킨 처리구가 매립지의 복토재로서 우선시 되는 수분저류능력과 식물의 생육면에서 가장 좋은 결과가 나타났다.

• 환경영향평가
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• 제16권2호
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• pp.143-156
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• 2007

This study has researched the management status and the pollution level of water, soil, stream sediments of 11 abandoned coal mines out of a total of 12 within Obong-Dam area except Bukyung mine, which was submerged when constructing Obong-Dam, and selected areas which are in needs to have pollution control facilities in the first place. From the results of examination on the runoff at the waste rock pile and mineheads, the runoff from Sueun mine (pH, Fe, Al), Samwon mine (pH, Al), Wangdo mine (pH, Al), Mose mine (pH, Fe, Al) and Daeryeong mine (pH) exceeded the permissible discharge standards of the water quality, but the water at merging point with Obong-Dam after joined with Doma branch satisfied both Water Quality Standards and Drinking Water Quality Standards. In regard to groundwater contamination, it is found that areas where exceeded the Drinking Water Quality Standards are Wangdo mine (pH), Jangjae mine (pH, Zn), Daeryeong mine (pH) whereas all areas satisfied Soil Contamination Warning Standards of Soil Environmental Conservation Law. When comparing a research result on underwater sediments of branches of abandoned mines to the EPA Guidelines for classification of great lakes harbor sediments, Dongguk Gaerim (Fe), Jungwon mine (Fe), Daebo mine (Mn), Samwon mine (Mn) and Daeryeong mine (Mn) showed mid-level of contamination, whereas Sueun (Fe, Mn), Daebo mine (Fe), Woosung mine (Fe, Mn), Wangdo mine (Fe, Mn), Mose mine (Fe) and Daeryeong mine (Fe) showed high-level of contamination. In addition, contamination levels of underwater sediments in Wangsan and Doma branch where abandoned mine's branches merge together, Wangsan branch showed no contamination at all whereas Doma branch shows mid-level of contamination which reflect the Doma branch is affected by waste rock pile and minehead runoff of the abandoned mines in the Doma branch area. It is concluded that Mose mine and Sueun mine required treatment of acid mine drainage. and Wangdo, Jungwon, and Samwon mines were in need of mine tailing and erosion control work. The Samwon mine additionally required a control system for closed minehead runoff. Although the Samwon mine reached a high concentration of Al, Mn $Ca^{2+}$, $SO{_4}^{2-}$ in the runoff, the levels decreased after it was combined with a tributary. It has been concluded that after further monitoring of the cause of pollution, a preventive measure system may be needed to be built.