• Title/Summary/Keyword: co-agent

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A Newly Developed Non-Cyanide Electroless Gold Plating Method Using Thiomalic Acid as a Complexing Agent and 2-Aminoethanethiol as a Reducing Agent

  • Han, Jae-Ho;Lee, Jae-Bong;Van Phuong, Nguyen;Kim, Dong-Hyun
    • Corrosion Science and Technology
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    • v.21 no.2
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    • pp.89-99
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    • 2022
  • A versatile method for performing non-cyanide electroless gold plating using thiomalic acid (TMA) as a complexing agent and 2-aminoethanethiol (AET) as a reducing agent was investigated. It was found that TMA was an excellent complexing agent for gold. It can be used in electroless gold plating baths at a neutral pH with a high solution stability, makes it a potential candidate to replace conventional toxic cyanide complex. It was found that one gold atomic ion could bind to two TMA molecules to form the [2TMA-Au+] complex in a solution. AET can be used as a reducing agent in electroless gold plating solutions. The highest current density was obtained at electrode rotation rate of 250 to 500 rpm based on anodic and cathodic polarization curves with the mixed potential theory. Increasing AET concentration, pH, and temperature significantly increased the anodic polarization current density and shifted the plating potential toward a more negative value. The optimal gold ion concentration to obtain the highest current density was 0.01 M. The cathodic current was higher at a lower pH and a higher temperature. The current density was inversely proportional to TMA concentration.

Stabilization of Doxorubicin Hydrochloride in Injections (염산 독소루비신 주사액의 안정화)

  • Lee, Sang-Cheol;Nam, Sang-Cheol;Kim, Chun-Seong;Shin, Hyun-Jong;Paik, Woo-Hyun
    • Journal of Pharmaceutical Investigation
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    • v.24 no.3
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    • pp.109-113
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    • 1994
  • Effects of various formulation factors using $L_8$ orthogonal arrays with the stability of doxorubicin hydrochloride injections(DHls) were investigated. The degradation of DHI may be occured by pH, temperature, light and metal ions. It is known that DHI should be stored on refrigerated condition of $4{\sim}8^{\circ}C$ because of its unstability on the room temperature. The employed factors were sodium chloride as isotonic solution, sodium bisulfite or sodium pyrosulfite as an antioxidant, disodium edetate as a chelating agent, methyl parahydroxybenzoate as a dissolution time shortening agent, and hydrochloric acid or citric acid as a pH adjusting agent at $22^{\circ}C$. From the results of $L_8$ orthogonal arrays, an optimal formula, including sodium chloride, disodium edetate, sodium bisulfite and hydrochloric acid, was obtained and the shelf-life of the formula was determined as 560 days approximately.

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A Study on electrical properties of silicone rubber for ATH of coupling agent (ATH 표면처리에 따른 실리콘 고무의 전기적 특성 연구)

  • Jung, Se-Young;Kim, Byung-Kyu;Park, Choon-Hyun;Yeo, Hak-Gue
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.11a
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    • pp.206-209
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    • 2002
  • The purpose of this research was to find influence of compounding materials on electrical properties of silicone rubber such as tracking characteristic. The tracking characteristic was tested through controlling the ATH, a widely use anti-tracking agent. Regarding the particle size and coupling agent of ATH, compound silicone rubber with ATH of coupling agent and larger diameter showed better anti-tracking properties. It can be included that ATH of coupling agent use vinyl silane, dispose of tracking characteristic was achieve excellant results.

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Brazilin as a new sunless tanning agent

  • Lee, Kang-Tae;Kim, Jeong-Ha
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.23 no.3
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    • pp.82-85
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    • 1997
  • To develop an active material for skin darkening, we examined the effect of 300 plants on tyrosinase activity and found only Caesalpinia sappan has an ability to increase tyrosinase activity highly and melanin contents in B-16 melanoma cells. A compound increasing tyrosinase activity and melanin production was isolated from Caesalpinia sappan Lignum. Brazilin was identified as a new active agent. Brazilin increases the tyrosinase activity and malanin production of B-16 melanoma cells. In conclusion, it seems that brazilin cal be used as a new sunless tanning agent.

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A Study on the Hydrolyzed Ginseng Saponin-Quaternary and its Application in Cosmetics (가수분해된 인삼사포닌 4급 암모늄엽과 화장품으로의 응용에 관한 연구)

  • 김영대;김창규;이정남;하병조
    • Journal of Ginseng Research
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    • v.13 no.2
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    • pp.189-197
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    • 1989
  • A new quaternary ammonium compound, hydrolyzed ginseng-saponin quaternary (HGSQ), from Korean ginseng saponin and 2,3-epoxypropyltrimethylammonium chloride has been developed as a conditioning agent in cosmetics. This structure has a hydrophobic group from the aglycone of ginseng saponin which is biologically active and considered to be the most important component of the Korean ginseng. Its properties : surface tension, critical micelle concentration (CMC), eye irritation, sorption onto hair, force reduction(%) and moisture retention effect were studied. Its cationic character allows the molecule to be more substantive than ginseng saponin. HGSQ had good physical properties and was safe. enough as a cosmetic raw material. Also half-head tests of HGSQ-containing shampoo were carried out to compare the conditioning effects in shampoos. HGSQ was an excellent conditioning agent in shampoo..

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The Effects of the Area of Openings on the Performance of a $CO_2$ Extinguishing System -The CFD Simulations of the Oil Surface Fire in a Machine Room- (개구부 면적이 $CO_2$ 소화설비의 소화성능에 미치는 영향 -기계실 석유 표면화재의 CFD simulations-)

  • Jeon, Heung-Kyun;Choi, Young-Sang;Park, Jong-Tack
    • Fire Science and Engineering
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    • v.22 no.1
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    • pp.1-9
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    • 2008
  • Carbon dioxide($CO_2$) agent, which has more safely extinguished fire than any other gaseous fire extinguishing agents, has been widely used in various protected enclosures and types of fires. According to the concept of performance-based design(PBD). $CO_2$ extinguishing system to be designed is needed to be evaluated for the performance of fire suppression with possible fire scenarios in an enclosure. In this paper, CFD simulations were carried out to study the effects of opening area on the performance of $CO_2$ extinguishing system and the flow characteristics in the machine room of $100m^3$ in which kerosene spill fire happened. This study showed that time of fire suppression increased linearly in proportion to the size of opening area, and fires for each model were completely suppressed prior to the end of discharge of $CO_2$ agent. It was shown that mass flow rate through opening was influenced by the combined effects of heat release rate of fire and discharge of $CO_2$ agent. After $CO_2$ agent was completely discharged, oxygen concentrations in enclosures for each model were lower than the limit concentration of combustion.

Human Chorionic Gonadotropin (hCG) Regression Curve for Predicting Response to EMA/CO (Etoposide, Methotrexate, Actinomycin D, Cyclophosphamide and Vincristine) Regimen in Gestational Trophoblastic Neoplasia

  • Rattanaburi, Athithan;Boonyapipat, Sathana;Supasinth, Yuthasak
    • Asian Pacific Journal of Cancer Prevention
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    • v.16 no.12
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    • pp.5037-5041
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    • 2015
  • Background: An hCG regression curve has been used to predict the natural history and response to chemotherapy in gestational trophoblastic disease. We constructed hCG regression curves in high-risk gestational trophoblastic neoplasia (GTN) treated with EMA/CO and identified an optimal hCG level to detect EMA/CO resistance in GTN. Materials and Methods: Eighty-one women with GTN treated with EMA/CO were classified as primary high-risk GTN (n = 65) and single agent-resistance GTN (n = 16). The hCG levels prior to each course of chemotherapy were plotted in the 10th, 50th, and 90th percentiles to construct the hCG regression curves. Diagnostic performance was evaluated for an optimal cut-off value. Results: The median hCG levels were 264,482 mIU/mL mIU/mL and 495.5 mIU/mL mIU/mL for primary high-risk GTN and single agent-resistance GTN, respectively. The 50th percentile of the hCG level in primary high-risk GTN and single agent-resistance turned to normal before the 4th and the 2nd course of chemotherapy, respectively. The 90th percentile of the hCG level in primary high-risk GTN and single agent-resistance turned to normal before the 9th and the 2nd course of chemotherapy, respectively. The hCG level of ${\geq}118.6mIU/mL$ mIU/mL at the 5thcourse of EMA/CO predicted the EMA/CO resistance in primary high-risk GTN patients with a sensitivity of 85.7% and a specificity of 100%. Conclusion: EMA/CO resistance in primary high-risk GTN can be predicted by using an hCG regression curve in combination with the cut-off value of 118.6 mIU/mL at the 5thcourse of chemotherapy.

CoDABot: An Agent-Based Continuous Double Auction System

  • Jung, Yong-Gyu;Kim, Kwang-Su;Kim, In-Cheol
    • Proceedings of the Korea Inteligent Information System Society Conference
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    • 2001.01a
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    • pp.78-82
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    • 2001
  • Most of current Internet auction systems are simple server programs that partly automated the function of the conventional auction house. These system do not provide sufficient independence, distribution and parallelism between the functions of the conventional auction house. In there are automated by server program, but still users need to execute a repetitive task to monitor the dynamic progress of a certain auction, decide proper bid price, and submit the bid. Another problem is that they support only single as English auction and Dutch auction, but they do not support the double auctions are superior to the single auction with respect to speed., efficiency, and the fair distribution of profit. In this paper, we present design and implement of an agent-based continuous double auction system, called CoDABot, in order to mitigate the limitations of current auctions system. CoDABot supports continuous double auction, provides various bidding agent for users to select, and has been implemented into a multi-agent system that realize more independent, distributed, and parallel subsystems.

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Sulfuric Acid Leaching of Valuable Metals from Spent Petrochemical Catalyst using Hydrogen Peroxide as a Reducing Agent (石油化學 廢觸媒로부터 過酸化水素를 還元劑로이용한 有價金屬의 황산침출)

  • 박경호;손정수;김종석
    • Resources Recycling
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    • v.10 no.2
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    • pp.20-26
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    • 2001
  • Sulfuric acid leaching of Mn, Co and Fe from spent petrochemical catalyst was performed using hydrogen peroxide as a reducing agent. Low extraction of Mn, Co and Fe was obtained by only sulfuric acid. When hydrogen peroxide were added as a reducing agent, the high extraction of these metals could be obtained. Different from ordinary leaching, the extraction per-centages of metal components decreased with elevating leaching temperature in this process. Under the optimum condition, the extraction percentages of Mn, Co and Fe were 93.0% , 87.0% and 100% respectively.

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Field Application of an Alternative Cleaning Agent to Methylene Chloride (Methylene Chloride의 대체세정제 적용 사례 연구)

  • 배재흠;신민철;이통영;조기수
    • Journal of the Korean institute of surface engineering
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    • v.32 no.2
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    • pp.109-124
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    • 1999
  • A study for replacing methylene chloride for an alternative cleaning agent which can be utilized for cleaning aluminium parts of hard disk drives was carried out at Suwon factory of Samsung Electro-mechanics Co. Ltd. As a result, quite a good cleaning agent was selected through data collection of alternative cleaning agents, their analysis of environment effects and safty factors and testing of their cleaning power. As compared with methylene chloride, the selected cleaning agent has better cleaning power. It is also more environmental-friendly, less toxic and more economical. And the operating cost reduction due to adoption of this alternative cleaning agent in Samsung Electro-mechanics Co. Ltd. was more than ₩l46,000,000 annually without any capital instrument in addition to improvement of environmental and safty conditions in the plant.

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