• Journal of the Korean Society of Combustion
• /
• v.8 no.2
• /
• pp.34-40
• /
• 2003

Analyses for concentration, surface phenomena, and crystal structure were performed to identify the causes of clinker formation in three type of pulverized coal fired boilers. Some clinkers had partially molten surface and more CaO and $Fe_2O_3$ as compared with fly ash, and the major crystalline phases identified in the clinker were mullite and quartz. Clinkers were formed in high temperature zone of the boiler according to the identification of mullite by XRD. Free $SiO_2$ in sand combined with K, Na and Ca in limestone served as a fluxing agent to form clinkers in a circulating bed boiler.

• Journal of Korean Society for Atmospheric Environment
• /
• v.9 no.2
• /
• pp.125-131
• /
• 1993

Electrostatic Precipitator has been widely used to get high efficiency which is required for collection of fine particles. In order to provide collection efficiency and size distribution data for a pilot electrostatic precipitator, a pilot study has been conducted on fly ash from pulverized coal burning apparatus. The aims of this study are to investigate characteristics of electric charge, to measure collection efficiency varied with the applied voltage, to get an optimum current and current density. Optimum current density was obtained to 0.7mA/$cm^2$ at the average electric field strength 2.33kV/cm in this experiment. Maximum particle collection efficiency was indicated 99.21% at the applied voltage 7kV. Finally, particle size distribution is also compared with photographic results. Both coarse and fine particles at the range of 0.5$\sim$2$\mu$m and 3$\sim$10 SEM $\mu$m were clearly removed by increasing applied voltage.

• Journal of Environmental Science International
• /
• v.20 no.11
• /
• pp.1437-1445
• /
• 2011

The adsorption performance of lead ion was studied using five zeolites (Na-P1, sodalite (SOD), analcime (ANA), nepheline hydrate (JBW), cancrinite (CAN)) synthesized from Jeju scoria. The adsorption performances of lead ion decreased in the order of Na-P1 > SOD > ANA > JBW > CAN. These results showed that the synthetic zeolite with a higher cationic exchange capacity showed a higher adsorption performance. The uptake of lead ion by synthetic zeolites were described by Freundlich model better than Langmuir model. The adsorption kinetics of lead ion by synthetic zeolites fitted the pseudo 2nd order kinetics better than pseudo 1st order kinetics. The effective diffusion coefficients of lead ion by synthetic zeolites were ten times higher than the zeolite A synthesized from coal fly ash.

• Proceedings of the Korean Environmental Health Society Conference
• /
• 2001.11a
• /
• pp.64-69
• /
• 2001

The present work provides a result from the preliminary experiment for hydrocyclone technology. In this work, local lake sediments and waste coal fly ash were used as test samples, prior to the application of hydrocyclone technology to the waste sludge thickening. A few cyclones based on the Rietema standard geometry were prepared. Chemical analysis of the sediments showed that more organic contaminants were in smaller particles. The experimental tests further showed that physical characteristics of particles, configuration of the cyclone and operation condition would affect the separation efficiency. The current results showed that small size cyclones might improve the separation and concentration of the lake sediments, and higher inlet velocity would increase the concentration rate of under flow and absolute concentration of sediment particles.

• Proceedings of the Korean Institute of Building Construction Conference
• /
• 2022.04a
• /
• pp.158-159
• /
• 2022

This study analyzed the temperature stress through mixtures mass concrete hydration heat analysis according to the replacement rates of FAC and CGS. As a result of the analysis, it was possible to confirm the effect of reducing hydration heat when CGS is substituted for the low heat mixture of mass concrete. However, the stress of the FAC+CGS combination exceeded the tensile stress. It is believed that it is necessary to apply the insulating sheet of the surface part and reduce the unit weight of cement.

• Proceedings of the Korean Institute of Building Construction Conference
• /
• 2022.04a
• /
• pp.117-118
• /
• 2022

In this study, adiabatic temperature rise of concrete depending on binder compositions and CGS contents is studied to provide informations for CGS low-heating aggregate and mixture designs for upper and lower placement lifts. Test nresults indicate that it is desirable to apply the combination of binders between top and bottom lift. For top lift, SESC or ESC is recommended, and for bottom lift, FAC+CGS 50 % is good for material composition.

• Journal of the Korean Recycled Construction Resources Institute
• /
• v.9 no.4
• /
• pp.578-584
• /
• 2021

This study comparatively analyzed the properties of hydration reaction and strength development of four types of pond ash(PA) and fly ash(FA), aiming for the effective use of PA. The PA whose chlorine content was highest due to the seawater movement method had a faster setting time, higher cumulative heat, and greater initial strength development than those of FA due to the acceleration of the cement hydration reaction. However, the activity factor increase rate decreased after seven days of curing due to the rapid generation of early hydrates. The PA that contained impurities, such as a large amount of unburned carbon, had a delayed setting time due to the lower hydration reaction. Moreover, the strength was degraded in all curing ages. The PA whose chlorine content was lower due to the freshwater movement method and the amorphous content exhibited similar hydration reactivity and strength development characteristics compared to that of FA. The thermogravimetric analysis results verified that it had a similar level of Ca(OH)₂ consumption and pozzolanic reactivity with that of FA. Conclusively, it is necessary to expand the application of the freshwater movement method and manage the ignition loss to raise PA's usability.

• Journal of Korean Society of Environmental Engineers
• /
• v.27 no.4
• /
• pp.445-449
• /
• 2005

Present study was designed to evaluate the practical application of triethyl amine(TEA) injection for improving the collection efficiency of electrostatic precipitator(ESP) connected to a real operating plant. The major fuels used at the domestic power stations were bituminous coals imported from Australia, China, South Africa, and USA. Although the values of the electric resistance would be more or less different according to the type of the coals used, the unique electric resistance values of fly ash from the coals were mostly higher than $1{\times}10^{12}\;{\Omega}-cm$ and therefore, back corona problems were always expected to occur in the electrostatic precipitator. The particulates concentrations, smoke concentrations and their electric resistivity measured at the outlet of ESP, and the inspection of collection indicated that the injection of TEA improved the collection efficiency of particulate at collection plates of ESP. The electric resistance for, fly ash with the injection concentration of TEA 15 ppm(Purity 99.7%) was lowered to $2.1{\times}10^{11}\;{\Omega}-cm$ after injection from $1.9{\times}10^{12}\;{\Omega}-cm$ before injection. Under this condition, the dust emission content at the stack was reduced to approximately 80%, lowering the average outlet concentrations of particulates from $70\;mg/Sm^3$ to $14\;mg/Sm^3$.

• Economic and Environmental Geology
• /
• v.51 no.5
• /
• pp.429-438
• /
• 2018

Since concrete is a hardened aggregates of various materials, it needs to be crushed for chemical analyses. However, the effect of sample crushing on the analytical results has not been precisely assessed till today. In this study, we prepared concrete test pieces using Portand cements and fly ashes as binding materials, and ponded ashes and sands as aggregates and analyzed the heavy metals of the test pieces using Standards for Fair Testing of Soil Contamination (SFTSC) and Wastes (SFTW). For this, each test piece was partially crushed at first and sieved for separation of grains of <0.15 mm, 0.15-0.5 mm, and 0.5-5 mm from the same crushed samples (Crushing Method I). Results of those samples using SFTSC showed a clear trend that analyzed heavy metal concentrations are higher in the finer fractions. Particularly, fractions with <0.15 mm indicated much higher concentrations than the theoretical ones, which were calculated based on the concentrations of individual materials and their mixing fractions. In contrast, the analytical results were generally comparable with the theoretical ones when the test pieces were totally pulverized such that all the crushed grains were <0.15 mm in size (Crushing Method II). These results are associated with the fact that cement materials and fly ashes, which are high in heavy metals relative to other materials, are enriched in the fine fractions. The analytical results using the SFTW derived very low concentrations in most of parameters and did not indicate the dependence of concentrations on the crushing methods due to using distilled water as leaching agent.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.22 no.5
• /
• pp.1-6
• /
• 2021

Mercury, once released, is not destroyed but accumulates and circulates in the natural environment, causing serious harm to ecosystems and human health. In the United States, sulfur-impregnated activated carbon is being considered for the removal of vapor mercury from the flue gas of coal-fired power plants, which accounts for about 32 % of the anthropogenic emissions of mercury. In this study, a high-efficiency porous mercury adsorption material was developed to reduce the mercury vapor in the exhaust gas of coal combustion facilities, and the mercury adsorption characteristics of the material were investigated. As a result of the investigation of the vapor mercury adsorption capacity at 30℃, the silica nanotube MCM-41 was only about 35 % compared to the activated carbon Darco FGD commercially used for mercury adsorption, but it increased to 133 % when impregnated with 1.5 % sulfur. In addition, the furnace fly ash recovered from the waste copper regeneration process showed an efficiency of 523 %. Furthermore, the adsorption capacity was investigated at temperatures of 30 ℃, 80 ℃, and 120 ℃, and the best adsorption performance was found to be 80 ℃. MCM-41 is a silica nanotube that can be reused many times due to its rigid structure and has additional advantages, including no possibility of fire due to the formation of hot spots, which is a concern when using activated carbon.