• Title/Summary/Keyword: chromium trivalent

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Chromium concentration and half-life in rats biological samples after intravenous administration of soluble trivalent and hexavalent chromium compounds (흰쥐에 정맥 주사한 수용성 크롬의 분포 및 배설)

  • Kim, Yong-Lae;Kim, Chy-Nyon;Roh, Jaehoon
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.11 no.1
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    • pp.9-16
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    • 2001
  • Chromium exposure can be in the forms of environmental pollution and occupational exposure. The harmful effects of chromium on the body greatly differ depending on its valence or solubility. Accordingly, the recommended permissible exposure limit for each chromium compound is different. This study investigated the increase or decrease of distribution and excretion of total chromium exposed simultaneously the soluble Cr+6 and Cr+3 compounds. There were no difference of total chromium concentration in plasma, red bloods cells, urine, organs between simultaneously injected and individually injected soluble Cr+6 and Cr+3 compound. The chromium clearances in urine also showed that there were two phases in the two groups. In the first phase, biological half lives of the total chromium of the two groups have been similar within 24 hr., but in the second phase, biological half life of the group injected simultaneously was 62.7 hr. and was less than that of the other group's 188.3 hr. The average concentration of total chromium in plasma was same with the control, and that of RBCs was $0.218nmol/m{\ell}$ and was slightly increased in comparison with $0.121nmol/m{\ell}$ of the control, which was not statistically significant. As a result, there were no differences of distribution and excretion of chromium between the group exposed simultaneously and the other group exposed separately the soluble Cr+6 and Cr+3 compounds. The biological half life of chromium of the former group in urine was less than that of the other group.

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Protective Effect of Korean Red Ginseng Against Dichromate Toxicity

  • Kim, Eun;Hyun, Hak-Chul;Na, Ki-jung
    • Proceedings of the Ginseng society Conference
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    • 1990.06a
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    • pp.132-136
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    • 1990
  • The metabolic disturbance and nephrotoxicity induced by sodium dichromate (20 mg/kg, SC) have been diminished by the administration of Korean red ginseng extract (100 mg/kg, PO). Red ginseng has a powerful potency on the blood urea nitrogen (BUN) increment shown in the early 2h after dichromate intoxication. It normalized the dichromate induced hepatic glycogenolysis. The effect of red ginseng on dichromate induced nephrotoxicity was investigated by hematological analysis, and urinalysis. Ginseng treatment significantly reduced the increases in the urinary excretion of protein and glucose. These effects were dose dependent. Ginseng protected the accumulation of BUN and cretonne in the blood, caused by dichromate intoxication. Unlike CaEDTA, ginseng did not change the urinary excretion chromium. And it could not convert htxavalent chromium to trivalent chromium. These results suggest that ginseng treatment is effective in decreasing the metabolic disturbance, one of the earliest signs of dichromate toxicity, resulting in the protective effect of dichromate induced renal damage.

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Efficacy of Cr (III) Supplementation on Growth, Carcass Composition, Blood Metabolites, and Endocrine Parameters in Finishing Pigs

  • Wang, M.Q.;He, Y.D.;Lindemann, M.D.;Jiang, Z.G.
    • Asian-Australasian Journal of Animal Sciences
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    • v.22 no.10
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    • pp.1414-1419
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    • 2009
  • The study was conducted to evaluate the effects of trivalent chromium from different sources on growth, carcass composition, and serum parameters in finishing pigs. Ninety-six crossbred pigs with an initial average body weight of 65.57${\pm}$1.05 kg were blocked by body weight and randomly assigned to four treatments with three replicates. Pigs were offered one of four diets including a control diet or the control diet supplemented with 200 ${\mu}g/kg$ chromium from either chromium chloride ($CrCl_{3}$), chromium picolinate (CrPic) or chromium nanocomposite (CrNano) for 40 days. After completion of the feeding trial, eight pigs from each treatment were selected to collect blood samples, and slaughtered to measure carcass composition. The results showed that supplemental chromium had no significant effect on growth performance, while CrNano increased carcass lean proportion and loin Longissimus muscle area (p<0.05), and decreased carcass fat proportion and 10th rib backfat depth (p<0.05). CrPic supplementation also resulted in lower fat proportion and larger Longissimus muscle area (p<0.05). The addition of Cr from CrNano or CrPic decreased serum glucose (p<0.05) and increased concentrations of total protein and free fat acid in serum (p<0.05). Serum urea nitrogen, triglyceride and cholesterol were decreased (p<0.05), and serum high density lipoprotein and lipase activity were increased (p<0.05) with the supplementation of CrNano. Serum insulin was decreased (p<0.05) by supplemental Cr from CrNano or CrPic, and serum insulin-like growth factor I was increased significantly in the CrNano treated group. These results suggest that chromium nanocomposite has higher efficacy on carcass composition in pigs compared to the traditional chromium sources.

Effects of pH and temperature on deposition behavior of black trivalent chromium deposition (흑색 3가크롬도금의 전착거동에 미치는 pH 와 온도의 영향)

  • Kim, Ji-Hyeon;Lee, Gyu-Hwan;U, Chang-Ho
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2009.05a
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    • pp.141-141
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    • 2009
  • 흑색 3가크롬용액을 최적의 전착조건을 찾기 위해서 pH와 온도의 변화에 따란 Hull-cell test, 두께측정, 분극실험을 실시하였다. 온도가 올라갈수록, pH가 낮을수록 도금층의 두께가 두꺼워졌으나, 온도 $40^{\circ}C$, pH 3.4-3.8일때 균일한 도금층을 얻을 수 있었다.

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Investigation on the Effect of Complexing Agents and Organic Additives in Trivalent Chromium Electroplating (3가크롬 도금에서 착화제 및 유기첨가제의 영향 연구)

  • Kim, Dong-Su;Lee, Ju-Yeol;Kim, Man;Gwon, Sik-Cheol
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2007.11a
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    • pp.81-82
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    • 2007
  • 3가크롬 도금액은 크롬원 (황화물계 또는 염화물계), 착화제, 완충제, 전도보조제, 산화방지제, 유기첨가제등으로 구성되어 있으며, 특히 착화제와 유기첨가제가 용액의 안정성 및 균일전착성에 미치는 영향이 크다고 보고되고 있다. 본 연구에서는 카르복시기의 작용기를 갖는 유기산을 착화제로 사용하고, 다양한 유/무기 첨가제의 조합 및 첨가량을 조절하여 크롬의 전착특성을 고찰하였다.

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Reduction of Hexavalent Chromium by Escherichia coli ATCC 33456 in Batch and Continuous Cultures

  • Bae, Woo-Chul;Kang, Tae-Gu;Kang, In-Kyong;Won, You-Jung;Jeong, Byeong-Chul
    • Journal of Microbiology
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    • v.38 no.1
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    • pp.36-39
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    • 2000
  • Toxic hexavalent chromium, Cr(VI), was reduced to a less toxic trivalent chromium form by E. coli ATCC 33456. The suitable electron donor for Cr(VI) reduction was glucose. E. coli ATCC 33456 was more resistant to metal cations than other reported Cr(VI) reducing microorganisms. Cell growth was inhibited by the presence of Cr(VI) in a liquid medium and Cr(VI) reduction accompanied cell growth. With a hydraulic retention time of 20 h, Cr(VI) reducing efficiency was 100% to 84% when Cr(VI) concentration in the influent was in the range of 10 to 40 mg L$\^$-1/. Specific rate of Cr(VI) reduction was 2.41 mg Cr(VI) g DCW$\^$-1/ h$\^$-1/ when 40 mg L$\^$-1/ of Cr(VI) influent was used. This result suggested the potential application of E. coli ATCC 33456 for the detoxification of Cr(VI) in Cr(VI) contaminated wastewater.

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