• 터널과지하공간
• /
• 제12권4호
• /
• pp.277-283
• /
• 2002

본 연구는 안쪽축이 회전하고 바깥쪽 실린더는 정지해있는 반경비가0.52이고 30$^{\circ}$ 경사진 동심 환형관내의 헬리컬 유동 특성에 관한 것이다. 비뉴튼 유체인 UC 수용액과 벤토나이트 수용액을 사용하여 안쪽축이 0~400pm으로 회전할 때 축방향 유동을 완전히 발달시킨 후 축방향 압력손실값을 측정하였다. 또한, 헬리컬 유동의 가시화는 불안정한 파를 관찰하기 위해 수행되었다. 현재 연구 결과는 표면마찰계수에 대해 로스비순(Ro)와 레이놀즈수(Re)의 관계를 나타내었다. 또한, 그 결과들은 유동 불안정성 메카니즘의 존재를 보인다. 축회전수가 증가함에 따라 압력손실이 증가하지만, 그 증가폭은 천이 및 난류영역에서는 레이놀즈수가 증가할수록 감소하며, 회전의 영향으로 유동교란이 증진되어 천이가 촉진된다. 또, 이런 유동교란의 증진은 표면마찰계수값의 증가와 함께 임계 레이놀즈수(Re$_{c}$)를 작게 만든다.

• 폴리머
• /
• 제37권3호
• /
• pp.332-341
• /
• 2013

H-shaped amphiphilic pentablock copolymers $(PSt)_2-b-PCL-b-PEO-b-PCL-b-(PSt)_2$ was synthesized via chemoenzymatic method by combining enzyme-catalyzed ring-opening polymerization (eROP) of ${\varepsilon}$-caprolactone (${\varepsilon}$-CL) and atom transfer radical polymerization (ATRP) of styrene. By this process, we obtained copolymers with controlled molecular weight and low polydispersity. The structure and composition of the obtained copolymers were characterized by nuclear magnetic resonance (NMR), gel permeation chromatography (GPC) and infrared spectroscopy analysis (IR). The crystallization behavior of the copolymers was analyzed by differential scanning calorimetry (DSC) and X-ray diffraction (XRD). The crystallization behavior of the H-shaped block copolymers demonstrated a PCL dominate crystallization. The self-assembly behavior of the copolymers was investigated in aqueous media. The hydrodynamic diameters of the copolymer micelles in aqueous solution were measured by dynamic light scattering (DLS). The morphology of the copolymer micelles was observed by atomic force microscopy (AFM) and transmission electron microscopy (TEM). The hydrodynamic diameters of spherical micelles declined gradually with the increase of the hydrophobic chain lengths of the copolymers. The critical micelle concentration (CMC) values were determined from fluorescence emission, and it was found that the CMCs decreased with an increase of PSt hydrophobic block lengths.

• 미생물학회지
• /
• 제14권3호
• /
• pp.117-127
• /
• 1976

A cellulase fraction (F IV-1) purified to about 8-folds was obtained from crude cellulase prepared from the wheat bran culture of S.atra. The partial purification of the enzyme was made by DEAE Sephadex and Sephdex cloumn chromatography in conjuction with ammonium sulfate precipitation. After stading at various pH's for 22 hours at $20^{\circ}C$, F IV-1 was most stable at pH 5.0 but when the enzyme fraction was stood for 74 hours, the point of pH stability was raised to around pH 6.0-7.0. After heating at various temperatures for 1 hour, F IV-1 was most stable at $20^{\circ}C$. The optimal enzyme activities of F IV-1 were seen at pH 6.0 and $50^{\circ}C$. The optimal concentrations of $Zn^{++}\;and\;Ca^{++}$ for the activities of crude cellulase were 6 and 4 mM respectively, but $Ca^{++}$ inhibited the enzyme activity at concentrations below 2 mM and above 6mM. Both $Cu^{++}\;and\;Mn^{++}$ ions inhibited cellulase activities and a ocmplete inactivation of crude cellulase was achieved at concentratioins of 5 and 2 mM of ions respectively. When Na-CMC was used as substrate, the Km values of crude cellulase and F IV-1 were calculated to be $5{\times}10^{-4}\;and\;2{\times}10^{-5}mM$, and V values 32 and 1.35 mmoles/hour, respectively. The Ki values of $Mn^{++}$ for crude cellulase and F IV-1 were found to be $8{\times}10^{-2}\;and\;3{\times}10^{-2}\;mM\;while\;those\;of\;Cu^{++}\;were\;at\;2{\times}10^{-1}\;and\;1{\times}10^{-1}\;mM\;respectively.\;Both\;Mn^{++}\;and\;Cu^{++}$ showed competitive inhibition with substrate.

• 한국언론정보학보
• /
• 제39권
• /
• pp.224-249
• /
• 2007

본 논문은 반사회적 활동으로 평가받고 있는 온라인 플레밍 현상을 설명하고 이를 해소할 수 있는 요인은 무엇인지를 살펴보고 있다. 이를 위해 본 논문은 상황에 걸쳐 일관된 행위 패턴을 보여주는 개성 특질(personality trait) 그리고 사회인구학적 요인(성별, 연령)을 통해 플레밍 행위를 설명하고자 하였다. 나아가 높은 플레밍을 보여주는 유의미한 설명변인 집단들에게 메시지 신뢰도가 미치는 영향 정도를 연구하고 있다. 이를 위해 인터넷 조사기관의 온라인 설문을 통한 자료수집이 이뤄졌다. 분석 결과에 따르면, 성별과 연령 그리고 언어적 공격(verbal aggression) 특질은 플레밍과 유의미한 관계가 있는 것으로 밝혀졌다. 특히 남성, 10대, 그리고 공격 특질이 높은 사람들은 플레밍 가능성이 높은 것으로 나타났다. 또한 플레밍 해소방안으로서 분석된 메시지의 신뢰도는 성별, 연령과는 무관한 것으로 나타난 반면, 개성 특질과는 어느 정도 유의미한 것으로 나타났다. 이러한 결과는 온라인에서 이뤄지는 커뮤니케이션의 질(quality)은 플레밍을 해소할 수 있는 하나의 방안일 수 있음을 시사하고 있다.

• 한국지반공학회:학술대회논문집
• /
• 한국지반공학회 2005년도 춘계 학술발표회 논문집
• /
• pp.653-657
• /
• 2005

This study applied the NDS method to the creek levee and the foundation of a building, for the purpose of ground improvement and cut-off. The conclusions are shown in the following. (1) The results of the field tests in the creek levee are as follows; the N value of the standard penetration test is $2{\sim}3$ before NDS grout and $9{\sim}21$ after NDS grout; in the alluvial layer, $7{\sim}11$ before NDS grout and $14{\sim}23$ after NDS grout. This confirms increasing ground strength with consistency ranging from stiff to very stiff. (2) The result of the permeability test in the creek levee shows that the ground had a great hydraulic conductivity with complete leakage before ground improvement but that the hydraulic conductivity has significantly increased to $3.17{\times}10^{-5}{\sim}4.65{\times}10^{-5}cm/sec$ after ground improvement by the NDS method. (3) The result from the field test of the foundation of the building confirms great reinforcing effects, showing that the allowable bearing capacity has increased from Pa = 5.0 $t/m^2$ before reinforcement to Pa = 25.0 $t/m^2$ after reinforcement.

• 한국환경과학회지
• /
• 제19권2호
• /
• pp.247-254
• /
• 2010

Ultrasound and Surfactant aided soil washing process has been shown to be an effective method to remove diesel from soils. The use of surfactants can improve the mobility of diesel in soil-water systems by increasing solubility of adsorbed diesel into surfactant micelles. However, a large amount of surfactant is required for treatment. In addition, synthetic surfactants, specially anionic, are more toxic and the surfactant wastewater is hard to treat by conventional wastewater treatments even by AOPs. Ultrasound improves desorption of the diesel adsorbed on to soil. The mechanisms are based on physical breakage of bonds by hot spot, directly impact onto soil particle surface, the fragmentation of long-chain hydrocarbons by micro-jet and microstreaming in the soil pores. The use of ultrasound as an enhancement method in both anionic and nonionic surfactant aided soil-washing processes were studied. And all experiments were examined proceeded under CMC surfactant concentration, frequency 35 khz, power 400 W, Soil-water ratio 1:3(wt%), particle size 0.24 ~ 2mm and initial diesel concentration. 20,000 mg/kg. Combination with ultrasound showed significant enhancements on all the processes. Especially, nonionic surfactant Triton-X100 with ultrasound showed remarkable enhancements and diesel removal rate enhanced by ultrasound helps desorpting of surfactant adsorbed onto soils which prevented decreasing surfactant activity.

• 대한한방소아과학회지
• /
• 제10권1호
• /
• pp.323-349
• /
• 1996

Gamitonggyutang has been used for treatment of rhinitis in oriental medical science. It is reported that Gamitonggyutang has a good effect on sinusitis in clinical medicine. So this study analysed the effect of Gamitonggyutang on anti-inflammatory, analgenic, anti-Allergic effect and Antibacterial Activity. The result were summerised as follows; 1. Gamitonggyutang extract decreased the edema indused by Carregennin at 200mg/kg and 400mg/kg. 2. Gamitonggyutang extract decreased the protein exudation indused by CMC-pouch at 200mg/kg and 400mg/kg. 3. Gamitonggyutang extract showed the ataralgesia at 800mg/kg by measurement of writhing syndrome, paw licking time and escape time induced by the i.p. infection of acetic acid and hot plate. 4. Gamitonggyutang extract decreased the effluent of vascular permeability indused by Evans blue at 600mg/kg and 800mg/kg. 5. Gamitonggyutang extract decreased the acute edema indused by Carregennin about 2 and 4 hours but didn't show useful effect. 6. Gamitonggyutang extract decreased the death rate, resulted from the effect of active systemic anaphylaxis reaction indused by CGG, but didn't show useful effect.. 7. Gamitonggyutang extract showed the growth inhibitory effect of each bacterias at $52mg/m{\ell}$. 8. Gamitonggyutang extract suppressed the growth of Streptococcus mutans 10449, and showed the supression of acid fabrication in case of 1:10 more than 1:100.

• 대한한방내과학회지
• /
• 제19권2호
• /
• pp.88-106
• /
• 1998

This study was designed to elucidate the antiinflammatory, cardiovascular, antithrombotic, and analgesic effect of Sambitang. The antiinflammatory effects was measured by the method of carrageenin induced edema, protein leakage test using CMC-pouch, and the effect of Sambitang on the cardiovascular system was observed by the change of flow rate of Ringer solution in the vascular system in the ear of rabbit, and the contraction and dilatation of rat tail artery. Death rate, platelet aggregation, plasma coagulation activity was observed for the measurement of the anticoagurative effect of Sambitang, and the analgesic effect was measured by the acetic acid method and hot plate method. The result was as follows: 1. Sambitang administration, edema and protein leakage was significantly decreased. 2. The drug increased the auricular blood flow in rabbit. 3. The drug relaxed the artery contraction by pretreated norepinephrine in rat. 4. The drug inhibited the death rate of mouse which was led to thromboembo- lism by serotonin and collagen. 5. The drug inhibited the platelet aggregation in rat. 6. The drug prolonged the prothrombin time and activated partial thromboplastin time on the test of plasma coagulation factor activity in rat, but was not valuable. 7. The slight anagesic effect of Sambitang extract was confirmed by the observation of writhing syndrome, paw licking time, and escape time.

• 대한기계학회:학술대회논문집
• /
• 대한기계학회 2001년도 추계학술대회논문집B
• /
• pp.324-329
• /
• 2001

This experimental study concerns the characteristics of a transitional flow in a concentric annulus with a diameter ratio of 0.52, whose outer cylinder is stationary and inner one rotating. The pressure losses and skin-friction coefficients have been measured for the fully developed flow of $0.1\sim0.4%$ aqueous solution of sodium carbomethyl cellulose (CMC), respectively at inner cylinder rotational speed of $0\sim600rpm$. The transitional flow has been examined by the measurement of pressure losses to reveal the relation of the Reynolds and Rossby numbers with the skin-friction coefficients. The present results show that the skin-friction coefficients have the significant relation with the Rossby numbers, only for laminar regime. The occurrence of transition has been checked by the gradient changes of pressure losses and skin-friction coefficients with respect to the Reynolds numbers. The increasing rate of skin-friction coefficients due to the rotation in uniform for laminar flow regime, whereas it is suddenly reduced for transitional flow regime and, then, is gradually declined for turbulent flow regime. Consequently, the critical(axial-flow) Reynolds number decrease as the rotational speed increases. Thus, the rotation of inner cylinder promotes the early occurrence of transition due to the onset of taylor vortices.

• 공업화학
• /
• 제8권1호
• /
• pp.29-38
• /
• 1997

고농축에멀션중합방법을 이용하여 친수성-친유성 고분자복합소재를 합성하였다. w/o 형태의 고농축에멀션의 연속상은 styrene이며, 분산상은 수용성 acrylamide용액으로 분산상의 부피분율이 0.74 이상이다. 중합온도에서 에멀션의 안정성에 미치는 주요 요인들로는 친유성액체와 친수성액체의 물리화학적 특성인 극성, pH, 이온세기 및 계면활성제의 종류와 농도가 있다. 친유성액체와 친수성액체 사이의 계면장력이나 친수성액체와 계면활성제 수용액사이의 계면장력에 있어 계면장력의 값이 큰 경우는 높은 에멀션의 안정성을 나타낸다. 계면활성제의 HLB가 3.0~9.0 경우와 계면활성제의 농도가 CMC가 이상에서 에멀션이 높은 안정성을 나타낸다. 전자현미경을 이용한 조사에 의하며 복합재료는 분산상의 Poly acrylamide입자가 망상구조의 얇은 polystyrene필림에 의해 분리된 구조로 이루어져 있음을 보여주고 있다. 고농축에멀션에서부터합성된 고분자복합재료막은 물-에탄온 혼합물에서 물에 대해서 높은 선택성을 나타내었으며, 또 에탄올의 농도가 증가할수록 막의 선택도는 증가하였으나 투과속도는 감소함을 나타내었다.