• Architectural research
• /
• 제7권1호
• /
• pp.49-54
• /
• 2005

Conventional studies have focused on the reduction in the water-cement ratio, the use of various admixtures, etc., to ensure the durability of reinforced concrete structures against such deterioration factors as carbonation and chloride attack. However, improvement in the concrete quality alone is not considered sufficient or realistic for meeting the recent demand for a service life of over 100 years. This study intends to improve the durability of reinforced concrete structures by improvement in the reinforcing steel, which has remained untouched due to cost problems, through subtle adjustment of the steel components to keep the cost low. As a fundamental study on the performance of Cr-bearing rebars in steel reinforced concrete structures exposed to corrosive environments, The test specimens were made by installing 8 types of rebars in concretes with a chloride ion content of 0.3, 0.6, 1.2, 2.4 and $24kg/m^3$. Corrosion accelerated curing were then conducted with them. The corrosion resistance of Cr-bearing rebars was examined by measuring crack widths, half-cell potential, corrosion area and weight loss after 155 cycles of corrosion-accelerating curing. The results of the study showed that the corrosion resistance increased as the Cr content increased regardless of the content of chloride ions, and that the Cr-bearing rebars with a Cr content of 5% and 9% showed high corrosion resistance in concretes with a chloride ion content of 1.2 and $2.4kg/m^3$, respectively.

• 해양환경안전학회지
• /
• 제20권6호
• /
• pp.730-737
• /
• 2014

본 연구에서는 남해안에 건설된 사용기간이 5~34년의 해상 콘크리트 교량의 염화물이온농도에 대한 실측데이터로부터 표면염화물이온농도를 추정하고, 기존에 제시된 시방서와 타 연구결과에서 제시한 값들의 타당성을 평가하였다. 그리고 해상 콘크리트 교량의 염해방지도장의 유무, 염화물이온농도, 탄산화 깊이 및 콘크리트 압축강도의 상관관계를 도출하여 상호 작용을 평가하였다. 연구결과에 의하면, 표면염화물이온농도는 간만대에서 KCI 2009, 물보라지역과 해상대기중에서 Cheong et al.(2005)의 제안한 값이 타당한 것으로 판단된다. 또한, 해상 콘크리트 교량의 염해방지도장은 염화물이온의 침투, 탄산화 깊이 및 압축강도 저하 대한 방지효과가 있음을 알 수 있었다. 콘크리트의 압축 강도는 탄산화 깊이와 염화물이온농도의 증가에 따라 감소하였다.

• Corrosion Science and Technology
• /
• 제22권3호
• /
• pp.201-213
• /
• 2023

Corrosion management of an aircraft and its engine relies on rinsing and cleaning using tap water. Few studies have reported effects of tap water species on corrosion behaviors of structural materials. In this study, a series of experiments were conducted based on the design of experiment. Solutions with different levels of chloride and sulfate ions were prepared using a full factorial design. Two structural materials (aluminum alloy and steel) were used for an alternate immersion test. Weight loss was then measured. In addition, a silver specimen was utilized as a sensor for chloride deposition measurement. The silver specimen was examined using the electrochemical reduction method, XPS, and SEM-EDS. Surface analysis revealed that levels of chloride and sulfate ions were sufficient for the formation of silver chloride and silver surface. Statistical analysis of weight loss and chloride deposition rate showed significant differences in measured values. Concentration of chloride ions greatly affected corrosion behaviors of structural materials. Sulfate ion hindered the adsorption reaction. These results emphasize the importance of controlling ion concentration of tap water used for cleaning and rinsing an aircraft.

• 한국생물공학회:학술대회논문집
• /
• 한국생물공학회 2005년도 생물공학의 동향(XVII)
• /
• pp.704-705
• /
• 2005

• 한국방사성폐기물학회:학술대회논문집
• /
• 한국방사성폐기물학회 2018년도 춘계학술논문요약집
• /
• pp.102-103
• /
• 2018

• Bulletin of the Korean Chemical Society
• /
• 제10권2호
• /
• pp.208-210
• /
• 1989

• Bulletin of the Korean Chemical Society
• /
• 제14권3호
• /
• pp.313-315
• /
• 1993

• 한국전산구조공학회논문집
• /
• 제28권5호
• /
• pp.563-570
• /
• 2015

기존 구조물의 손상평가에 관한 연구는 지진 등과 같은 과도한 하중에 의한 손상을 고려하였다. 그러나 구조물은 과도한 하중없이도 장기간의 시간에 따라 염화물, 탄성화 등과 같은 이유로 노후화가 진행되어 구조성능이 저하될 수 있다. 그래서 구조물의 건전도를 효과적으로 관리하기 위해서는 노후화에 의한 구조성능 저하도 검토되어야 한다. 본 연구에서는 염화물에 의한 철근의 부식을 노후화 요인으로 고려한다. 철근부식에 의한 재료의 구조성능 저하를 고려하기 위해 부식정도에 따른 철근의 단면적, 항복강도, 파단변형률, 피복 콘크리트 강도 등을 예측한다. 이를 구조모델링에 적용하여 구조부재 및 구조물의 구조성능 저하를 분석한다. 구조부재의 구조성능을 분석하기 위해 모멘트-곡률 해석을 수행한다. 구조물 레벨의 구조성능을 고려하기 위해, 고유치해석을 통한 고유주기와 모드형상을 분석한다. 또한 비선형 정적해석을 통해 구조물의 강도와 변형성능을 분석한다.

• 한국분말재료학회지
• /
• 제18권4호
• /
• pp.359-364
• /
• 2011

Zr-Ti alloy powders were successfully synthesized by magnesium thermal reduction of metal chlorides. The evaporated and mixed gasses of $ZrCl_4+TiCl_4$ were injected to liquid magnesium and the chloride components were reduced by magnesium leading to the formation of $MgCl_2$. The released Zr and Ti atoms were then condensed to particle forms inside the mixture of liquid magnesium and magnesium chloride, which could be dissolved fully in post process by 1~5% HCl solution at room temperature. By the fraction-control of individually injected $ZrCl_4$ and $TiCl_4$ gasses, the final compositions of produced alloy powders were changed in the ranges of Zr-0 wt.%~20 wt.%Ti and their purity and particle size were about 99.4% and the level of several micrometers, respectively.

• 한국환경복원기술학회지
• /
• 제22권6호
• /
• pp.15-25
• /
• 2019

Contamination of soil by deicing salt is among the important environment problems due to their toxicity and negative impact to human health and the environment. One of the effective methods for cleaning the soil from deicing salts is desalination using soil amendment-phytoremediation continuum treatment. The purpose of this study was to determine how much of the pH, EC control and Ca²⁺, Na⁺, Mg²⁺, and K⁺ taken up soil amendments and Miscanthus sinensis, and to evaluate the effect of salt reduction and growth improvement as affected by soil amendment in high concentration of calcium chloride (CaCl₂) deicing salts. Results indicated that the addition of soil amendments was decrease the EC and pH, also significantly reduce the leaching of Ca²⁺, Na⁺, Mg²⁺, K⁺, a chloride ions related deicing salts, compared to the control for CaCl₂ 10 g/L treatment. It also resulted in an enhanced plant growth and higher plant height, leaf length, leaf width, number of leaves, fresh weight and dry weight in Hydroball treatment + Miscanthus sinensis planting continuum treatment compared to the treatment that planted Miscanthus sinensis only. Therefore, we concluded that soil amendments might be attributed to an accumulation of deicing slats in the roadside soil, resulting in the improvement of Miscanthus sinensis growth.