• Title/Summary/Keyword: co-cycle

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Hybrid Capacitors Using Organic Electrolytes

  • Morimoto, T.;Che, Y.;Tsushima, M.
    • Journal of the Korean Electrochemical Society
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    • v.6 no.3
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    • pp.174-177
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    • 2003
  • Electric double-layer capacitors based on charge storage at the interface between a high surface area activated carbon electrode and an electrolyte solution are characterized by their long cycle-life and high power density in comparison with batteries. However, energy density of electric double-layer capacitors obtained at present is about 6 Wh/kg at a power density of 500W/kg which is smaller as compared with that of batteries and limits the wide spread use of the capacitors. Therefore, a new capacitor that shows larger energy density than that of electric double-layer capacitors is proposed. The new capacitor is the hybrid capacitor consisting of activated carbon cathode, carbonaceous anode and an organic electrolyte. Maximum voltage applicable to the cell is over 4.2V that is larger than that of the electric double-layer capacitor. As a result, discharged energy density on the basis of stacked volume of electrode, current collector and separator is more than 18Wh/l at a power density of 500W/l.

Characteristics of Chemical Reactions in Coal Gasification Processes (석탄가스화 화학반응의 기본 특성 분석 연구)

  • Baek, Seung-Chul;Sohn, Jeong-L.;Song, Seung-Jin
    • Proceedings of the KSME Conference
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    • 2008.11b
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    • pp.3125-3130
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    • 2008
  • Coal is one of the most abundant and cheapest energy sources in the earth, but its typical combustion product, $CO_2$, is related with serious recent environmental issues such as global warming. The Integrated Coal Gasification Combined Cycle (IGCC) with $CO_2$ sequestration is one of the most promising options to produce electricity using a relatively cheap fuel (coal) with minimum impact on environment. In IGCC power generation systems, some chemical reactions are required to gasify coal to produce syngases such as $H_2$ and CO, which would be burnt in the combustor to produce heat for power generation, with a penalty of additional energy consumption. In this paper, several chemical reactions for the gasification of coal are considered and their characteristics are investigated.

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Performance Analysis on Gas Turbine based Oxy-fuel Combustion Power Plants (가스터빈과 순산소 연소를 적용한 발전시스템의 성능해석)

  • Lee, Young-Duk;Lee, Sang-Min;Park, Jun-Hong;Yu, Sang-Seok;Ahn, Kook-Young
    • Proceedings of the KSME Conference
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    • 2008.11b
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    • pp.3169-3174
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    • 2008
  • Future power plants will be required to adopt some type of carbon capture and storage (CCS) technologies to reduce their CO2 emissions. One of distinguished CCS techniques expected to resolve the green house effect is to apply the oxy-fuel combustion technique to power plant, and a lot of research/demonstration programs have been going on in the world. In this paper, CO2-capturing power plants based on gas turbine and oxy-fuel combustion are investigated over several types of configurations. As a prior step, simulation model for 500 MW-class combined cycle power plant was set and was used as a reference case. The efficiencies of several power plants was compared and the advantages and disadvanteges was investigated.

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Study on the Fuzzy Control of CO2 Heat Pump System (이산화탄소 열펌프 시스템의 퍼지 제어에 관한 연구)

  • Lee, Jae-Seung;Han, Yung-Hee;Kim, Min-Soo
    • Proceedings of the SAREK Conference
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    • 2008.11a
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    • pp.513-518
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    • 2008
  • In the air-conditioning and refrigeration industry, the efforts to protect the environment have been made. One of them is to use carbon dioxide as an alternative refrigerant, however, several researches have shown that the transcritical heat pump system using $CO_2$ has relatively lower efficiency resulting in a degraded steady-state system performance. Capacity control with fuzzy controller was carried out for $CO_2$ heat pump system. Evaporator secondary fluid outlet temperature was suggested for the control variable of compressor speed modulation.

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Characteristics and electrochemical performance of Metal Oxide/MWNTs/nano-composites for ultra capacitor (울트라 커패시터용 Metal Oxide/MWNTs의 특성과 전기화학적 성능)

  • Shin, Jeong-Gyun;Park, Soo-Gil
    • Proceedings of the KIEE Conference
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    • 2007.07a
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    • pp.1365-1366
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    • 2007
  • Cobalt oxide was composite with MWNT to attain cycle stable by chemical method. We have been considered CoOx is the ideal material for high energy density electrochemical capacitor due to pseudo capacitor reaction. In this study we found that decrease in resistance due to composite MWNT. Also CoOx/MWNT composite material have resulted larger capacitance and exhibits better electrochemical behavior. The structural feature was investigated by using SEM. The CoOx/MWNT composite is not only a promising ultracapacitor material for energy storages but also has a good possibility because of its great capacitive properties, simple preparation and low cost.

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Electrical Degradation of Stator Bars for Large Turbine Generator after 1000 Thermal Cycles (대형 터빈 발전기용 고정자 권선의 1000 thermal cycle 후 전기적 특성 변화)

  • Kang, Myung-Guk;Kim, Tae-Hee;Lee, Jai-Kwun
    • Proceedings of the KIEE Conference
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    • 2007.07a
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    • pp.975-976
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    • 2007
  • Thermal and mechanical stresses, caused by repetitive start and stop and load fluctuation during long time operation, on winding stator bars are one of the main causes for electrical degradation of insulating materials. To understand the degradation process, we manufactured bar specimens with the same processes that make generator winding stator bars and the specimens were subjected to various degrees of thermal cycling. Measurements of the insulation properties, such as dissipation factor, tip-up and partial discharge, for un-aged specimens and for specimens aged by thermal cycling at 50, 100, 250, 500 and 1000 thermal cycles were performed. Finally all specimens were tested to obtain electrical breakdown voltages. In this paper we present the data and electrical degradation analysis results obtained during this program.

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A Study on Development of Flux to Restrict Occurrence of ion Migration in Lead-Free Solder (무연솔더 내 마이그레이션 플럭스개발에 관한 연구)

  • Ryu Dong Su;Lim Jae Hoon;Woo Seong Woo
    • Proceedings of the Korean Reliability Society Conference
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    • 2005.06a
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    • pp.385-392
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    • 2005
  • The restriction of the use of hazardous substances in electrical and electronic equipment legislation mandates the substitution of lead and other hazardous substances in electronics products by July 2006. Due to this legislative pressure, the electronics industry is moving to adoption of lead free solders. In this paper, we investigated a flux to restrict generating electrochemical migration in lead-free solder. The lead-free solders used in this study were Sn-0.7Cu-0.01P and Sn-3.0Ag-0.5Cu. To measure the resistance of electrochemical migration, the dew-cycle test and water drop test were adopted. As the result, now flux having high durable of electrochemical migration was developed.

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The water-energy-food resources and environment: Evidence from selected SAARC countries

  • Mansoor, Abdul;Sultana, Baserat;Shafique, Saima;Zaman, Khalid
    • Advances in Energy Research
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    • v.6 no.1
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    • pp.1-15
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    • 2019
  • The objective of the study is to examine the relationship between water resources, energy demand, food production, and environmental pollutants in selected SAARC nations, namely, Bangladesh, India, Pakistan, and Sri Lanka, during the period of 1990-2016. The results show that water, energy, and food (WEF) resources substantially affected air quality in the form of high mass carbon emissions, fossil fuel energy demand, methane discharges, nitrous oxide emissions, and greenhouse gas emissions in these countries. Food production and food deficit largely increase $CO_2$ emissions due to unsustainable production and malnutrition, while land use under cereal production increases $CH_4$ and $N_2O$ emissions. Electricity production escalates $CO_2$ emissions and fossil emissions across countries. The results support the carbon EKC hypothesis, while monotonic increasing function exists in case of fossil fuel energy. The study emphasizes the need to ensure environmental sustainability agenda by adopting cleaner production technologies in WEF resources.

Sensitization of the Apoptotic Effect of ${\gamma}$-Irradiation in Genistein-pretreated CaSki Cervical Cancer Cells

  • Shin, Jang-In;Shim, Jung-Hyun;Kim, Ki-Hong;Choi, Hee-Sook;Kim, Jae-Wha;Lee, Hee-Gu;Kim, Bo-Yeon;Park, Sue-Nie;Park, Ok-Jin;Yoon, Do-Young
    • Journal of Microbiology and Biotechnology
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    • v.18 no.3
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    • pp.523-531
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    • 2008
  • Radiotherapy is currently applied in the treatment of human cancers. We studied whether genistein would enhance the radiosensitivity and explored its precise molecular mechanism in cervical cancer cells. After co-treatment with genistein and irradiation, the viability, cell cycle analysis, and apoptosis signaling cascades were elucidated in CaSki cells. The viability was decreased by co-treatment with genistein and irradiation compared with irradiation treatment alone. Treatment with only ${\gamma}$-irradiation led to cell cycle arrest at the $G_1$ phase. On the other hand, co-treatment with genistein and ${\gamma}$-irradiation caused a decrease in the $G_1$ phase and a concomitant increase up to 56% in the number of $G_2$ phase. In addition, co-treatment increased the expression of p53 and p21, and Cdc2-tyr-15-p, supporting the occurrence of $G_2/M$ arrest. In general, apoptosis signaling cascades were activated by the following events: release of cytochrome c, upregulation of Bax, down regulation of Bcl-2, and activation of caspase-3 and -8 in the treatment of genistein and irradiation. Apparently, co-treatment downregulated the transcripts of E6*I, E6*II, and E7. Genistein also stimulated irradiation-induced intracellular reactive oxygene, species (ROS) production, and co-treatment-induced apoptosis was inhibited by the antioxidant N-acetylcysteine, suggesting that apoptosis has occurred through the increase in ROS by genistein and ${\gamma}$-irradiation in cervical cancer cells. Gamma-irradiation increased cyclooxygenase-1 (COX-2) expression, whereas the combination with genistein and ${\gamma}$-irradiation almost completely prevented irradiation-induced COX-2 expression and $PGE_2$ production. Co-treatment with genistein and ${\gamma}$-irradiation inhibited proliferation through $G_2/M$ arrest and induced apoptosis via ROS modulation in the CaSki cancer cells.

Metabolic Characteristic of the Liver of Dairy Cows during Ketosis Based on Comparative Proteomics

  • Xu, Chuang;Wang, Zhe;Liu, Guowen;Li, Xiaobing;Xie, Guanghong;Xia, Cheng;Zhang, Hong You
    • Asian-Australasian Journal of Animal Sciences
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    • v.21 no.7
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    • pp.1003-1010
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    • 2008
  • The objective of the present study was to identify differences in the expression levels of liver proteins between healthy and ketotic cows, establish a liver metabolic interrelationship of ketosis and elucidate the metabolic characteristics of the liver during ketosis. Liver samples from 8 healthy multiparous Hostein cows and 8 ketotic cows were pooled by health status and the proteins were separated by two-dimensional-electrophoresis (2D-E). Statistical analysis of gels was performed using PDQuest software 8.0. The differences in the expression levels of liver proteins (p<0.05) between ketotic and healthy cows were identified by matrix-assisted laser desorption/ionization time-of-flight (MALDI-TOF-TOF) tandem mass spectrometry. Five enzymes/proteins were identified as being differentially expressed in the livers of ketotic cows: expression of 3-hydroxyacyl-CoA dehydrogenase type-2 (HCDH), acetyl-coenzyme A acetyltransferase 2 (ACAT) and elongation factor Tu (EF-Tu) were down-regulated, whereas that of alpha-enolase and creatine kinase were up-regulated. On the basis of this evidence, it could be presumed that the decreased expression of HCDH, which is caused by high concentrations of acetyl-CoA in hepatic cells, in the livers of ketotic cows, implies reduced fatty acid ??oxidation. The resultant high concentrations of acetyl-CoA and acetoacetyl CoA would depress the level of ACAT and generate more ??hydroxybutyric acid; high concentrations of acetyl-CoA would also accelerate the Krebs Cycle and produce more ATP, which is stored as phosphocreatine, as a consequence of increased expression of creatine kinase. The low expression level of elongation factor Tu in the livers of ketotic cows indicates decreased levels of protein synthesis due to the limited availability of amino acids, because the most glucogenic amino acids sustain the glyconeogenesis pathway; thus increasing the level of alpha-enolase. Decreased protein synthesis also promotes the conversion of amino acids to oxaloacetate, which drives the Krebs Cycle under conditions of high levels of acetyl-CoA. It is concluded that the livers of ketotic cows possess high concentrations of acetyl-CoA, which through negative feedback inhibited fatty acid oxidation; show decreased fatty acid oxidation, ketogenesis and protein synthesis; and increased gluconeogenesis and energy production.