• Journal of Environmental Health Sciences
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• v.28 no.5
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• pp.93-101
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• 2002

We have studied that the prediction of desulfurization efficiency by limestone in fluidized-bed coal combustor. The results were presented as follows : Firstly, the bed temperature had a great deal of effect on the desulfurization and the optimum temperature of limestone was 85$0^{\circ}C$~90$0^{\circ}C$. Secondly, as the velocity and temperature increased, $K_{s}$, K and the desulfurization efficiency increased. So, $k_{s}$, $k_{d}$ highly depended on the air velocity and bed temperature, and $k_{s}$, $k_{d}$ were 82.53 mm/sec, 0.0041/sec at 0.2 m/sec, 85$0^{\circ}C$, $k_{s}$, $k_{d}$ were 125.62 mm/sec. 0.00532/sec at 0.3 m/sec, 80$0^{\circ}C$ respectively. And $k_{s}$, $k_{d}$ were 143.78 mm/sec, 0.00568/sec at 0.3 m/sec, 85$0^{\circ}C$. Thirdly, as a result of desulfurization modeling, there was good agreement between theory and experiments as anthracite fraction increased. At 3.0 of optimum Ca/S molar ratio, there was very good agreement between theory and experiments.riments.riments.s.

• Resources Recycling
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• v.15 no.1 s.69
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• pp.58-65
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• 2006

A new technology for refused derive fuel(RDF) utilization in circulating fluidized bed is under development. The RDF is tested in a bench scale circulating fluidized bed(CFB) combustor and its burning characteristics were investigated and collected as design parameters. The combustions were controllable and the HCl emission which is most important toxic emission were below 150 ppm at the exit of the combustor. The differences between conventional coal homing circulating fluidized bed boiler and the exclusive RDF boiler were studied and commercial scale co-generation CFB for RDF was designed.

• Proceedings of the Korean Institute of Resources Recycling Conference
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• 2005.10a
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• pp.124-134
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• 2005

A new technology for refused derive fuel(RDF) utilization in circulating fluidized bed is under development. The RDF is tested in a bench scale circulating fluidized bed(CFB) combustor and it's burning characteristics were investigated and collected as design parameters. The combustions were controllable and the HCl emission which is most important toxic emission were below 150ppm out of combustor. The differences between conventional coal burning circulating fluidized bed boiler and the exclusive RDF boiler were studied and commercial scale co-generation RDF CFB's were designed.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.25 no.10
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• pp.1373-1383
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• 2001

The desulfurization characteristics of anthracite in a bench scale pressurized fluidized bed combustor are investigated. The coal used in the experiment is domestic anthracite from Kangwon Taeback area. The desulphurization experiment is performed with limestone from Chungbuk Danyang. The pressure of the combustor is maintained at 6 atm, and the combustion temperatures are 850, 900, and 950$\^{C}$. The superficial gas velocities are 0.9, 1.1, and 1.3 m/s. The excess air ratio is varied from 5 to 35%. The Ca/S mole ratios are 0.5, 1.5, 2.5 and 4.5 mole. All experiments are executed at 2m bed height. Consequently, SO$_2$ concentration in the flue gas is increased with incresing bed temperature and superficial gas velocity. However SO$_2$ concentration is decreased with incresing excess air ratio and Ca/S mole ratio.

• 한국신재생에너지학회:학술대회논문집
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• 2010.06a
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• pp.105.2-105.2
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• 2010

석탄의 직접 연소 대신 고온/고압의 조건에서 불완전연소 및 가스화 반응을 통하여 일산화탄소(CO)와 수소($H_2$)가 주성분인 합성가스를 제조하여 이용하는 석탄 가스화 기술은 현실적인 에너지원의 확보를 위한 방법인 동시에 이산화탄소를 저감할 수 있는 기술이라 할 수 있다. 따라서, 본 연구에서는 non-slagging 방식의 pilot급 분류층 석탄가스화기를 대상으로 고압 미분탄공급장치, 합성가스 냉각장치, 고온 집진장치 등을 연계하여 상용급 석탄가스기와 유사한 $1,300^{\circ}C$, 20 kg/$cm^2$의 운전조건에서 미분탄의 안정적인 공급을 통한 양질의 합성가스 제조 및 제조된 합성가스의 분기 공급특성 시험을 진행하였다. 그리고, 고압 미분탄공급장치는 공급호퍼에 저장된 미분탄을 고온/고압 조건으로 운전되는 석탄가스화기에 공급하기 위한 설비로서, 이러한 고압 미분탄공급장치를 이용한 기류수송 방식의 미분탄 공급 기술은 가스화기 설계 및 운전제어 기술과 더불어 석탄가스화기 시스템의 안정적 연속운전을 위한 가장 핵심적인 기술 중 하나라고 할 수 있다. 따라서, 본 연구에서는 아역청탄인 인도네시아 ABK탄을 대상으로 향후 dense phase 고압 기류수송을 목적으로 하는 고압 미분탄공급장치의 성능특성을 시험을 진행하였는데, 시험 결과 73 kg/h 조건에서 20 kg/$cm^2$의 가스화기에 대한 안정적인 미분탄 공급특성을 확인할 수 있었으며, 이러한 미분탄 공급 조건에서 CO 40～45%, $H_2$ 16~20%, $CO_2$ 5~8% 조성의 양질의 합성가스를 평균적으로 $230{\sim}50Nm^3/h$ 안정적으로 제조할 수 있었다.

• Korean Chemical Engineering Research
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• v.44 no.5
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• pp.489-497
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• 2006

The economical efficiency of conversion of the PC (pulverized coal) firing boiler to the CFB (circulating fluidized bed) boiler which used Koran anthracite as fuel was evaluated. The economic feasibility study was also carried out with regard to maintenance of the existing PC boiler. The sensitivity of economical efficiency with variation of the electric power and coal industry and the policy of government was analyzed and compared. As a results of the evaluation, the economical efficiency of maintenance of the existing PC boiler was higher than that of conversion to the CFB boiler because of the special policy of the government for Korean anthracite. However, the conversion to the CFB boiler was more economically attractive from a point of view of effective use of energy resources and future electric power industry. Additionally, the fund support for electric power industry using Korean anthracite would be effective as changing the policy of the government.

• Journal of Soil and Groundwater Environment
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• v.18 no.7
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• pp.32-40
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• 2013

This study was objected to evaluate the potential impact on the groundwater environment of the coal bottom ash used as fill materials on the land surface. From four coal-fired power plants, bottom-ashes were collected and analyzed through sequential extraction and column leaching tests following the meteoric water mobility procedure. The column tests shown leaching heavy metals including Pb, As, B, Cu, Zn, Mn, Ni, Ba, Sr, Sb, V, Cr, Mo, and Hg. The relatively high concentrations of B, Sr, Ba, and V in leachate were attributed to both the higher concentrations in the bottom ash and the relatively higher portion of leachable state, sorbed state, of metals. Bottom-ash samples from the D-plant only show high leaching potential of sulfate ($SO_4$), probably originated from the coal-combustion process, called the Fluidized Bed Combustion. Consequently, to manage recycling bottom ashes as fill materials, an evaluation system should be implemented to test the leaching potentials of metals from the ashes considering the absolute amount of metals and their state of existence in ashes, and the coal-combustion process.

• Journal of Energy Engineering
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• v.12 no.1
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• pp.1-10
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• 2003

Pressurized fluidized bed combustion unit is operated at pressures of 1~1.5 MPa with combustion temperatures of 850~87$0^{\circ}C$. The pressurized coal combustion system heats steam, in conventional heat transfer tubing, and produces a hot gas supplied to a gas turbine. Gas cleaning is a vital aspect of the system, as is the ability of the turbine to cope with some residual solids. The need to pressurize the feed coal, limestone and combustion air, and to depressurize the flue gases and the ash removal system introduces some significant operating complications. The proportion of power coming from the steam : gas turbines is approximately 80:20%. Pressurized fluidized bed combustion and generation by the combined cycle route involves unique control considerations, as the combustor and gas turbine have to be properly matched through the whole operating range. The gas turbines are rather special, in that the maximum gas temperature available from the FBC is limited by ash fusion characteristics. As no ash softening should take place, the maximum gas temperature is around 90$0^{\circ}C$. As a result a high pressure ratio gas turbine with compression intercooling is used. This is to offset the effects of the relatively low temperature at the turbine inlet.

• Journal of The Korean Society of Agricultural Engineers
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• v.50 no.3
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• pp.43-48
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• 2008

The economics of a passive solar heating system (PSHS) with the pebble bed heat storage was evaluated, and the applications of the PSHS were analyzed, in this study. The results are as follows: The heating load, solar heat gain, and stored heat/year of the PSHS in the solar house model were found to be 10,778MJ, 3,438MJ, and 11,682MJ, respectively. The yearly energy expenses of the PSHS and the alternative heating system (conventional coal heating system, CCHS), which uses coal, were found to be USD 1.60/year and USD 60.90/year, respectively, and the yearly expenses of the PSHS were found to be 38 times less than those of the alternative heating system (CCHS). If it will be supposed that the life cycle of the passive solar heating system, according to the results of the LCC analysis in the two systems, is 40 years, the total expenses for the life cycle of the PSHS and the CCHS will be USD 1,431.50 and USD 2,740.00, respectively. The period for the investment payback of the PSHS is six years.

• Journal of Korean Society of Environmental Engineers
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• v.27 no.7
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• pp.762-770
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• 2005

Adsorption and biodegradation performance of chlorinated by-products such as trihalomethanes(THMs) and haloacetic acids(HAA5) on granular activated carbon were evaluated in this study. The coconut-based activated carbon was found more effective than others in adsorption of THMs due to larger pore volume of less than $20{\AA}$. The wood-based activated carbon was less effective than coconut- and coal-based activated carbon in adsorption nevertheless having larger pore volume and specific surface area than others. The maximum adsorption capacity(X/M) of coconut-based carbon for THMS was 1.1-1.5 times larger than coal based carbon and 14.1-31.4 times larger than wood based activated carbons. Activated carbon usage rate(CUR) of coconut-, coal- and wood-based activated carbons for chloroform were 9.4, 11.2 and 38 g/day respectively. In the evaluation of adsorption isotherm of THM species for coconut-, coal- and wood-based activated carbons, k value of chloroform was the lowest in the THM species, It menas that chloroform is difficult to remove by activated carbon adsorption. and BDCM, CDBM, bromoform are in the succeeding order of adsorption. In the evaluation of biodegradation rate, mean biodegradation rate was chloroform 7%, BDCM 5%, CDBM 4% and bromoform 3%, respectively THMs are difficult materials to be biodegraded. In the evaluation of characteristics of adsorption and biodegradation for HAA5 species, HAA5 species appear to be removed effectively by activated carbon. Most of the HAA5 are adsorbed at the beginning of operation periods and HAA5 except TCAA were almost biodegraded from bed volume of 2,000 and more than 90 percent of biodegradation of TCAA was started from bed volume around 4,000 and after that biodegradation rate was increased with increasing bed volume.