• Title/Summary/Keyword: chlorinated polyethylene(CPE)

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A Study on Thermal Stability of Chlorinated Polyethylene (함염소 폴리에틸렌의 열안정성에 관한 연구)

  • Seul S. D.;Lee N. W.
    • Journal of the Korean Institute of Gas
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    • v.1 no.1
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    • pp.120-126
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    • 1997
  • The thermal decomposition of low density polyethylene(LDPE) and $25\%{\~}48\%$ chlorinated polyethylene(CPE) were studied using a dynamic thermogravimetry in the stream of nitrogen gas with 20ml/min. The mathematic method, differential (Friedman) and Integral (Ozawa) method were used to obtain value of activation energy of decomposition energy on the reaction. The activation energies evaluated by the above methods agree with each other very well. The maximum average activation energy calculated was 71.71kcal/mol. The thermal decomposition of LDPE and CPE were considered to be carried out by main chain scission and the thermogravimetric trace curve agree with the theoretical equation.

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Flame Retardance and Thermal Resistance of CPE Rubber Compound Containing a Phosphoric Ester Flame Retardant BDPDH (인산 에스테르게 난연제 BDPDH를 첨가한 CPE 고무재료의 난연성 및 내열성)

  • Park, Hyun-Ho;Lee, Chang-Seop
    • Elastomers and Composites
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    • v.38 no.1
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    • pp.72-80
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    • 2003
  • Phosphoric ester compound was employed as thermal resistant and flame retardant for chlorinated polyethylene(CPE) rubber material which is used to prepare automotive oil cooler hose. Cure characteristics, physical properties, thermal resistance, and flame retardation of CPE rubber compounds were investigated. CPE rubber which has excellent properties such as cold resistance and chemical corrosion resistance, and is inexpensive in price than existing ethyleneacrylate rubber(EAR) was used to prepare a rubber compound useful for hose. A non-halogen flame retarding agent N,N'-bis- (diphenylphosphoro) diaminohexane(BDPDH), which is condensed phosphoric ester, was synthesized and it was mixed to CPE rubber material with the range of $0{\sim}30 phr$. From the test results, rheological properties, heat resistance, and flame retardance of CPE rubber compounds were found out to be much increased. The optimum content of BDPDH to rubber which gives maximum effect on thermal resistance and flame retardation, within the range of tolerable specification for rubber materials, was determined to be 20 phr.

Development of the EM Wave Absorber for Preventing RFID Reader Interference in UHF band (UHF대역 RFID 리더 간섭방지용 전파흡수체 개발)

  • Park, Soo-Hoon;Choi, Chang-Mook;Song, Young-Man;Kim, Dong-Il;Jung, Ji-Won;Kim, Ki-Man
    • Journal of Navigation and Port Research
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    • v.32 no.5
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    • pp.349-353
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    • 2008
  • In this paper, the EM wave absorber was designed and fabricated for preventing Reader Interference of RFID communication system in UHF band We fabricated several samples in different composition ratios of Amorphous and CPE(Chlorinated Polyethylene). Absorption abilities were simulated in accordance with different thicknesses of the prepared absorbers and changed complex relative permittivity and permeability due to composition ratio. The mixing ratio of Amorphous and CPE was searched as 80 : 20 wt.% by experiments and simulation. Then the EM wave absorber was fabricated and tested using the simulated data. As a result, the developed EM wave absorber has a thickness of 4 mm and absorption ability was over 20 dB in frequency range of $860\;MHz{\sim}960\;MHz$. Therefore, it was confirmed that the developed absorber can be used for suppressing RFID reader interference in UHF band.

Development of EM Wave Absorber for Countermeasure against EM Wave Environment of 2.4 GHz Wireless LAN (2.4 GHz 무선LAN 전자파 환경대책용 전파흡수체 개발)

  • Yoon, Sang-Gil;Kim, Dae-Hun;Park, Soo-Hoon;Kim, Dong-Il
    • Journal of Navigation and Port Research
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    • v.33 no.3
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    • pp.193-197
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    • 2009
  • In this paper, the EM wave absorber was designed and fabricated for improvement of Wireless LAN environment at 2.4 GHz. We fabricated several samples in different composition ratios of Sendust and CPE(Chlorinated Polyethylene). Absorption abilities were simulated in accordance with different thicknesses of the prepared absorbers and changed complex relative permittivity and permeability due to composition ratio. The mixing ratio of Sendust and CPE was searched as 80: 20 wt.% by experiments and simulation Then the EM wave absorber was fabricated and tested using the simulated data. As a result, the EM wave absorber was fabricated based on simulated data. Simulated and measured results agreed well. As a result, the developed EM wave absorber with thickness of 3.25 mm has absorption ability of 19 dB at 2.4 GHz.

Development of EM Wave Absorber for Port Logistics RFID System by Using Amorphous Metal Powder (Amorphous Metal Powder를 이용한 항만 물류 RFID 시스템용 전파흡수체 개발)

  • Choi, Dong-Soo;Yoo, Gun-Suk;Kim, Dong-Il
    • Journal of Navigation and Port Research
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    • v.34 no.1
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    • pp.27-31
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    • 2010
  • In this paper, we developed an EM wave absorber having the absorption ability of more than 15 dB for port logistics RFID system by using AMP. Firstly, we fabricated EM wave absorber by using AMP and CPE(Chlorinated Polyethylene) with different composition ratios 80:20 wt.% and 85:15 wt.%. Secondly, we designed the optimum EM wave absorber using the calculated material constants obtained from measured input impedance of the samples. Therefore, EM wave absorber with absorption ability of 17.5 dB at 433 MHz when composition ratio of AMP:CPE=85:15 wt.% and thickness of 5.5 mm.

Development of the EM Wave Absorber Using MnZn-Ferrite and Sendust for Wireless LAN at 2.4 GHz (MnZn-Ferrite와 Sendust를 이용한 2.4 GHz 무선LAN용 전파흡수체 개발)

  • Lee, Dae-Hee;Choi, Chang-Mook;Choi, Dong-Han;Kim, Dong-Il
    • Journal of Navigation and Port Research
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    • v.31 no.10
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    • pp.865-868
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    • 2007
  • Recently, wireless LANs are often applied in home or office because of its various of convenience. Frequency range of wireless LANs specified by IEEE 802.11b is at 2.4 GHz. The bluetooth, the microwave oven, and the PDA(Personal Digital Assistants) uses, however, the same frequency band. So problems will be produced in these environments, such as multi-pass interference and system-to-system interference. These problems can be eliminated by using EM wave absorber. In this paper, we designed and fabricated EM wave absorber using MnZn-Ferrite, Sendust, and CPE( Chlorinated Polyethylene). The EM wave absorber with the ratio of material (MnZn-Ferrite : Sendust : CPE = 64 : 16 : 20 wt.%) has thickness of 3.7 mm and absorption ability more than 17 dB at 2.4 GHz.

A Study on Development of EM Wave Absorber Using TiO2 for Automotive Radar in Cars

  • Choi, Chang-Mook;Kim, Dong-Il
    • Journal of electromagnetic engineering and science
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    • v.8 no.3
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    • pp.110-113
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    • 2008
  • In this paper, we designed and fabricated an electromagnetic(EM) wave absorber for automotive radar in cars using $TiO_2$ as a dielectric material and chlorinated polyethylene(CPE) as a binder. First of all, we confirmed that the optimum composition ratio of $TiO_2$ was about 70 wt.%. The complex relative permittivity of a sample containing $TiO_2$: CPE=70:30 wt.% was calculated from S-parameter. The EM wave absorption abilities were simulated for the EM wave absorbers of different thickness using the calculated relative permittivity, and the EM wave absorber was manufactured based on the simulated design. A comparison of simulated and measured results is in good agreement. Measurement shows that a 1.85 mm thick absorber has absorption ability higher than 20 dB in the frequency range of $76{\sim}77$ GHz for automotive radars.

UHF 대역 RFID 리더 간섭방지용 전파흡수체 개발

  • Park, Su-Hun;Choe, Chang-Muk;Song, Yeong-Man;Kim, Dong-Il
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2007.12a
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    • pp.14-16
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    • 2007
  • 본 논문에서는 UHF대역 RFID 통신 시스템 간에 발생하는 리더 간섭을 방지하기 위한 전파흡수체를 설계 및 제작하였다. 먼저 자성손실 재료인 Amorphous와 지지재인 CPE(Chlorinated Polyethylene)를 이용하여 조성비별 전파흡수체 샘플을 제작하였고, 이 전파흡수체 샘플로부터 구한 재료정수를 이용하여 시뮬레이션을 한 결과 최적의 조성비가 Amorphous: CPE = 80 : 20 wt.% 임을 확인하였다. 그리고 시뮬레이션 결과를 토대로 전파흡수체를 실제작하여 전파흡수능을 비교 ${\cdot}$ 분석하였다. 그 결과 Amorphous : CPE = 80 : 20 wt.%의 조성비 일 때, 두께 4mm 의 전파 흡수체가 860 MHz ${\sim}$ 960 MHz의 주파수 범위에서 전파흡수능 20 dB 이상의 특성을 얻음으로써 UHF대역의 RFID 리더 간섭을 억제할 수 있음을 확인하였다.

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A Study on the EM Wave Absorber for the Electromagnetic Environment of Indoor Wireless LAN (실내 무선 LAN 전자파 환경 대책용 전파 흡수체에 관한 연구)

  • Yoon, Sang-Gil;Kim, Dong-Il;Lee, Dae-Hee;Choi, Chang-Mook
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.18 no.11
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    • pp.1224-1230
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    • 2007
  • Recently, wireless LAN are often applied in home or office because of its various of convenience. Frequency rage of wireless LAN specified by IEEE 802.11a is at 5.2 GHz and IEEE 802.11b is 2.4 GHz. But in offices with wireless LAN devices, reflection of waves against walls, ceilings, floors and desks made of metal creates multipath problems that reduce communication speed and lose data. These problems can be solved by using EM wave absorber. In this paper, we designed and fabricated EM wave absorbers using MnZn-ferrite, sendust, carbon and CPE(Chlorinated Polyethylene). The EM wave absorber with the ratio of MnZn-Ferrite : sendust : CPE=64 : 16 : 20 wt.% has thickness of 3.7 mm and absorption ability more than 17 dB at 2.4 GHz and the EM wave absorber with the ratio of MnZn-ferrite : carbon : CPE=40 : 15 : 45 wt.% has thickness of 3.8 mm and absorption ability more than 23 dB at 5.2 GHz.

Design and Fabrication of the EM Wave Absorber with Excellent Characteristics for ETC System

  • Kim, Dong-Il;Choi, Dong-Soo;Choi, Dong-Han;Kim, Do-Yeol
    • Journal of electromagnetic engineering and science
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    • v.12 no.1
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    • pp.20-25
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    • 2012
  • In this paper, the EM wave absorber for ETC system was designed and fabricated. We fabricated several samples in different composition ratios of flaked sendust and CPE(Chlorinated Polyethylene). Absorption abilities were simulated in accordance with different thicknesses of the prepared absorbers and changed complex relative permittivity and permeability according to composition ratio. The optimized mixing ratio of flaked sendust and CPE was found as 60 : 40 wt.% by experiments and simulation. Then the EM wave absorber was fabricated and tested using the simulated data. As a result, the developed EM wave absorber has the thickness of 2.75 mm and absorption ability was 22.5 dB in the case of normal incidence at 5.8 GHz. Therefore, it was confirmed that the newly developed absorber can be used for ETC system.