• Title/Summary/Keyword: co occurrence

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Water Gas Shift Reaction Research of the Synthesis Gas for a Hydrogen Yield Increase (수소 수율 증가를 위한 합성가스의 수성가스전환 반응 연구)

  • Kim, Min-Kyung;Kim, Jae-Ho;Kim, Woo-Hyun;Lee, See-Hoon
    • New & Renewable Energy
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    • v.5 no.2
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    • pp.9-14
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    • 2009
  • Automobile Shredder Residue (ASR) is very appropriate in a gasification melting system. Gasification melting system, because of high reaction temperature over than $1,350^{\circ}C$, can reduce harmful materials. To use the gasification processes for hydrogen production, the high concentration of CO in syngas must be converted into hydrogen gas by using water gas shift reaction. In this study, the characteristics of shift reaction of the high temperature catalyst (KATALCO 71-5M) and the low temperature catalyst (KATALCO 83-3X) in the fixed - bed reactor has been determined by using simulation gas which is equal with the syngas composition of gasification melting process. The carbon monoxide composition has been decreased as the WGS reaction temperature has increased. And the occurrence quantity of the hydrogen and the carbon dioxide increased. When using the high temperature catalyst, the carbon monoxide conversion ratio ($1-CO_{out}/CO_{in}$) rose up to 95.8 from 55.6. Compared with average conversion ratio from the identical synthesis gas composition, the low temperature catalyst was better than the high temperature catalyst.

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Effects of Outside Repair Welding on the Crack Growth in the Surge Nozzle Weld on the Hot Leg Side in a Nuclear Power Plant (외면 보수 용접이 원전 고온관 밀림노즐에서의 결함성장에 미치는 영향)

  • Na, Kyung-Hwan;Yun, Eun-Sub;Park, Young-Sheop
    • Journal of Welding and Joining
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    • v.29 no.2
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    • pp.34-39
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    • 2011
  • Nickel-based austenitic alloys such as Alloy 82 and 182 had been employed as the weld metals in nuclear power plants (NPPs) due to their high corrosion resistance as well as good mechanical properties. However, since the 2000s, the occurrence of primary water stress corrosion cracking has been reported in conjunction with these alloys in domestic and oversea NPPs. In the present work, we assumed an imaginary crack at the inner surface of a surge nozzle weld that had previously experienced the outside repair welding, and constructed its finite element model. Finite element analysis was performed with respect to the heat transfer, and then to the residual stress for obtaining the total applied stress distributions. These stress distributions were finally converted to the stress intensity factors for estimating crack growth rate. From the comparison of crack growth rate curves for the cases of no repair welding and outside repair welding, it was found that the outside repair welding did not exhibit negative effect on the crack growth for the surge nozzle under consideration in this work; in both cases, the cracks stopped growing before they became the through-wall cracks.

Study on the Graft Effect in Emulsion Polymerization of Poly(vinyl acetate-co-ethylene) Using Poly(vinyl alcohol) as Emulsifier (Poly(vinyl alcohol)를 이용한 Poly(vinyl acetate-co-ethylene) 에멀젼 중합에서 그라프트 연구)

  • Choi, Yong-Hae
    • Journal of Adhesion and Interface
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    • v.12 no.1
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    • pp.1-10
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    • 2011
  • An automated reaction calorimeter was used to directly monitor the rate of emulsion polymerization of vinyl acetate using poly(vinyl alcohol) (PVAs) having different degrees of blockiness. By using this technique in conjunction with other off-line measurements of the evolution of particle size distributions, important details of the process were observed. No constant graft rate period was observed for both low and high initial monomer-water ratios. The gel effect was observed for the low monomer-water ratio recipe. The particle size distributions were broad (particle diameter 40~100 nm) and bimodal. Continuous nucleation was observed to be accompanied by 'limited aggregation' and flocculation during the particle growth stages. It was speculated to be due to the occurrence of the extensive 'limited aggregation' and chain transfer to PVA leading to grafting.

A Study on the Rotating Biological Contactors for the Nitrification of Sewage (회전원판공정을 이용한 하수의 질산화에 관한 연구)

  • Jung, Kun-jin;Lee, Sang-Soo;Kim, Si-Hyeon;Park, Kyoo-hong
    • Journal of Korean Society on Water Environment
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    • v.18 no.2
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    • pp.189-199
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    • 2002
  • Nitrogen, in its various forms, can deplete dissolved oxygen levels in receiving waters, stimulate aquatic growth, exhibit toxicity toward aquatic life and affect the suitability of sewage for reuse. Pilot-scale Rotating Biological Contactor(RBC) experiments were conducted to examine biological nitrification, respectively, of municipal sewage with five different internal recirculation ratios of 0, 1, 2, 3, and 4 using the constant hydraulic loading of $205L/m^2{\cdot}day$. The use of internal recirculation improved nitrification on account of the dilution of biodegradable organic carbon in influent sewage down to 15 mg/L of $SBOD_5$ or less. Ammonium nitrogen of $14.3{\pm}2.4%$ was consumed by cellular assimilation without the occurrence of denitrification. The thickness of biofilm didn't seem effect significantly the nitrification and denitrification. Nitrification with internal recirculation was found to occur using hydraulic loading rate of as high as $205L/m^2{\cdot}day$, which was beyond the generally known values of it.

STEAM GENERATOR TUBE INTEGRITY ANALYSIS OF A TOTAL LOSS OF ALL HEAT SINKS ACCIDENT FOR WOLSONG NPP UNIT 1

  • Lim, Heok-Soon;Song, Tae-Young;Chi, Moon-Goo;Kim, Seoung-Rae
    • Nuclear Engineering and Technology
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    • v.46 no.1
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    • pp.39-46
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    • 2014
  • A total loss of all heat sinks is considered a severe accident with a low probability of occurrence. Following a total loss of all heat sinks, the degasser/condenser relief valves (DCRV) become the sole means available for the depressurization of the primary heat transport system. If a nuclear power plant has a total loss of heat sinks accident, high-temperature steam and differential pressure between the primary heat transport system (PHTS) and the steam generator (SG) secondary side can cause a SG tube creep rupture. To protect the PHTS during a total loss of all heat sinks accident, a sufficient depressurization capability of the degasser/condenser relief valve and the SG tube integrity is very important. Therefore, an accurate estimation of the discharge through these valves is necessary to assess the impact of the PHTS overprotection and the SG tube integrity of the primary circuit. This paper describes the analysis of DCRV discharge capacity and the SG tube integrity under a total loss of all heat sink using the CATHENA code. It was found that the DCRV's discharge capacity is enough to protect the overpressure in the PHTS, and the SG tube integrity is maintained in a total loss of all heat accident.

Fillers in the Hong Kong Corpus of Spoken English (HKCSE)

  • Seto, Andy
    • Asia Pacific Journal of Corpus Research
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    • v.2 no.1
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    • pp.13-22
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    • 2021
  • The present study employed an analytical framework that is characterised by a synthesis of quantitative and qualitative analyses with a specially designed computer software SpeechActConc to examine speech acts in business communication. The naturally occurring data from the audio recordings and the prosodic transcriptions of the business sub-corpora of the HKCSE (prosodic) are manually annotated with a speech act taxonomy for finding out the frequency of fillers, the co-occurring patterns of fillers with other speech acts, and the linguistic realisations of fillers. The discoursal function of fillers to sustain the discourse or to hold the floor has diverse linguistic realisations, ranging from a sound (e.g. 'uhuh') and a word (e.g. 'well') to sounds (e.g. 'um er') and words, namely phrase ('sort of') and clause (e.g. 'you know'). Some are even combinations of sound(s) and word(s) (e.g. 'and um', 'yes er um', 'sort of erm'). Among the top five frequent linguistic realisations of fillers, 'er' and 'um' are the most common ones found in all the six genres with relatively higher percentages of occurrence. The remaining more frequent realisations consist of clause ('you know'), word ('yeah') and sound ('erm'). These common forms are syntactically simpler than the less frequent realisations found in the genres. The co-occurring patterns of fillers and other speech acts are diverse. The more common co-occurring speech acts with fillers include informing and answering. The findings show that fillers are not only frequently used by speakers in spontaneous conversation but also mostly represented in sounds or non-linguistic realisations.

Preliminary Study on Chlorination Reaction of Lithium Carbonate for Carbon-Anode-Based Oxide Reduction Applications

  • Jeon, Min Ku;Kim, Sung-Wook;Choi, Eun-Young
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.19 no.2
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    • pp.225-231
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    • 2021
  • The reaction between Li2CO3 and Cl2 was investigated to verify its occurrence during a carbon-anode-based oxide reduction (OR) process. The reaction temperature was identified as a key factor that determines the reaction rate and maximum conversion ratio. It was found that the reaction should be conducted at or above 500℃ to convert more than 90% of the Li2CO3 to LiCl. Experiments conducted at various total flow rate (Q) / initial sample weight (Wi) ratios revealed that the reaction rate was controlled by the Cl2 mass transfer under the experimental conditions adopted in this work. A linear increase in the progress of reaction with an increase in Cl2 partial pressure (pCl2) was observed in the pCl2 region of 2.03-10.1 kPa for a constant Q of 100 mL·min-1 and Wi of 1.00 g. The results of this study indicate that the reaction between Li2CO3 and Cl2 is fast at 650℃ and the reaction is feasible during the OR process.

Co-existence of relapsing polychondritis and Crohn disease treated successfully with infliximab

  • Jung, Hye-In;Kim, Hyun Jung;Kim, Ji-Min;Lee, Ju Yup;Park, Kyung Sik;Cho, Kwang Bum;Lee, Yoo Jin
    • Journal of Yeungnam Medical Science
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    • v.38 no.1
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    • pp.70-73
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    • 2021
  • Relapsing polychondritis (RP) is a rare, progressive immune-mediated systemic inflammatory disease of unknown etiology, characterized by recurrent inflammation of cartilaginous structures. Approximately 30% of RP cases are associated with other autoimmune diseases. However, the co-occurrence of RP and Crohn disease (CD) has rarely been reported. Herein, we present a 35-year-old woman diagnosed with RP and CD, who was refractory to initial conventional medications, including azathioprine and glucocorticoid, but who subsequently responded to infliximab (IFX). For both diseases, remission was sustained with IFX. There has been no previous report regarding the successful treatment of co-existing RP and CD with IFX.

Influence of Microbial Activity on the Long-Term Alteration of Compacted Bentonite/Metal Chip Blocks

  • Lee, Seung Yeop;Lee, Jae-Kwang;Kwon, Jang-Soon
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.19 no.4
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    • pp.469-477
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    • 2021
  • Safe storage of spent nuclear fuel in deep underground repositories necessitates an understanding of the long-term alteration of metal canisters and buffer materials. A small-scale laboratory alteration test was performed on metal (Cu or Fe) chips embedded in compacted bentonite blocks placed in anaerobic water for 1 year. Lactate, sulfate, and bacteria were separately added to the water to promote biochemical reactions in the system. The bentonite blocks immersed in the water were dismantled after 1 year, showing that their alteration was insignificant. However, the Cu chip exhibited some microscopic etch pits on its surface, wherein a slight sulfur component was detected. Overall, the Fe chip was more corroded than the Cu chip under the same conditions. The secondary phase of the Fe chip was locally found as carbonate materials, such as siderite (FeCO3) and calcite ((Ca, Fe)CO3). These secondary products can imply that the local carbonate occurrence on the Fe chip may be initiated and developed by an evolution (alteration) of bentonite and a diffusive provision of biogenic CO2 gas. These laboratory scale results suggest that the actual long-term alteration of metal canisters/bentonite blocks in the engineered barrier could be possible by microbial activities.

A Study on Market Convergence Dynamics Based on Startup Data: Focusing on Korea (스타트업 데이터 기반의 시장융합 다이내믹스 분석: 한국을 중심으로)

  • Song, Chie Hoon
    • Journal of the Korean Society of Industry Convergence
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    • v.25 no.4_2
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    • pp.627-636
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    • 2022
  • Market convergence plays an increasingly important role in sustaining competitiveness and providing impetus for the new product development. However, existing research focused mostly on the analysis of convergence at technology level. This study examines the phenomenon of market convergence based on the start-up data. Similar to the analysis of technology convergence, this study adopts the concept of co-classification analysis for constructing the co-occurrence matrix and the corresponding network. In this context, network centrality measures were calculated to assess the influence of individual market segments. Based on three metrics "growth", "persistence" and "novelty", the market convergence dynamics were explored and promising interactions between two distinct market segments were highlighted. The findings suggest that both segments "AI" and "blockchain" are acting as a driver that fosters market convergence in the startup landscape. The analysis results can provide valuable information for the R&D managers and policy makers in the design of targeted policies and programs, which can promote market convergence and interdisciplinary knowledge transfer.