• Bulletin of the Korean Chemical Society
• /
• 제4권1호
• /
• pp.3-9
• /
• 1983

Lithium n-butylborohydride was prepared from borane-dimethylsulfide (BMS) and n-butyllithium, and the approximate rates and stoichiometrics of its reactions with selected organic compounds containing representative functional groups were studied in THF at room temperature. Phenol and benzenetiol liberated hydrogen quickly and quantitatively, and the reactions of primary alcohols, 2,6-di-ter-butylphenol and 1-hexanethiol liberated hydrogen quantitatively within 3 hrs, whereas the reactions of secondary and tertiary alcohols were very slow. Aldehydes and ketones were reduced rapidly and quantitatively to the corresponding alcohols. Cinnamaldehyde utilized 1 equiv. of hydride rapidly, suggesting the reduction to cinnamyl alcohol. Carboxylic acids evolved 1 equiv. of hydrogen rapidly and further reduction was not observed. Anhydrides utilized 2 equiv. of hydride rapidly but further hydride uptake was very slow, showing a half reduction. Acid chlorides were reduced to the alcohol stage very rapidly. All the esters examined were reduced to the corresponding alcohol rapidly. Lactones were also reduced rapidly. Expoxides took up 1 equiv. of hydride at a moderate rate to be reduced to the corresponding alcohols. Nitriles and primary amides were inert to this hydride system, whereas tertiary amide underwent slow reduction. Nitroethane and nitrobenzene were reduced slowly, however azobenzene and azoxybenzene were quite inert. Cyclohexanone oxime evolved 1 equiv. of hydrogen rapidly, but no further reduction was observed. Phenyl isocyanate and pyridine N-oxide were proceeded slowly, showing 1.74 and 1.53 hydride uptake, respectively in 24 hours. Diphenyl disulfide was reduced rapidly, whereas di-n-butyl disulfide, sulfone and sulfonic acids were inert or sluggish. n-Hexyl iodide and benzyl bromide reacted rapidly, but n-octyl bromide, n-octyl chloride, and benzyl chloride reacted very slowly.

• 한국구조물진단유지관리공학회 논문집
• /
• 제9권2호
• /
• pp.121-128
• /
• 2005

본 연구의 목적은 염화물의 침투로 인한 RC 교량 바닥판의 신뢰성지수를 계산하고 철근부식으로 인한 교량 덱의 상태등급과 신뢰성지수와의 관계를 연구하는 것이다. 이런 목적을 위해 먼저 휨강도와 관련한 파괴확률을 열화(제설염에 의한 장기간의 구조물 손상 및 구조물 안전성 저하)와 관련하여 계산하였으며 구조물 면에 포함된 염화물의 농도, 피복두께 및 철근의 초기부식시간 그리고 염화물 확산으로 인한 철근의 균열시간 등을 MCS기법을 이용하여 찾아내었다.

• 한국해양공학회지
• /
• 제19권6호통권67호
• /
• pp.29-34
• /
• 2005

This paper describes the effect of fly ash replacement on seawater resistance of anti-washout underwater concrete, which was replaced cement by fly ash from $0\%$ to $50\%$. The experimental work was performed to find out the variations of length and weight of specimens, using a chloride acceleration test in $40\^{\circ}$C The results shaw that the admixture using fly ash on an anti-washcout underwater concrete in the sea environment makes it more durable for the attacks of chloride by seawater. Also, the length of specimens of anti-washout underwater concrete, at age 180 days, increased substantially, compared with normal concrete; however, the mixture in which cement was replaced $50\%$ of fly ash shows $93\%$ reduction of the expansion, compared with the normal anti "washout underwater concrete specimen.

• 공업화학
• /
• 제3권2호
• /
• pp.288-295
• /
• 1992

Triirondodecacarbonyl에 의한 니트로벤젠의 환원 반응에 상 이동 촉매를 사용한 결과 상온에서 높은 수율의 아닐린을 합성할 수 있었다. Benzyltriethylammonium chloride, tricaprylmethylammonium chloride, 18-crown-6, polyethyleneglycol-400 등이 이 반응에 좋은 상 이동 촉매임을 알 수 있었고, 반응온도, 수용액상의 NaOH 농도, 유기용매가 반응속도 및 아닐린의 수율에 미치는 영향을 고찰하였다.

• Corrosion Science and Technology
• /
• 제4권1호
• /
• pp.19-22
• /
• 2005

Two Au-Ag-Cu-Pd dental casting alloys (Au:12% and 20%) used. The test solutions used 0.9 % NaCl solution (isotonic sodium chloride solution), 0.9 % NaCl solution containing 1 % lactic acid, and 0.9 % NaCl solution containing 1 % lactic acid and 0.1 mol $dm^{-3}$ $Na_2S$. The surface of two samples in three sample solutions was not natural discoloration during one year. The alloy containing 12 % gold was easily alloyed and the composition was uniform comparing with the alloy containing 20 % gold. The rest potentials have not a little effect after three months. The kinds of metals could not definitely from the oxidation and reduction waves of metal on the cyclic voltammograms. The dissolutions of gold and palladium were 12 % Au sample in the 0.9 % NaCl solution containing 1 % lactic acid and 0.1 mol $dm^{-3}$ $Na_{2}S$. The pH of solution had an affect on dissolution of copper, and sulfur ion had an affect on dissolution of silver. The copper dissolved amount from 20 % gold sample was about 26 times comparing with that of 12 % gold sample in the 0.9 % solution containing 1 % lactic acid. Corrosion products were silver chloride and copper chloride in NaCl solution, and silver sulfide and copper sulfide in NaCl solution containing $Na_{2}S$.

• Membrane and Water Treatment
• /
• 제6권1호
• /
• pp.43-52
• /
• 2015

A small-scale electro-dialysis system was constructed for domestic use. It is composed of six compartments in which five special polystyrene ionic membranes are housed. A series of experiments on the transport of sodium and chloride ions through polystyrene membranes was performed and the effects of electric current and voltage on the pH of water were investigated. This electrodialyser could reduce the NaCl content to an acceptable level (5307 mg/L) when water containing 9945 mg/L of sodium chloride is fed to the electrodialyser. The reduction was by the action of direct current 60 mA/100 mA when a 15 V / 20 V potential is maintained across the membrane. The results showed that the pH of the treated water attained a value in the range of 7-8, with the chloride concentration of 5307 mg/L when the voltage was in the range of 20 volts. This was achieved when two of the small-scale electro-dialysers were placed in series and the solutions from the respective compartments were mixed. This is considered useful because this complies to the requirement of drinking water standard both in terms of chloride and pH. Therefore, this type electrodialyserhas the potential for domestic uses in isolated houses where potable water supply is not available.

• Journal of Electrochemical Science and Technology
• /
• 제12권4호
• /
• pp.440-452
• /
• 2021

Enhancement of durability and reduction of maintenance cost of concrete, with the implementation of various approaches, has always been a matter of concern to researchers. The integration of pozzolans as a substitute for cement into the concrete is one of the most desirable technique. Silica fume (SF) and colloidal nanosilica (CS) have received a great deal of interest from researchers with their significant performance in improving the durability of concrete. The synergistic role of the micro and nano-silica particles in improving the main characteristics of cemented materials needs to be investigated. This work aims to examine the utility of partial substitution of cement by SF and CS in binary and ternary blends in the improvement of the durability characteristics linked to resistance for electrochemical corrosion using electrical resistivity and half-cell potential analysis and chloride penetration trough rapid chloride penetration test. Furthermore, the effects of this silica mixture on the compressive strength of concrete under normal and aggressive environment have also been investigated. Based on the maximum compression strength of the concrete, the optimal cement substituent ratios have been obtained as 12% SF and 1.5% CS for binary blends. The optimal CS and SF combination mixing ratios has been obtained as 1.0% and 12% respectively for ternary blends. The ternary blends with substitution of cement by optimal percentage of CS and SF exhibited decreased rate for electrochemical corrosion. The strength and durability studies were found in consistence with the microstructural analysis signifying the beneficiary role of CS and SF in upgrading the performance of concrete.

• Bulletin of the Korean Chemical Society
• /
• 제22권11호
• /
• pp.1202-1206
• /
• 2001

Irradiation of 1-(o-hydroxyphenyl)-2-pentamethyldisilanylethyne 1 in a concentrated benzene solution has provided photodimer product 7 along with other reported photoproducts. Irradiation of 1 in methanol yields 1-(o-hydroxyphenyl)-2-trimethylsilylethyne 2 and its reduction product 13, via silacyclopropene intermediate 10, and the reduction product 8 and two methanol addition products, 11 and 12, via o-hydroxyphenylethyne. Photolysis of 1 with acetone in deaerated methylene chloride affords site specific and regioselective 1 : 1 adduct 16 via silacyclopropene intermediate 10.

• 콘크리트학회논문집
• /
• 제25권4호
• /
• pp.411-418
• /
• 2013

최근 해양 콘크리트 구조물의 염해 및 수화열 저감을 위한 재료적 대책으로 혼합시멘트의 사용이 증가하고 있다. 혼합시멘트는 염해 및 수화열 저감 성능이 우수한 결합재이지만 재령 28일까지의 압축강도 발현이 작은 특징이 있다. 그러나 현행 해양 콘크리트 시방 규정은 높은 수준의 설계기준 압축강도를 재령 28일에 엄격히 만족하도록 되어 있다. 따라서 혼합시멘트를 사용하면 물-결합재비는 작고 단위결합재량은 많은 해양 콘크리트 배합이 예상된다. 이와 같이 높은 압축강도 위주의 해양 콘크리트 배합은 염해 내구성 확보에 유리하지만 수화열 저감에는 불리하다. 따라서 이 연구에서는 물-결합재비 및 결합재 종류에 따른 해양 콘크리트의 재료적 특성을 실험적으로 검토하고 예측하였다. 검토 및 예측 결과, 고로슬래그시멘트(BSC) 및 삼성분계 혼합시멘트(TBC) 배합은 1종 보통포틀랜드시멘트(OPC) 배합보다 재령 28일까지의 압축강도 발현은 상대적으로 작지만 재령 56일에는 유사한 압축강도를 발현하였으며 염해 및 수화열에 유리한 것으로 나타났다. 그러나 현행 해양 콘크리트의 최소 설계기준 압축강도를 만족하기 위해서는 단열온도 상승량이 크게 증가하는 것으로 예측되어 이에 대한 대책이 필요할 것으로 판단된다.

• 설비공학논문집
• /
• 제7권3호
• /
• pp.359-365
• /
• 1995

The drag reduction phenomenon with an additives of surfactant(STAC, stearlytrimethyl ammonium chloride) and polymer(PEO, polyethlene oxide) was investigated in fully developed turbulent pipe and channel flows at various low Reynolds numbers as well as very low additives concentration. A maximum of 70% drag reduction compared with plain water flow was found. This maximum drag reduction percentage obtained with surfactant solution was slightly higher than that of the Virk's asymptote in polymer solution.