• The Journal of the Petrological Society of Korea
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• v.22 no.2
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• pp.137-151
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• 2013

This study is focused on element behaviors and mineral compositions of the fault rock developed in Yongdang-ri, Yangbuk-myeon, Gyeongju City, Korea, using XRF, ICP, XRD, and EPMA/BSE in order to better understand the chemical variations in fault rocks during the fault activity, with emphasis on dependence of chemical mobility on mineralogy across the fault zone. As one of the main components of the fault rocks, $SiO_2$ shows the highest content which ranges from 61.6 to 71.0%, and $Al_2O_3$ is also high as having the 10.8~15.8% range. Alkali elements such as $Na_2O$ and $K_2O$ are in the range of 0.22~4.63% and 2.02~4.89%, respectively, and $Fe_2O_3$ is 3.80~12.5%, indicating that there are significant variations within the fault rock. Based on the chemical characteristics in the fault rocks, it is evident that the fault gouge zone is depleted in $Na_2O$, $Al_2O_3$, $K_2O$, $SiO_2$, CaO, Ba and Sr, whereas enriched in $Fe_2O_3$, MgO, MnO, Zr, Hf and Rb relative to the fault breccia zone. Such chemical behaviors are closely related to the difference in the mineral compositions between breccia and gouge zones because the breccia zone consists of the rock-forming minerals including quartz and feldspar, whereas the gouge zone consists of abundant clay minerals such as illite and chlorite. The alteration of the primary minerals leading to the formation of the clay minerals in the fault zone was affected by the hydrothermal fluids involved in fault activity. Taking into account the fact that major, trace and rare earth elements were leached out from the precursor minerals, it is assumed that the element mobility was high during the first stage of the fault activity because the fracture zone is interpreted to have acted as a path of hydrothermal fluids. Moving toward the later stage of fault activity, the center of the fracture zone was transformed into the gouge zone during which the permeability in the fault zone gradually decreased with the formation of clay minerals. Consequently, elements were effectively constrained in the gouge zone mostly filled with authigenic minerals including clay minerals, characterized by the low element mobility.

• Journal of Conservation Science
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• v.25 no.3
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• pp.299-316
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• 2009

The Goryeo roof tiles from the Oegol site in Tangjeong, Asan are classified into three groups in color such as gray, red yellow and gray-yellow groups, respectively. While each group of tiles shows characteristic specific gravity, absorption ratio, LOI and vitrification degree, mineral content and distribution, and chemical composition are generally homogeneous among all groups of roof tiles. Also, all roof tiles and soils from the site show similar geochemical behavior of elements and clay-mineralization degree. This indicates that the soil from the site is probable to be a raw material of the roof tiles. Firing temperature of the roof tiles is estimated as 950 to $1,050^{\circ}C$ for the gray group, 800 to $900^{\circ}C$ for the red yellow group, and 900 to $950^{\circ}C$ for the gray-yellow group. In conclusion, roof tiles from the Oegol site is interpreted to be made of local clay without additive minerals, applying various firing conditions and standardized purifying process of raw clay materials.

• Journal of the Mineralogical Society of Korea
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• v.26 no.2
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• pp.129-138
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• 2013

River bank filtration has been considered as a promising alternative water management scheme, in which groundwater is extracted from an aquifer near a river after infiltration of the river water into the aquifer, thereby improving and maintaining the quality of water recovered. Iron (Fe) associated with sediment in contact with groundwater and infiltrating surface water is an important factor in determining the quality of water recovered from the pumping wells in river bank filtration. This study reports the results of Fe speciation in the aquifer sediment samples collected from different depths at the river bank filtration site in Changwon, studied using four different chemical extraction methods, namely, ferrozine, oxalate, HCl, and DCB methods. Overall, the results show that Fe(II) as well as the total Fe content decreases with depth down to ~20 m and then increases further below. This trend is consistent with the redox characteristics suggested by visual observation. The silt/clay size fraction (${\phi}$ < 62.5 ${\mu}M$) has up to 2~10 times more Fe compared with the sand size fraction (62.5 ${\mu}M$ < ${\phi}$ < 2 mm), depending on the extraction method. Of the four extraction methods, DCB solution extracted the most Fe from the sediment samples. The amounts of Fe extracted by the different extraction methods can be a good indicator of the redox conditions along the depth of the aquifer.

• The Journal of the Acoustical Society of Korea
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• v.26 no.1E
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• pp.33-38
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• 2007

Compressional wave velocity and shear wave velocity were measured for gassy sediments collected from Jinhae Bay, Korea. To distinguish inhomogeneities of gassy sediments, Computed Tomography (CT) was carried out for gassy sediment using CT Scanner. The cored sediments are composed of homogeneous and soft mud (greater than $8{\Phi}$ in mean grain size) containing clay content more than 50%. In depth interval of gassy sediments, compressional wave velocity is significantly decreased from 1480m/s to 1360m/s, indicating that the gas greatly affects compressional wave velocity due to a gas and/or degassing cracks. Shear wave velocity shows a slight increasing pattern from ${\sim}55\;m/s$ in the upper part of the core to ${\sim}58\;m/s$ at 320 cm depth, and then decreases to ${\sim}54\;m/s$ in the lower part of the core containing a small amount of gas. But shear wave velocity in the gassy sediments is slightly greater than that of non-gassy sediments in the upper part of the core. Thus, the Vp/Vs ratio is decreased (from 30 to 25) in gas charged zone. The Vp/Vs ratio is well correlated with shear wave velocity, but no correlation with compressional wave velocity. This suggests that low concentrations of gas have little affects on shear wave velocity. By CT images, the gas in the sediments is mostly concentrated around inner edge of core liner due to a long duration after sediment collection.

• Geomechanics and Engineering
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• v.11 no.2
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• pp.197-209
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• 2016

Clayey rock has large clay mineral content. When in contact with water, this expands considerably and may present a significant hazard to the stability of the rock in geotechnical engineering applications. This is particularly important in the present work, which focused on mitigating some unwelcomed properties of clayey rock. Changes in its physical properties were simulated by subjecting the rock to a low voltage direct current (DC) using copper, steel and aluminum electrodes. The modified mechanism of the coupled electrical and chemical fields acting on the clayey rock was analyzed. It was concluded that the essence of clayey rock electrochemical modification is the electrokinetic effect of the DC field, together with the coupled hydraulic and electrical potential gradients in fine-grained clayey rock, including ion migration, electrophoresis and electro-osmosis. The aluminum cathodes were corroded and generated gibbsite at the anode; the steel and copper cathodes showed no obvious change. The electrical resistivity and uniaxial compressive strength (UCS) of the modified specimens from the anode, intermediate and cathode zones tended to decrease. Samples taken from these zones showed a positive correlation between electric resistivity and UCS.

• Journal of Plant Biology
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• v.14 no.3
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• pp.1-20
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• 1971

Ecological factors limiting Stipa pulchra have been determined in experimental gardens and at several sites in the hills south and east of Monterey, California. The Stipa pulchrafacies of Valley Grassland communities were found to be dominated by that species, though a total of 36 grasses and forbs were collected and identified. Basal area was not large, but aerial cover by Stipa alone averaged over 50 per cent. Across an ecotone between a Stipa association and the California Annual Type a sudden and dramatic change was recorded. Soil measurements there, and in other nearby areas, showed a much higher clay content with more available water and elemental phosphorus at the Stipa sites. Germination of Stipa seeds was high under all laboratory and field conditions, though growth of seeldings was highly variable. Seedlings grown in Stipa woil with an abundance of water were vigorous and reached anthesis the first year. In other soils they grew less, and when grown in competition with Avena fatua they scarcely grew at all. These findings indicate that when established on desirable soils, Stipa competes well and apparently precludes the dominance of Avena fatua and other large annual grasses. On the other hand, because of a lack of vigor in its seedlings, Stipa cannot reinvade the rich more friable soils on which it was once found, and on which it was shown to grow satisfactorily. This supports the contention that Sipa pulchra was the dominant grass through much of the Valley Grassland and Foothill Woodland, but also indicates that well-drained soils and those poor in mineral nutrients probalby never supported such associations.

• The Journal of Engineering Geology
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• v.17 no.1 s.50
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• pp.125-133
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• 2007

The environmental and geotechnical properties are investigated to the 8th landfill area made of only sewage sludge in Nanji-Do. To do this, the soils are sampled in this area, and leaching tests, heavy metal content tests, and so on are performed to research the environmental properties. As the result of heavy metal content tests, Pb, Zn, Cu, Ni, Cd and Cr were leached from the sewage sludge. Because the leaching concentration of Cu is more than the standard value of California state, Cu content have to bring down during the recycling of the sewage sludge. Meanwhile, a series of tests concerning specific gravity, liquid and plastic limits, compaction, permeability and shear strength is performed to research the geotechnical properties. The sewage sludge is consisted of sand, silt and clay, and is classified into non-organic silt or organic clay with 42.3% of plastic index. As the result of compaction test, it is expected that the compaction effect according to variation of water contents is low relatively because the dry unit weight is low and the curve of compaction forms flatness. Also, as the result of direct shear tests, the cohesion is $0.058kg/cm^2$, and the internal friction angle is $14^{\circ}$. Taking everything into consideration, the various problems are happening in case of recycling the sludge like the cover layer of landfill and so on because the compaction is bad, and the shear strength is low. Also, it is expected that the ground water pollution caused by leaching the heavy metal into the sludge. To do recycling the sewage sludge in this site, supplementary and treatment programs should be prepared.

• Korean Journal of Soil Science and Fertilizer
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• v.34 no.4
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• pp.237-244
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• 2001

Investigation on the surface charge properties of some Korean arable soils was performed by ion adsorption technique with two kinds of indifferent ion ($Na^+$ and $K^+$) at the range of pH 3 to 9 in bulk solution. The contribution of soil components(organic matter, oxides and clay mineral) on the surface charge density was determined at two soil depth with different solid particle composition When the pH of solution increased, the negative charge of soil surface was increased among the all soils, but positive charge were not appeared above pH 6. apparently. The magnitude of surface charge density measured by NaCl adsorption method showed ra nges of $0.01{\sim}2.84cmol_c{\cdot}kg^{-1}$ and $7.41{\sim}12.20cmol_c{\cdot}kg^{-1}$ at pH 3 and pH 9, respectively. Ion adsorption method using KCl as index ion overestimated than the method using NaCl as index ion. The content of organic matter is the strongest factor on the value of dCEC/dpH.

• Journal of the Mineralogical Society of Korea
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• v.19 no.4 s.50
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• pp.291-300
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• 2006

This study has been carried out to reveal the mineralogical compositions, the concentrations of heavy metals, and related factors in the sediments of the Kumho River which is the main tributary of the Nakdong River. Even though this river flows in a short distance, it runs through different geology and industrial areas and can be a good candidate to study different geological and anthropogenic factors affecting the concentrations of heavy metals in the sediment. The major rock-forming minerals were quartz and albite. Minor amount of orthoclase, microcline, and amphybole were also identified. Clay minerals including illite, chlorite, kaolinite were associated with those minerals. In the downstream, no noticeable changes in species and amount of minerals were observed, indicating there is almost no influence on the mineralogical compositions from rock types. The concentrations of heavy metals in the sediments are in the order of Zn > Pb > Cu > Ni > Cr > Co > Cd. Following the downstream, the concentrations of heavy metals generally increase, except Pb. The regional increase of the heavy metal content is well correlated with the location of the tributary. Without changes in mineral compositions, the main factors controlling the heavy metal contents are the locations of pollutant sources. Except Pb and Ni, most of the concentrations of heavy metals were thought to be enriched by the past pollutant sources.

• Journal of the Korean GEO-environmental Society
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• v.11 no.4
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• pp.13-18
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• 2010

The present study was undertaken to investigate the characteristic of suspended matter in soils of Imha-Dam area by turbidity. Soil sampling was conducted at 5 points of Yeongyang (Turbid area) and 2 points of Cheongsong (Clean area). Experimental analysis was conducted using those samples. The pH of water in the soils at turbid area was higher than that of clean area. X-ray diffraction analysis showed that every sample consists in mainly quartz, illite and feldspar before precipitation. After precipitation for 3 days, the content of quartz and feldspar was decreased and the content of illite was increased at turbid area. The soil of Sinheung (St. 6) at clean area was analyzed only illite. SEM-EDS analysis showed the much content of $SiO_2$ as to every sample before precipitation, but $K_2O$, MgO, $Al_2O_3$, CaO and $Fe2O_3$ with illite was increased after precipitation for 3 days as to every sample. Experimental results exhibited that the major mineral of turbid water was illite at turbid area and clean area.