• Title/Summary/Keyword: chloride resistance performance

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Effect of RuCl3 Concentration on the Lifespan of Insoluble Anode for Cathodic Protection on PCCP

  • Cho, H.W.;Chang, H.Y.;Lim, B.T.;Park, H.B.;Kim, Y.S.
    • Corrosion Science and Technology
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    • v.14 no.4
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    • pp.177-183
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    • 2015
  • Prestressed Concrete steel Cylinder Pipe (PCCP) is extensively used as seawater pipes for cooling in nuclear power plants. The internal surface of PCCP is exposed to seawater, while the external surface is in direct contact with underground soil. Therefore, materials and strategies that would reduce the corrosion of its cylindrical steel body and external steel wiring need to be employed. To prevent against the failure of PCCP, operators provided a cathodic protection to the pre-stressing wires. The efficiency of cathodic protection is governed by the anodic performance of the system. A mixed metal oxide (MMO) electrode was developed to meet criteria of low over potential and high corrosion resistance. Increasing coating cycles improved the performance of the anode, but cycling should be minimized due to high materials cost. In this work, the effects of $RuCl_3$ concentration on the electrochemical properties and lifespan of MMO anode were evaluated. With increasing concentration of $RuCl_3$, the oxygen evolution potential lowered and polarization resistance were also reduced but demonstrated an increase in passive current density and oxygen evolution current density. To improve the electrochemical properties of the MMO anode, $RuCl_3$ concentration was increased. As a result, the number of required coating cycles were reduced substantially and the MMO anode achieved an excellent lifespan of over 80 years. Thus, we concluded that the relationship between $RuCl_3$ concentration and coating cycles can be summarized as follows: No. of coating cycle = 0.48*[$RuCl_3$ concentration, $M]^{-0.97}$.

Corrosion Protection Method of Reinforcing Steel in Concrete by Using Corrosion Inhibitors

  • Bae Su-Ho;Chung Young-Soo;Kim Dae-Ho
    • KCI Concrete Journal
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    • v.14 no.4
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    • pp.145-150
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    • 2002
  • Reinforced concrete is inherently a durable composite material. When properly designed for the environment to be exposed and carefully constructed, reinforced concrete is capable of giving maintenance-free performance. However, unintentionally using improper materials such as non-washed sea sand having much salt together with poor controlled quality, or the concrete are placed in highly severe environment such as marine atmosphere, the corrosion of reinforcing steel in concrete becomes one of the most significant concerns of concrete. The purpose of this experimental research is to evaluate the performance of corrosion inhibitors for normal strength and high strength concrete, and to propose desirable measures for controlling corrosion of reinforcing steel in concrete. Test specimens in normal strength and high strength concrete were made with and without corrosion inhibitors. The accelerated corrosion test for reinforcing steel in concrete was adopted in accordance with JCI-SC3, which required the periodic 20 cycles for 140 days. One cycle includes 3 days for the wetting condition of $65^{\circ}C$ and $90\%$ RH, and 4 days for the drying condition of $15^{\circ}C\;and\;60\%$ RH. It was observed from the test that corrosion inhibitors in normal strength concrete and high strength concrete showed excellent corrosion resistance for reinforcing steel in concrete, but the silica fume in high strength concrete was found to have a negligible corrosion resistance if not used with corrosion inhibitors, since the chloride corrosion threshold limit in concrete containing silica fume without corrosion inhibitor was found to be considerably smaller than that of the case with corrosion inhibitor.

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Effect of Latex and Mineral Additive on Durability of Remicon LMC (라텍스와 광물질 첨가제가 레미콘LMC (Remicon Latex Modified Concrete) 내구성에 미치는 영향)

  • Choi, So Yeong;Choi, Yoon Suk;Heo, Hyeong Seok;Yang, Eun Ik
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.34 no.6
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    • pp.1743-1751
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    • 2014
  • It is well known that latex modification can lead to enhancement compressive and flexural performance, tensile bond strength, chloride penetration resistance and freezing-thawing resistance for concrete. For these, many studies for LMC pavement have been widely conducted more than those for conventional pavement concrete. However, due to several problems such as noise and construction cost, new approaches for LMC have been executed to improve the performance of LMC. Recently, Remicon LMC was developed in order to solve the problems of LMC. In this study, the durability of Remcion LMC was compared with latex and mineral additive mixing ratio. From the results, when latex and mineral additive were mixed in Remicon LMC, compressive, flexural and bond strength were satisfied with Korea Highway Construction Guide Specification. And, it showed that the qualitative effect of latex and mineral additive mixing ratio on the durability of Remicon LMC was investigated experimentally. Also, the latex mixed in Remicon LMC must be at least 8%, in order to ensure the durability equivalent or higher than conventional LMC.

An Electrochemical Evaluation of the Corrosion Property on the Welded Zone of Sea Water Pipe according to Welding Materials (용접 재료 별 해수 배관 용접부위의 부식 특성에 관한 전기화학적 평가)

  • Kim, Jin-Gyeong;Won, Chang-Uk;Jo, Hwang-Rae;Lee, Myung-Hoon;Kim, Yun-Hae;Moon, Kyung-Man
    • Journal of Ocean Engineering and Technology
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    • v.21 no.5
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    • pp.39-46
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    • 2007
  • The sea water pipe of a ship's engine room is a severely corrosive environment caused by fast flawing sea water containing chloride ions and high conductivity. Therefore, leaking of sea water may occur as a result of local corrosion of the welded zone. Leaking is usually controlled by various welding methods. In this study, when the sea water pipe is welded with certain welding methods and welding electrodes, the corrosion resistance of WM (Welding metal) and HAZ (Heat affected zone) was investigated using electrochemical methods. Although the corrosion potential of the HAZ is higher than that of WM, the corrosion resistance of WM is superior to HAZ. However, when WM and HAZ are both opened to the sea water, the WM part with the anode was more seriously corroded than was the HAZ of the cathode by performance of a galvanic cell due to difference of the corrosion potential between HAZ and WM. In particular TIG welding showed relatively good results in corrosion resistance of both HAZ and WM compared to other welding methods.

The Analysis of Thermal Conductivity and Basic Quality Performances of Decoration Wood-based Flooring Board Laminated with PVC Surface Decoration Materials (PVC 표면치장재를 적층한 치장목질마루판의 열특성 및 기초 품질성능 분석)

  • Park, Cheul-Woo
    • Journal of the Architectural Institute of Korea Structure & Construction
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    • v.34 no.1
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    • pp.53-60
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    • 2018
  • For test on flooring board laminated with PVC decoration materials in order to replace the current surface materials such as HPL in decoration wood-based flooring board. the Results of comparison and analysis are as follows: For thermal conductivity, flooring board decorated with PVC did not show huge differences when temperature was rising and lowering compared to the flooring materials laminated with the existing HPL surface materials. It seems the most meaningful results for using it as indoor flooring materials. That is, in Korea where there is the culture focusing on ondol heating, use amount of heat energy and efficiency of flooring materials are very important and sensitive issues, involving immediately with household economy of final consumers, and it might be a criteria to judge basic performances required as flooring materials. As a result of the analysis on mandatory durability test items such as abrasion resistance, absorption width expansion rate, impact resistance, surface hardness, and impact absorption for flooring materials, compared to flooring board laminated with general HPL surface decoration materials, decoration wood-based flooring board laminated with PVC surface decoration materials which is higher abrasion resistance with smaller transformation and has better durability and impact absorption of the surface, is available for actual application as indoor flooring board, and for replacing surface decoration materials impregnated with heat-hardened resion such as HPL.

A Fundamental Study on the Influence of Performance of Cementitious Composites of Inorganic Core Material for Self-Healing Capsule of Cracks (균열 자기치유를 위한 캡슐용 무기계 코어재료의 시멘트 복합체 성능에 미치는 영향에 관한 기초적 연구)

  • Choi, Yun-Wang;Oh, Sung-Rok;Choi, Byung-Keol;Kim, Cheol-Gyu
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.1
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    • pp.74-82
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    • 2017
  • In this study, we prepared a core material based on the inorganic materials in liquid form for applying an inorganic-based core material to a core material for the self-healing capsules as a part of the basic study to manufacture of self-healing capsule that can heal cracks of cementitious composite. Manufactured core material based on the inorganic materials were applied directly to the cement composite before its encapsulation, were evaluated the effect on performance of cementitious composite as wall as repair performance of the cracks in the cracks. The test results showed that core material based on the inorganic materials was effective to improve the compressive and adhesion strength, had an absorption, permeation water, penetration of chloride iones and freeze-thaw resistance performance. Through the results of this paper, we want to utilize the results as a basis data of the performance of the cement composite that can be obtained when applied to inorganic core materials based on self-healing capsules and future advances localized self-healing capsule technology.

An Experimental Evaluation on Performance of Surface Protector for Concrete Structures (콘크리트 구조물 표면 보호재의 성능에 대한 실험적 평가)

  • Nam, Yong-Hyuk;Chung, Young-Jun;Jang, Suk-Hwan;An, Young-Ki
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.10 no.5
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    • pp.157-163
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    • 2006
  • This study is on the evaluation of double surface protection method using water repellent primer and final top coat to protect concrete. Water repellent agent has been applied on the final top coat to protect concrete. However, to make up for the weakness to the ultraviolet of the water repellent, the work procedure of these protectors is done vice versa. This combination of protectors was compared with existing ones in this study. Even though the final top coat was applied on the water repellent primer, its adhesive strength met to KS F 4936-' 03 with other protectors used in this study. All surface protectors used in this study were excellent in protecting concrete. Especially, in case of applying with final top coat in conjunction with water repellent primer, the resistance against chloride ion penetration and neutralization by $CO_2$ was more efficient than other surface protectors used in this study under this given condition.

Properties of Polymer Cement Mortars under Combined Cures (복합양생에 의한 폴리머 시멘트 모르타르의 성질)

  • Jo, Young-Kug
    • Journal of the Korea Concrete Institute
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    • v.18 no.5 s.95
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    • pp.667-675
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    • 2006
  • Concrete is much more easily damaged by various parameters than by the only one and performance reducing mechanism grows more complicated in that condition. In addition, the factors which really act in concrete structure tend to be activated in turn and the degradation of concrete is very rapidly progressed. The purpose of this study is to evaluate the properties of polymer cement mortars under combined cures. The polymer cement mortars are prepared with various polymer types, polymer-cement ratios and cement-fine aggregate ratio, and tested for compressive and flexural strengths, accelerated carbonation, chloride ion penetration and acid resistance test, and freezing-thawing test. The properties of polymer cement mortars under combined cures is discussed. From the test results, polymer cement mortars have superior strengths compared with plain cement mortar under combined cures. The strengths of polymer cement mortars are markedly increased at curing condition II and V, however strengths are not improved at curing condition I and IV irregardless of polymer types. The carbonation and chloride ion penetration depths of polymer cement mortars tend to decrease in curing conditions, III-C, IV-B, V-A order, and decrease with increasing polymer cement ratios. It is concluded that polymer cement ratio of 10 to 15% are considered optimum for the preparation of such polymer cement mortars.

Thermodynamic Modeling of Long-Term Phase Development of Slag Cement in Seawater (해수에 노출된 슬래그 시멘트의 장기 상변이 열역학 모델링)

  • Park, Solmoi;Suh, Yongcheol;Nam, Kwang Hee;Won, Younsang
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.41 no.4
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    • pp.341-345
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    • 2021
  • Known to improve resistance to chloride ingress, blast furnace slag is a widely used supplementary cementitious material. However, a detailed characterization of cements blended with slag exposed to seawater remains unavailable. This study employs thermodynamic modeling as a toolkit for assessing the long-term phase evolution of slag cement in seawater. The modeling result shows that slag incorporation leads to the formation of phases that are less prone to structural alteration in seawater. Formation of more ettringite is expected to induce expansion in both plain and blended cements, while brucite is unstable in the blended systems. Despite this, the porosity is expected to increase in the blended cements, and aluminate hydrates with a higher chloride binding capacity are more abundant in the blended cements. The results suggest that the use of slag in concrete improves the durability performance of concrete in marine environments.

Performance and reusability of certified and uncertified face masks (보건용 마스크 초미세먼지 제거 성능 평가 및 재사용 연구)

  • Lee, Haebum;Kim, Seojeong;Joo, HungSoo;Cho, Hee-joo;Park, Kihong
    • Particle and aerosol research
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    • v.15 no.4
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    • pp.191-202
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    • 2019
  • In this study, performance (particle removal efficiency and breathing resistance) of several commercially available face masks (electrostatic filter masks (KF80 certified), a nanofiber filter mask (KF80 certified), and an uncertified mask) with their filter structure and composition were evaluated. Also, effects of relative humidity (RH) of incoming air, water and alcohol exposure, and reusability on performance of face masks were examined. Monodisperse and polydisperse sodium chloride particles were used as test aerosols. Except the uncertified mask filter, PM2.5 removal efficiency was found to be higher than 90%, and the nanofiber filter mask had the highest quality factor due to the low pressure drop and high removal efficiency (nanofibers were arranged in a densely packed pore structure and contained a significant amount of fluorine in addition to carbon and oxygen). In the case of the KF80 certified mask, the removal efficiency was little affected when the RH of incoming air increased. When the mask filters were soaked in water, the removal efficiency of mask filters was degraded. In particular, the uncertified mask filter showed the highest removal efficiency degradation (26%). When the mask was soaked in alcohol, the removal efficiency also decreased with the greater degree than the water soaking case. The nanofiber mask filter showed the strongest resistance to alcohol exposure among tested mask filters. During evaluation of reusability of masks in real life, the removal efficiency of certified mask filter was less than 4% for 5 consecutive days (2 hours per day), while the removal efficiency of uncertified mask filter significantly decreased by 30% after 5 days.