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Studies on the Printability Improvement of Hanji by Surface Sizing with Mixed Agents

  • Seo, Seung-Man;Kang, Jin-Ha;Lim, Hyun-A
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.38 no.5 s.118
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    • pp.38-46
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    • 2006
  • Many researches for extensive uses of Hanji have been performed. With the advent of an information-oriented age, the development of Hanji which is printable has been considered as a new field of study. Since Hanji has many drawbacks in comparison with common printing papers, that is, rougher surface, huger absorption of ink and lower physical properties and printabilities. Improving the properties and printabilities of Hanji is therefore the most important work to deal with. This study was conducted to find out useful mixed agents for surface sizing suitable for printable Hanji. Four surface sizing agents (CMC, corn starch, PYA, AKD) were applied for mixture in this study. The physical properties of surface sized Hanji were measured. Results obtained were as follows. Based on designated agents according to concentration, each of the mixed agents was prepared. The kinds of mixture were corn starch (3%) and PVA (5%), corn starch (3%) and AKD (0.1%), corn starch (3%) and CMC (1%), AKD (0.1%) and CMC (1%), AKD (0.1%) and PVA (5%), CMC (1%) and PVA (5%). Each mixed surface sizing agents was included with these ratios (100:0, 90:10, 70:30, 50:50, 30:70, 10:90, 0:100) respectively. All the mixed agents improved the physical properties and printabilities of Hanji. Among them, mixed agent of CMC (1%) and corn starch (3%) with 90:10 ratio is superior to the others for not only smoothness but also ink printability. In view of the result achieved, it is regarded that it can be fit for using Hanji as a printing paper and turned out to be a good contribution to Hanji industry.

Effect of Multilayer Edible Coatings on the Lemon Quality Changes during the Storage (Multilayer 식용코팅의 레몬 저장성에 대한 효과)

  • Choi, Jin Wook;Lee, Seung Ju
    • Food Engineering Progress
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    • v.14 no.1
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    • pp.27-34
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    • 2010
  • Multilayer edible coatings was applied to lemon with beeswax-hydroxypropyl methylcellulose (BW-HPMC), soybean oil-carboxymethyl cellulose (SBO-CMC), and carnaubawax-shellac-locust bean gum (CW-SL-LBG), respectively. The multilayer was composed of two layers of the same material, but the outer layer only contained vitamins C and E as antioxidants. Coating amounts built on lemon peel were measured to be large in the order of CW-SLLBG> BW-HPMC> SBO-CMC. The coated lemons were stored at 30${^{\circ}C}$ for 12 days. CW-SL-LBG showed the least change during the storage in weight loss, rotten rate, firmness, and browning. Whereas SBO-CMC had the least change in pH, soluble solid amount, and titratable acidity. In a sensory test, CW-SL-LBG was evaluated to be the best in the attributes such as spoilage, glossiness, color, firmness, and flavor. Overall CW-SL-LBG was judged to be the best for multilayerd coating with vitamin C and E on lemon.

The Effect of Surfactant on Controlled Release of Amino acids Through Poly(2-Hydroxyethyl Methacrylate) Membrane (Poly(2-Hydroxyethyl Methacrylate)막을 통한 아미노산의 방출 조절에 대한 계면활성제의 효과)

  • Kim Ui-Rak;Jeong Bong-Jin;Lee Myung-Jae;Min Kyung-Sub
    • Journal of the Korean Chemical Society
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    • v.37 no.1
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    • pp.22-35
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    • 1993
  • The transport phenomena of the free amino acids through poly(hydroxyethyl methacrylate)[P(HEMA)] have been investigated with and without various kinds of surfactants solution and in the mixed surfactants solution. Glutamine has the highest diffusivity among 4 amino acids at 1CMC of cetyldimethylethylammonium bromide(CTABr) surfactant. Glutamic acid is not affected by the concentration of CTABr. Methionine and Lysine shows slight decreased diffusivity at 0.5 CMC, but increase its diffusivity at 1CMC and 2CMC due to the structure change of membrane and the viscosity change of surfactant solution. Glutamic acid has the highest diffusivity among four amino acids at sodium dodecyl sulfate(SDS) and Triton X-100 surfactant. In mixed surfactant solution, each amino acids shows high diffusivity through 45% water content membrane at the 0.5 mole fraction of SDS in the SDS/TX-100 surfactant mixtures. It has been found that not only the property of membrane but also the effects of solute-solvent interactions and solvent effect are very important as the permeation of amino acids occurs through P(HEMA) membrane. The diffusivities of free amino acids through membrane depend upon their molecular shape, size and charge.

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Effect of Chicken Manure Compost Application on the Growth of Vegetables and Nutrients Utilization in Upland Soil (계분퇴비 시용이 채소류 생육과 양분이용율에 미치는 영향)

  • Kim, Jong-Gu;Lee, Kyeong-Bo;Lee, Deog-Bae;Lee, Sang-Bok;Kim, Seong-Jo
    • Korean Journal of Soil Science and Fertilizer
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    • v.31 no.2
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    • pp.177-182
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    • 1998
  • To evaluate the effect of chicken manure compost(CMC) application on nutrient utilization and reduction of N fertilizer application for vegetables such of cabbage, reddish, and eggplant, four different application rates of CMC such as 0, 10, 30. $50Mg\;ha^{-1}$ were amended with three different rates of chemical fertilizer of 0, 15, $300kg\;ha^{-1}$. The efficiency of nutrient utilization on CMC were in the order of N, P, K. For each respective nutrient utilization by cabbage, reddish, and eggplant, N were 29%, 20%, 14%; P were 10%,<1%, and <1% ; K were 5%, 22%, 32%. The greater application of CMC, the less the efficiency, while the efficiency of P was increased with increasing application of CMC. The highest efficiency of nutrient utilization was found in $10Mg\;ha^{-1}$. The amounts of reduction of N fertilizer application in soils amended with $10Mg\;ha^{-1}$ of CMC with respect to maintain the normal production of each vegetables observed in this experiment were as follows: $25kg\;ha^{-1}$ and $15kg\;ha^{-1}$ less, and $13kg\;ha^{-1}$ more than the recommended rate for cabbage, eggplant, and reddish, respectively. For elution of available of N by the application of CMC, there was a gradual increase up to 30 day, then gradually decreased. However, there was increase of N eluted in the application of $50Mg\;ha^{-1}$. For soil chemical properties, pH, T-N, OM, and $P_2O_5$ were increased with increased application of CMC, as well as did cations such as K, Ca, and Mg. Yield and glucose of cabbage was significantly increased at the application of $30Mg\;ha^{-1}$ CMC, but content of nitrate in eggplant and raddish was highly increased with increasing application of N fertilizer and CMC. By the way, the yields of cabbage, reddish, and eggplant were slightly decreased with CMC application greater than $50Mg\;ha^{-1}$.

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Basic Studies on the Development of Diet for the Treatment of Obesity I. The Inhibitory Effect of Alginic Acid as a Dietary Fiber on Obesity (비만치료식 개발을 위한 기초연구 1. 식물섬유로서의 알긴산의 비만억제효과)

  • CHOI Jin-Ho;RHIM Chae-Hwan;KIM Jae-Yeun;YANG Jong-Soon;CHOI Jae-Sue;BYUN Dae-Seok
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.19 no.4
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    • pp.303-311
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    • 1986
  • This work was designed as basic studies on the development of diet for the treatment of obesity. The effect of alginic acid which is the major component of brown algae was investigated by comparing with agar, cellulose, carboxymethylcellulose (CMC), chitin, and lignin as dietary fibers. These dietary fibers ($10\%$) supplemented to basic diet were fed ad libitum to Sprague Dawley rat for 4 weeks, and the inhibitory effects on obesity were evaluated by measuring body weight gain and feed efficiency, the content of glucose and cholesterol in serum, lipase activity in serum, lipid content in liver, adipose tissue around epididymis and ovarium, and Lee index etc. Among the inhibitory effect of these dietary fibers on obesity, lignin was the most effective (p<0.001), followed by Na-alginate (p<0.01) for body weight gain, but lignin was the most effective, followed by CMC, and followed by Na-alginate for feed efficiency (p<0.001). In the inhibitory effects on lipid accumulation in liver and adipose tissue around epididymis and ovarium, lignin and Na-alginate group among these dietary fibers were more effective than others, but there was no significant difference between male and female. The inhibitory effect on obesity evaluated by Lee index was effective in the order of Na-alginate>lignin>CMC>chitin>cellulose (p<0.001). The decreasing effects of lipid content in liver by dietary fibers were found in the order of agar>CMC>cellulose>Na-alginate>chitin>lignin (p<0.001). Glucose content in serum was significantly decreased in cases of CMC, lignin and Na-alginate, whereas a slight difference was found in chitin, but cholesterol content in serum was decreased for all dietary fibers examined except cellulose group. The increasing effect of lipase activity in plasma was found in cases of Na-alginate and chitin, while cellulose, CMC and lignin groups were decreased.

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Evaluation on Effectiveness for Preventing Post Surgical Adhesion of Sodium Hyaluronate/Sodium Carboxymethyl Cellulose (HA/CMC) Membrane in Rat Cecum/Peritonium Model (쥐 맹장/복벽 찰과상 모델에서 Sodium Hyaluronate/sodium Carboxymethyl Cellulose 멤브레인의 수술 후 유착방지에 대한 유효성 평가)

  • Lee, Young-Moo;Lee, Young-Woo
    • Membrane Journal
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    • v.15 no.3
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    • pp.213-223
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    • 2005
  • We prepared an anti-adhesion membrane made of sodium hyaluronate/sodium carboxymethylcellulose (HA/CMC) and evaluated its effectiveness for adhesion prevention in a rat model. The anti-adhesion membrane was prepared by lyophilizing HA/CMC solution and cross-linking properly with 1-Ethyl-3-(3-dimethylaminopropyl) carbodiimide (EDAC). In a cecum/abdominal wall abrasion model of Sprague-Dawley rat, cecal serosa and abdominal wall were abraded in $1\times2\;(cm^2)$ with a bone burr after peritoneal midline incision and sutured at 3 points around the injured surface. The denuded cecum was covered with HA/CMC membrane (experimental group), or nothing (control group) and apposed to the abdominal wall. Most of the control group represented 3 or more of adhesion grade at POD 7, 14, 21, and 28, whereas $60\~70\%$ of the experimental group was 2 or less of adhesion grade at 14, 21, and 28. It was similar in the adhesion strength. In a general manner, the adhesion grade and strength showed gradual increasing until POD 14, almost same or a little increasing POD 21, but decreasing POD 28. Also the control group was much higher in adhesion grade, strength, and area than the experimental group. It is expected that the anti-adhesion membrane will have a good clinical result in postoperative adhesion prevention.

Improvement of Cycle Performance of Graphite-Silicon Monoxide Mixture Negative Electrode in Lithium-ion Batteries (흑연과 실리콘 일산화물의 혼합물로 구성된 리튬이온 이차전지용 음극의 사이클 성능개선 연구)

  • Kim, Haebeen;Kim, Tae Hun;Ryu, Ji Heon
    • Journal of the Korean Electrochemical Society
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    • v.22 no.4
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    • pp.155-163
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    • 2019
  • Mixture electrodes of a graphite having a good cycle performance and a silicon monoxide (SiO) having a high capacity are fabricated and their cycle performances are evaluated as negative electrodes for lithium-ion batteries. The electrode prepared by mixing the natural graphite and carbon-coated SiO in a mass ratio of 9:1 shows a reversible capacity of $480mAh\;g^{-1}$, 33% higher than that of graphite. However, the capacity deteriorates continuously upon cycling due to the volume change of silicon monoxide. In this study, the factors that can improve the cycle performance have been discussed through the change in the configurations of the electrode and the electrolyte. The electrode using the carboxymethyl cellulose (CMC) binder shows the best cycle performance compared to the conventional binders. The electrode sing the CMC and styrene-butadiene rubber (SBR) binder not only has almost the similar cycle characteristics with the electrode using the CMC binder but also has the better rate capability. When the fluoroethylene carbonate (FEC) is used as an electrolyte additive, the cycle life is improved. However, the electrolyte with 5 wt% of FEC is appropriate because the rate capability decreases when the content of FEC is increased to 10 wt%. In addition, when the mass loading of the electrode is lowered, the cycle performance is greatly improved. Also, enhanced cycle performance is achieved using the roughened Cu current collector polished by abrasive paper.

Improvement of Dissolution Rate for Zaltoprofen Tablets Using CMC and HPMC (CMC와 HPMC를 이용한 잘토프로펜 정제의 용출률 개선)

  • Park, Hyun-Jin;Hong, Hee-Kyung;Song, Yi-Seul;Hong, Min-Sung;Seo, Han-Sol;Hong, Dong-Hyun;Lee, Dong-Won;Khang, Gil-Son
    • Polymer(Korea)
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    • v.34 no.4
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    • pp.300-305
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    • 2010
  • Zaltoprofen is a propionic acid derivative of non-steroidal anti-inflammatory drugs (NSAIDs) and has been widely used in the treatment of a number of arthritic conditions or lumbago. Zaltoprofen has low water solubility and low bioavailability, therefore great efforts have been devoted to enhance the extent of drug adsorption. In this study, zaltoprofen was formulated into a tablet to enhance the bioavailability and to achieve sustained-release using additives such as lactose monohydrate, carboxymethylcellulose (CMC), hydroxypropylmethylcellulose (HPMC). Fourier transform-infrared (FTIR) and differential scanning calorimeter (DSC) were employed to study the structure and crystallization of zaltoprofen in the tablet with various contents of additives. It was found that additives had interactions with zaltoprofen and inhibited the crystallization of zaltoprofen. Tablets containing low viscosity HPMC showed a higher release than those containing high viscosity HPMC. Also, as the amount of CMC increased zaltoprofen release increased.

Synthesis and Characterization of Interfacial Properties of Sorbitan Laurate Surfactant (Sorbitan Laurate 계면활성제 합성 및 계면 특성에 관한 연구)

  • Lee, Seul;Kim, ByeongJo;Lee, JongGi;Lim, JongChoo
    • Applied Chemistry for Engineering
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    • v.22 no.1
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    • pp.37-44
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    • 2011
  • The critical micelle concentration (CMC) of sorbitan laurate SP 20 surfactant in this paper was near $7.216{\times}10^{-4}mol/L$ and the surface tension at CMC was about 26.0 mN/m, which showed higher CMC and lower surface tension than those of octylphenol ethoxylate octylphenol ethoxylate (OPE) 10 surfactant. Dynamic surface tension measurement using a maximum bubble pressure tensiometer showed that the adsorption rate at the interface between air and surfactant solution was found to be slower with SP 20 surfactant, presumably due to a low mobility of SP 20 surfactant monomer. The contact angle of SP 20 surfactant solution was observed to decrease with an increase in surfactant concentration and showed a larger value than that of OPE 10 surfactant solution. Half-life time for foams generated with 1 wt% surfactant solution was also larger with SP 20 surfactant, which indicated higher foam stability with SP 20 surfactant. Dynamic behavior study reveals that the solubilization of n-decane oil was much lower with SP 20, which is in good agreement with experimental results of foam stability, contact angle and CMC. Dynamic interfacial tension measurement by a spinning drop tensiometer shows that interfacial tensions at equilibrium condition in both systems were almost the same but the time required to reach equilibrium was longer with SP 20.