• Journal of the Korean Society of Safety
• /
• v.23 no.4
• /
• pp.59-66
• /
• 2008

Recently, the deterioration of reinforced concrete structures, primarily due to corrosion of steel reinforcement, has become a major concern. Chloride-induced deterioration is the most important deterioration phenomenon in reinforced concrete structures in harsh environments. For the realistic prediction of chloride penetration into concrete, a mathematical model was developed in which the effects of diffusion, chloride binding and convection due to water movement can be taken into account. The aim of this research was to reach a better understanding on the physical mechanisms underlying the deterioration process of reinforced concrete associated with chloride-induced corrosion and to propose a reliable method for estimating these effects. Chloride concentrations coming from de-icing salts are significantly influenced by the exposure conditions such as salt usage, ambient temperature and repeated wet-dry cycles.

• Corrosion Science and Technology
• /
• v.11 no.5
• /
• pp.157-164
• /
• 2012

In first experiment series, this paper is devoted for examining progress of reinforcement corrosion due to carbonation in concrete and to quantify uncarbonation depth to protect reinforcement from corroding. The tolerance of cover depth should be considered in order to prevent carbonation-induced corrosion. From the relationship between the weight loss of reinforcement and corrosion current density for a given time, therefore, the tolerance of cover depth to prevent carbonation-induced corrosion is computed. It is observed that corrosion occurs when the distance between carbonation front and reinforcement surface (uncarbonated depth) is smaller than 5 mm.As a secondary purpose of this study, it is investigated to examine the interaction between carbonation and chloride penetration and their effects on concrete. This was examined experimentally under various boundary conditions. For concrete under the double condition, the risk of deterioration due to carbonation was not severe. However, it was found that the carbonation of concrete could significantly accelerate chloride penetration. As a result, chloride penetration in combination with carbonation is a serious cause of deterioration of concrete.

• Journal of the Korea Concrete Institute
• /
• v.15 no.6
• /
• pp.902-912
• /
• 2003

The most common deteriorating processes of concrete structures are carbonation and chloride ion ingress. Many concrete structures have been suffered from chloride ions diffusion or carbonation induced reinforcement corrosion damage and many studies have been done on it. However, those studies were confined mostly to the single deterioration of carbonation or chloride attack only, although actual environment is rather of combined conditions. In case of many in-situ concrete structures, deterioration happened more for the case of combined attack than the single case of carbonation or chloride attack. In this paper, chloride profiles of carbonated concrete is predicted by considering two layer composite model, which is based on Fick's 2nd law. From the experimental result on combined deterioration of chloride and carbonation, it was examined that high chloride concentration was built up to 3∼5 mm over depth from carbonation depth. The analytical modeling of chloride diffusion was suggested to depict the relative influence of the carbonation depth. The diffusion coefficients of carbonation concrete and uncarbonated concrete with elapsed time were considered in this modeling.

• Structural Engineering and Mechanics
• /
• v.84 no.6
• /
• pp.831-849
• /
• 2022

One of the most prevalent causes of reinforced concrete (RC) structural deterioration is chloride-induced corrosion. This paper aims to provide a comprehensive insight into the environmental effect of RC's chloride ingress process. The first step is to investigate how relative humidity, temperature, and wind influence chloride ingress into concrete. The probability of initiation time of chloride-induced corrosion is predicted using a probabilistic model that considers these aspects. Parametric analysis is conducted on several factors impacting the corrosion process, including the depth of concrete cover, surface chloride concentration, relative humidity, and temperature to expose environmental features. According to the findings, environmental factors such as surface chloride concentration, relative humidity and temperature substantially impact on the time to corrosion initiation. The long- and short-distance impacts are also examined. The meteorological data from the National Meteorological Center of China are collected and used to analyze the environmental characteristics of the chloride ingress issue for structures along China's coastline. Finally, various recommendations are made for improving durability design against chloride attacks.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2005.05b
• /
• pp.249-252
• /
• 2005

Chloride ingress is a common cause of deterioration of reinforced concrete structures. Modeling the chloride ingress is an important basis for designing reinforced concrete structures and for assessing the reliability of an existing structure. The modelling is also needed for predicting the deterioration of a reinforced structure. This paper presents an approach for the probabilistic modeling of the chloride-induced corrosion of reinforcement steel in concrete structures that takes into account the uncertainties in the physical models. The parameters of the models are modeled as random variables and the distribution of the corrosion time and probability of corrosion are determined by using Monte Carlo simulation. The predictions of the proposed model is very effective to do the decision-making about initiation time and deterioration degree.

• Corrosion Science and Technology
• /
• v.6 no.6
• /
• pp.297-303
• /
• 2007

This paper discusses the chloride-induced corrosion of reinforcement in marine concrete structures focusing on the variability in the progress of deterioration. Through tests and analyses of reinforced concrete slabs taken out from existing open-pile structures that have been in service for 30 to 40 years, the following topics were particularly discussed: variation in chloride ion profiles of concrete, variation in corrosion properties of reinforcement embedded in concrete, and influence of the reinforcement corrosion on the load-carrying capacity of the concrete slabs. As a result, their variability was found to be very large even in one reinforced concrete slab with almost the same conditions. It was also discussed how to determine the calculation parameters for prediction of decreasing in load-carrying capacity of concrete members with chloride-induced corrosion of reinforcement.

• Journal of the Korean Society of Hazard Mitigation
• /
• v.2 no.1 s.4
• /
• pp.143-152
• /
• 2002

The objectives of this paper were to obtain the fundamental data to analyze the causes of deterioration of 39 freeway concrete viaducts in Seoul metropolitan area. To investigate the degree of concrete deterioration, carbonation depth, soluble chloride concentration in hardened concrete and half-cell potentials of reinforcement were measured. The number of structures which carbonation depth penetrates to reinforcement was 25% of total. The model of carbonation .ate was induced to 3.92 $\sqrt{t}$, which was 5% faster than 3.727 $\sqrt{t}$ assumed 60% water-cement ratio, R=1 in that of kishitani. After measuring chloride concentration in concrete, it was concluded that about 24% of all readings on samples from concrete exceed the critical content to minimize the risk of chloride-induced corrosion. About 31% of the freeway viaducts structures had a value lower than -350mV(vs. CSE), so it could conclude that the excessive chloride concentration was the major cause of reinforcement corrosion. Among the structures which measured half-cell potentials less than -350mV, about 50% exceeds the maximum acceptable limit of chloride concentration.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2003.05a
• /
• pp.1061-1066
• /
• 2003

Chloride penetration into concrete is the main cause of the steel corrosion in concrete structures exposed to chloride-rich environments. Protective surface coatings are increasingly being applied to concrete structures to reduce chloride penetration. In this study, the performance of various surface coatings was evaluated. Most coatings showed good results for the various tests of the performance evaluation. Surface coatings can delay deterioration such as chloride-induced reinforcing bar corrosion effectively.

• Advances in concrete construction
• /
• v.1 no.3
• /
• pp.201-213
• /
• 2013

While recognizing the problem of reinforcement corrosion and premature structural deterioration of reinforced concrete (RC) structures as a combined effect of mechanical and environmental actions (carbonation, ingress of chlorides), emphasis is given on the effect of the latter, as most severe and unpredictable action. In this study, a simulation tool, based on proven predictive models utilizing principles of chemical and material engineering, for the estimation of concrete service life is applied on an existing reinforced concrete bridge (${\O}$resund Link) located in a chloride environment. After a brief introduction to the structure of the models used, emphasis is given on the physicochemical processes in concrete leading to chloride induced corrosion of the embedded reinforcement. By taking under consideration the concrete, structural and environmental properties of the bridge investigated, an accurate prediction of its service life is taking place. It was observed that the proposed, and already used, relationship of service lifetime- cover is almost identical with a mean line between the lines derived from the minimum and maximum critical values considered for corrosion initiation. Thus, an excellent agreement with the project specifications is observed despite the different ways used to approach the problem. Furthermore, different scenarios of concrete cover failure, in the case when a coating is utilized, and extreme deicing salts attack are also investigated.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2009.05a
• /
• pp.259-260
• /
• 2009

Many concrete structures have suffered from carbonation or chloride ion diffusion induced reinforcement corrosion, and a number of studies have been done on these topics. Many studies were mostly confined to the single deterioration of carbonation or chloride ion, although the environment actually presents a combined condition. This paper tried to develop the approach to compute re-diffusion of de-sorbed chloride due to carbonation of concrete. This is a key for successful combined deterioration model of carbonation and chloride. It is thought that this paper can contribute to express mathematically chloride enrichment and re-diffusion of chloride at front of carbonation.