• 제목/요약/키워드: coal slag

검색결과 135건 처리시간 0.023초

가스화 조건에서 슬래그 성분이 크롬계 내화재 미세구조 변화에 미치는 영향 (Effects of Slag Composition on the Microphase Change of a Chromia Refractory under Gasification Conditions)

  • 오명숙;김한봄;박우성
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2007년도 추계학술대회 논문집
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    • pp.441-444
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    • 2007
  • The inside wall of a coal gasifier is lined with refractory, and the corrosion of the refractory by coal sag is an important parameter affecting the refractory lifetime and the replacement period. This paper examines the changes in microstructure of a chromia refractory due to chemical reactions with penetrating slag as a function of slag composition. The effects of CaO and $Fe_2O_3$ concentrations were studied using Datong and KIDECO slag. Static corrosion experiments were carried out, the percent slag penetration and changes in the microstructure were determined by SEM/EDX analyses. FactSage equilibrium calculations were carried out to determine the equilibrium products and the predictions were compared with experimental observations.

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석탄가스화 발전슬래그를 잔골재로 사용한 콘크리트 Mock-up 부재의 공학적 특성 (Engineering Properties of Concrete Mock-up Using Coal Gasification Slag as Fine Aggregate.)

  • 한준희;이영준;현승용;한민철;윤기원;한천구
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2018년도 추계 학술논문 발표대회
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    • pp.159-160
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    • 2018
  • In this study, the characteristics of the Mock-up test were reviewed to analyze the applicability of the coal gasification slag (CGS) from the integrated gasification combination Cycle (IGCC) to the concrete fine aggregate. The analysis shows that CGS and crushed sand mix is the best combination of CGS combined with about 50 % of CGS based on the effects of promoting liquidity and strength. This is expected to be a positive factor in securing the strength and flexibility of concrete given the optimal mix of CGS, and may also contribute to the improvement of quality.

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Mock up test를 통한 석탄가스화 발전슬래그를 잔골재로 사용한 콘크리트의 현장적용 가능성 분석 (Effect of Using Coal Gasification Slag as Fine Aggregate on Field Applicability of the Concrete through Mock-up Test)

  • 한준희;이영준;현승용;한민철;윤기원;한천구
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2018년도 추계 학술논문 발표대회
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    • pp.21-22
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    • 2018
  • In this study, the characteristics of the Mock-up test were reviewed to analyze the applicability of the coal gasification slag (CGS) from the integrated gasification combination Cycle (IGCC) to the concrete fine aggregate. The analysis shows that CGS and crushed sand mix is the best combination of CGS combined with about 50 % of CGS based on the effects of promoting liquidity and strength. This is expected to be a positive factor in securing the strength and flexibility of concrete given the optimal mix of CGS, and may also contribute to the improvement of quality.

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석탄가스화 용융 슬래그 치환 콘크리트의 염화이온 침투 저항성 검토 (Evaluation of Chloride Ion Penetration Resistance of Coal Gasification Slag Replaced Concrete)

  • 조현서;김민혁;이건철
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2019년도 추계 학술논문 발표대회
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    • pp.166-167
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    • 2019
  • In this study, to test the performance of concrete used as a concrete admixture as a recycling method of CGS, gypsum was mixed and the chloride ion penetration resistance test of CGS and BFS substituted concrete was conducted. As a result, it was found that without gypsum type test specimen, the CGS sustituted test specimens had lower chloride ion penetration resistance than the BFS substituted specimens. When gypsum was added, it was confirmed that the chloride ion penetration resistance was poor regardless of the type of admixture. In addition, it was confirmed that both admixtures were less resistant to chloride ion penetration than OPC, regardless of the presence of gypsum. However, considering the uneven quality variation of coal, which greatly affects the quality of CGS, further research is needed.

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석탄 가스화 용융 슬래그를 혼합 잔골재로 사용한 FA 치환 콘크리트의 수화열 저감 (Reduction of Hydration heat of FA concrete using Coal Gasification Slag for Mixed Fine Aggregate)

  • 한준희;이영준;최일경;김종;한민철;한천구
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2019년도 추계 학술논문 발표대회
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    • pp.79-80
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    • 2019
  • This study was intended to examine the possibility of reducing hydration heat by FA substitution and combination of slag (CGS) from coal gasification power generation (IGCC) with mixed aggregate for concrete. The analysis results showed good results if liquidity increases as the ratio of CGS increases, air volume decreases, and compressive strength is mixed up to 25% in the residual aggregate. The results showed that the heat of hydration was reduced compared to plain due to the boron content of CGS as the CGS substitution rate increased, but it was larger due to the combination with FA substitution. It was found that the heat of hydration was reduced.

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석탄 가스화 용융 슬래그를 콘크리트용 잔골재로 활용하기 위한 재료 특성 분석 (Analysis of The Properties of Materials for Utilizing Fine Aggregates for Concrete for Coal Gasification Slag)

  • 김수호;임군수;한준희;현승용;김종;한민철
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2021년도 가을 학술논문 발표대회
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    • pp.170-171
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    • 2021
  • This study compared the characteristics of the newly established JISA 5011-5 coal gasification slag fine aggregate with the characteristics of CGS generated in Korean IGCC through microscopic analysis. As a result of the study, similar results to K_CGS and J_CGS were found

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석탄 가스화 용융 슬래그의 비열 및 미소수화열 특성 (The Characteristics of Isothermal Conduction Calorimetry and Specific Heat in Coal Gasification Slag)

  • 한준희;후윈야오;임군수;김수호;김종;한민철
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2021년도 가을 학술논문 발표대회
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    • pp.182-183
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    • 2021
  • In this study, This is the result of thermal characteristics analysis to suggest an efficient method of using coal gasification slag(CGS) of byproduct from integrated gasification combined cycle(IGCC). In Specific Heat characteristics, CGS and CS showed similar values. Isothermal Conduction Calorimetry showed that the hydration reaction of cement was retarded when CGS was used. Therefore, it is expected that CGS will be used as an efficient alternative to reducing the hydration heat of mass concrete as a functional aggregate combination.

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고로슬래그 기반 순환유동층 플라이애시 및 미분탄 플라이애시 혼입에 따른 시멘트 모르타르의 특성 (Properties of Cement Mortar According to Mixing of Circulating Fluidized Bed Fly Ash and Pulverized Coal Fly Ash based on Blast Furnace Slag)

  • 조성우;나형원;형원길
    • 한국건축시공학회지
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    • 제21권2호
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    • pp.141-148
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    • 2021
  • 본 연구에서는 산업부산물 중 순환유동층 연소방식과 미분탄 연소과정에서 발생되는 플라이애시와 고로슬래그 미분말을 치환한 시멘트 모르타르의 특성을 파악하였다. 연구 결과, 순환유동층 플라이애시 및 미분탄 플라이애시 혼합 사용 시 강도발현 뿐만 아니라 내구성 측면에서도 유리하게 나타난다. 순환유동층 플라이애시는 초기 반응성 향상에 기여하며, 미분탄 플라이애시는 포졸란 반응으로 장기 강도 발현에 관여하게 된다. 따라서 순환유동층 플라이애시와 미분탄 플라이애시의 혼합사용은 고로슬래그 미분말을 치환한 시멘트 모르타르의 상호 보완적인 요소로 작용함을 알 수 있다.

제강슬래그, 우분 및 석회석을 활용한 폐 석탄광의 산성광산배수 처리 (Remediation of Acid Mine Drainage from an Abandoned Coal Mine Using Steel Mill Slag, Cow Manure and Limestone)

  • 정명채
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제10권3호
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    • pp.16-23
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    • 2005
  • 중금속과 황산이온의 농도가 높은 산성광산배수(AMD)를 배출하는 강원도 정선군에 위치한 삼척탄좌 정암광업소 유출수를 대상으로 제강 슬래그, 우분 및 석회석 등을 활용하여 처리실험을 수행하였다. Batch test와 적용성 시험 결과, 원수 1 L당 15 g의 제강 슬래그, 15 g의 우분 및 500 g의 석회석이 최적의 기질물질 양으로 조사되었다. 이를 기초로 제강 슬래그, 우분과 석회석으로 충진한 SAPS조, 침전조, 산화조 순서로 구성된 처리시스템을 구성하였다. 총 54일간 시행된 실험결과, 원수에 비해 pH의 상승(3.0에서 8.3)과 더불어 61%의 황산염이온 농도가 저감되었다 (1,042 mg/L에서 409 mg/L). 또한, 초기농도 대비 최종 방류수의 중금속 처리효율은 매우 높은 수준으로써 99.9% 이상의 Al, Fe, Zn과 92.6% Mn이 제거되었다. 즉, 제강 슬래그, 우분 및 석회석을 활용하면 산성광산수의 중화와 금속 침전효과를 얻을 수 있음을 확인하였다.

50kWth미분탄 연소 시스템에서 탄종별 슬래깅 및 파울링 특성 연구 (An Experimental Study on Slagging/Fouling Characteristics for Various Coals in a 50kWth Pulverized Coal Combustion System)

  • 강기섭;이재욱;채태영;류창국;양원
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2012년도 제45회 KOSCO SYMPOSIUM 초록집
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    • pp.107-109
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    • 2012
  • In Korean coal power plants, rising coal prices have recently led to the rapid utilization of low lank coals such as sub-bituminous coal with low calorific values and low ash fusion temperatures. Using these coals beyond the design range has resulted in important issues including slagging and fouling, which cause negative effects in boiler performances and unstable operations. The purpose of this study is to observe slagging and fouling characteristics resulted from burning various ranks of pulverized coals. We have tested 3 different coals: FLAME(bituminous), KCH(sub-bituminous) and MOOLARBEN(bituminous)coals in the pilot system $50kW_{th}$ scale. A stainless steel tube with preheated air inside was installed in the downstream in order to simulate water wall. Collected ash on the probe and the slag inside the furnace near burner were analyzed by SEM (scanning electron microscopy) to verify the formation degree, surface features and color changes of the pasty ash particles. Induced coupled plasma and energy dispersive X-ray spectroscopy were also performed to figure out the chemical characteristics of collected samples. As a result, KCH was observed that more slag was developed inside the walls of the furnace and on the probe than the other two kinds of coals, as shown in the calculate slagging and fouling indices as well.

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