• Journal of Welding and Joining
• /
• 제23권2호
• /
• pp.75-80
• /
• 2005

The effect of chemical constituents of $(Cr,\;Fe)_7C_3$ carbide phase on its hardness in the chromium-carbide type Cr white iron hardfacing weld deposits has been investigated. In order to examine $(Cr,\;Fe)_7C_3$ carbide phase, a series of filler metals with varying chromium contents was used. The alloys were deposited once or twice on a mild steel plate using the self?shielding flux cored arc welding process. The hardness of $(Cr,\;Fe)_7C_3$ carbide phase was measured by the micro-Vickers hardness test. It was shown that hardness of $(Cr,\;Fe)_7C_3$ carbide phase increased with increasing Cr content in $(Cr,\;Fe)_7C_3$ carbide phase. This behavior of the hardness of $(Cr,\;Fe)_7C_3$ carbide phase was explained by the types of chemical bonds that hold atoms together in $(Cr,\;Fe)_7C_3$ carbide phase.

• Journal of Welding and Joining
• /
• 제16권2호
• /
• pp.64-72
• /
• 1998

This study aims a investigating the effect of volume fraction of chromium carbide phase(VFC) of hardfaced iron/chromium alloys on fracture toughness. The alloys were deposited twice on a mild steel plate using self-shielding flux cored arc welding process. In order to examine VFC effect, different VFC (0.28∼0.62) were employed by changing the Cr and C content, while the ratio of Cr/C was fixed in the range of 5.7∼6.6. Fracture toughness was constant as increasing VFC because fracture surface was developed in the eutectic phase which was growing parallel with introduced sharp notch in the hypoeutectic alloys, but fracture toughness did not decreased in spite of increasing volume fraction of coarse primary chromium carbide phase which was easily craced at the low stress because the growth direction of chromium carbide phase were more irregular as increasing VFC in the hypereutectic alloys.

• 한국재료학회:학술대회논문집
• /
• 한국재료학회 1996년도 재료학회 추계학술발표회
• /
• pp.84-84
• /
• 1996

• Journal of Welding and Joining
• /
• 제16권1호
• /
• pp.125-133
• /
• 1998

The effect of volume fraction of Cr carbide phase (Cr CVF) on the low stress abrasion resistance in the chromium-carbide-type high Cr white iron hardfacing weld deposits has been investigated. In order to examine Cr CVF, a series of alloys with varying Cr CVF by changing chromium and carbon contents and the ratio of Cr/C were employed. The alloys were deposited once or twice on a mild steel plate using the self-shielding flux cored arc welding process. The low stress abrasion resistance of the alloys against sands was measured by the Dry Sand/Rubber Wheel Abrasion Test (RWAT). It was shown that hardness and abrasion resistance increased with increasing Cr CVF within the whole test range (Cr CVF : 0.23-0.64). Both primary Cr carbide and eutectic Cr carbide were particularly effective in resisting wear due to their high hardness.

• 한국생산제조학회지
• /
• 제18권5호
• /
• pp.469-476
• /
• 2009

Hard facing overlay welding in high chromium carbide is a representative way of extending the fatigue life or recompensing damage, because workpiece surface is uniformly overlay-welded by alloy material. In general, grinding process is currently used for finish due to hardness of weld material. The development of tool material, such as PCBN, has made it possible to use turning instead of grinding. There are many advantages of hard Owning, as lower equipment costs, shorter setup time, fewer process steps, higher material removal rate, better surface integrity and the elimination of cutting fluid. In this paper, machining characteristics and cutting performance are examined to investigate turning possibility of overly welding in high chromium carbide.

• 한국표면공학회지
• /
• 제23권1호
• /
• pp.16-26
• /
• 1990

The standrd electrolyte for the electrodeposition of chromium were preparwith reagent grade chromic acid(200g/L), sulfuric acid(pH=1.8)and oxalic acalic acid(640g/L)as additive. Carbon content in chromium plating varied about2.0-3.8 wt% with current density and temperatures of the bath. The hardeness of chromium platings incresed with increasing the annealing temperatures and showed maximum value of about Hv 1700 after annealing at$ 700^{\circ}C$for 60min. But, decreased it as annealing at above $700^{\circ}C$. The reason for varing thee hardness of chromium codeposited with carbon gradually foumed chromium carbide(Cr7C3), but that changed to Cr23C6 as annealing temperature at above $^700{\circ}C$. The X-ray diffraction pattern indicated that chromium carbides, such as Cr7C3 or Cr3C2, formed at formed at above $300^{\circ}C$. titanium coating sputtered on the on surface of chromium plating had performed and determined the hardness after annealing at 500, 600, $700^{\circ}C$ for 60min. the maximum hardeness was about Hv 2400 as annealing at $700^{\circ}C$. The titanium carbide formed in layer was identified by X-ray diffraction. It was confirmed that chromium and titanium carbide has effect of increasing the hardness.

• 한국재료학회지
• /
• 제28권7호
• /
• pp.423-427
• /
• 2018

For diamond/metal composites it is better to use diamond particles coated with metal carbide because of improved wettability between the diamond particles and the matrix. In this study, the coating of diamond particles with a chromium carbide layer is investigated. On heating diamond and chromium powders at $800{\sim}900^{\circ}C$ in molten salts of LiCl, KCl, $CaCl_2$, the diamond particles are coated with $Cr_7C_3$. The surfaces of the diamond powders are analyzed using X-ray diffraction and scanning electron microscopy. The average thickness of the $Cr_7C_3$ coating layers is calculated from the result of the particle size analysis. By using the molten salt method, the $Cr_7C_3$ coating layer is uniformly formed on the diamond particles at a relatively low temperature at which the graphitization of the diamond particles is avoided. Treatment temperatures are lower than those in the previously proposed methods. The coated layer is thickened with an increase in heating temperature up to $900^{\circ}C$. The coating reaction of the diamond particles with chromium carbide is much more rapid in $LiCl-KCl-CaCl_2$ molten salts than with the molten salts of $KCl-CaCl_2$.

• 한국표면공학회지
• /
• 제44권1호
• /
• pp.7-12
• /
• 2011

The effect of organic additives, polyethylene glycol (PEG), on the trivalent chromium electroplating was analysed in the view point of current efficiency, solution stability and metallurgical structure. It was measured that PEG-containing trivalent chromium solution had about 10% higher current efficiency than pure solution and controlled the micro-crack density of electrodeposits. PEG exhibited profound effect on the solution stability by reducing the consumption rate of formic acid which acts as a complexant to lower the activation energy required for electrochemical reduction of trivalent chromium ions. It was also revealed that the formation of chromium carbide layer was facilitated in the presence of polyethylene glycol, which meant easier electrochemical codeposition of chromium and carbon, not single chromium deposition. Trivalent chromium layer formed from PEG-containing solution was amorphous with local nano-crystalline particles, which were prominently developed on the entire surface after non-oxidative heat treatment.

• Journal of Welding and Joining
• /
• 제16권2호
• /
• pp.73-83
• /
• 1998

This study investigated the relationships between the microstructure and the wear resistance of hardfaced iron/chromium alloys to examine the low stress abrasive wear mechanism. The effects of volume fraction of reinforcing phases(chromium carbide and eutectic phase) were studied. The alloys were deposited once or twice on a mild steel plate using a self-shielding flux cored arc welding process. The low stress abrasion resistance of he alloys against dry sands was measured by the Dry Sand/Ruber Wheel Abrasion Tester (RWAT). The wear resistance of hypoeutectic alloys, below 0.36 volume fraction of chromium-carbide phase (VFC), behaved as Equal Pressure Mode (EPM) for the inverse rule of mixture whereas the wear resistance of hypereutectic alloys, above 0.36 VFC, represented Equal Wear Mode (EWM) for the linear rule of mixture.

• 대한용접접합학회:학술대회논문집
• /
• 대한용접접합학회 2005년도 춘계학술발표대회 개요집
• /
• pp.48-50
• /
• 2005

Advanced hard materials based on diamond are in common use. In this study our main goal was employed to analyze, the mechanisms for the rich phases and chromium carbide, interface of a diamond grits brazed to a Ni-based brazing filler metal matrix. When Ni-7Cr-3Fe-3B-4Si (wt. %) was utilized as the brazing alloy, an isothermal holding resulted in the various products(Ni-rich/Cr-rich domains, carbide). According to these results, the chemical compounds and chromium carbides products is considered to play an important role in brazing temperature and time. Especially chromium carbide has an influence on brazing junction properties.